Vibrational State Mixing and Vibrational Relaxation of Electronically Excited Polyatomic Molecules PDF Download

Author: Desmond John Muller
Publisher:
ISBN:
Category : Vibration
Languages : en
Pages :

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Author: David Bates Moss
Publisher:
ISBN:
Category : Benzene
Languages : en
Pages : 336

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 17

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Book Description
The transfer of energy in isolated or colliding molecules is a fundamental process with practical consequences for complex phenomena occurring in atmospheric chemistry, combustion, molecular lasers, plasmas, and a host of other environments containing energetic species. We have developed a technique that combines vibrational overtone excitation, to prepare highly vibrationally excited initial states, and time-resolved spectroscopic detection, to probe the evolution of the prepared state, for studying energy transfer in vibrationally energized molecules. We have used this approach to determine directly, for the first time, the frequencies of the three ungerade vibrations in the first electronically excited state of acetylene. Using this information we have characterized highly vibrationally excited states of acetylene and directly the frequencies and rotational constants of the perturbing vibrational states at these energies. Combining these spectroscopic insights on the vibrationally and electronically excited states of acetylene has allowed us to determine the energy transfer rates and pathways in the collisional relaxation of a polyatomic molecule containing 10,000 cm-1 of vibrational energy, Rotational energy transfer is very rapid, occurring on about every other collision, but is essentially unaffected by the identity of the vibrational state in which the rotational relaxation occurs.

Author: Kenneth Michael Beck
Publisher:
ISBN:
Category :
Languages : en
Pages : 440

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Author: John Vlahoyannis
Publisher:
ISBN:
Category :
Languages : en
Pages : 326

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Author: Mario Capitelli
Publisher: Springer Science & Business Media
ISBN: 3642486150
Category : Science
Languages : en
Pages : 354

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This book is devoted to the systematic treatment of nonequi 1 ibrium vibrational kinetics in molecular systems. Particular emphasis is given to the vibrational excitation of diatomic molecules by low-energy electrons in a discharge and by IR photons in laser-pumped systems. The book follows the different steps of the introduction, redistribution, loss, and chemical conversion of the vibrational quanta, from the points of view of the overall kinetics and the dynamics of elementary processes. These two aspects are balanced in a multidisciplinary approach. The different chapters give the basic instruments (theoretical and experimental) which are needed to understand the ki netics of nonequilibrium systems. The book will introduce the reader to different areas such as plasmachemistry, laser chemistry, IR and Raman spectroscopy, and relaxation phenomena, emphasizing how the vibrational energy affects such research fields. The chapters dedicated to collisional dynamics involving vibrational excited molecules provide an introduc tion to the modern techniques uti 1 ized in the scattering theory of inelastic and reactive collisions. The extension of the vibrational kinetics to polyatomic mole cules, discussed in Chap. 10, is the natural bridge between coll ision and coll i sionless regimes. In conclusion, we hope that the approach followed in this book will stimulate the collaboration of researchers coming from different research fields, which are too often completely separate.

Author: Amy S. Mullin
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 352

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Book Description
Integrating both theoretical and experimental approaches, this unique book examines transition states and chemical reactivity, and will be a useful tool for anyone studying the chemical dynamics, nature, and behavior of molecules in an excited state. The subject has important applications in atmospheric chemistry, plasmas, high-temperature materials processing, combustion, photosynthesis, detonation, and explosives.

Author: James Dewe Lambert
Publisher: Oxford University Press, USA
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 168

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Author: Joshua Jortner
Publisher: Springer Science & Business Media
ISBN: 9400979274
Category : Science
Languages : en
Pages : 550

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The Fifteenth Jerusalem Symposium reflected the high standards of the former international scientific meetings, which convene once a year at the Israel Academy of Sciences and Humanities in Jerusalem to discuss a specific topic in the broad area of quantum chemistry and biochemistry. The topic at this year's Jerusalem Symposium was intramo lecular dynamics, a subject of central interest for theoreticians, che mists and biologists. During the last two decades, there has been remarkable pro gress in our understanding of time dependent phenomena. The development and application of the modern techniques of quantum mechanics and sta tistical mechanics to excited-state dynamics and to chemical and biophy sical systems constitutes a fast developing current research area. The main theme of the Symposium was built around a conceptual framework for the elucidation of photophysical and photochemical phenomena in atoms, molecules, van der Waals complexes and clusters, condensed phases, poly mers and biological supermolecules. The interdisciplinary nature of this research field was deliberated by intensive and extensive interactions between scientists from different disciplines and between theory and experiment. This volume provides a record of the invited lectures at the Symposium.

Author: Edward C. Lim
Publisher: Elsevier
ISBN: 1483275493
Category : Science
Languages : en
Pages : 262

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Book Description
Excited States, Volume 7 is a collection of papers that discusses the excited states of molecules. The first paper reviews the rotational involvement in intra-molecular in vibrational redistribution. This paper analyzes the vibrational Hamiltonian as to its efficacy in detecting the manifestations of intra-molecular state-mixing in time-resolved and time-averaged spectroscopic measurements. The next paper examines the temporal behavior of intra-molecular vibration-rotation energy transfer (IVRET) and the effects of IVRET on collision, reaction, and the decomposition processes. This paper also describes how IVRET can decrease the anisotropy of the angular distribution of photo dissociating molecules that takes longer than the rotational period of disassociation. The third paper explains rotations and electronic decay by focusing on nonresonant light scattering, which is explained in the theory of radiationless transitions, when the exciting light source is included. The last paper shows how sub-Doppler techniques adapted from atomic physics can measure accurately dense rotational triplet structure and singlet-triplet couplings in high vibrational triplet levels. This book will prove helpful for researchers whose work involves physical chemistry or molecular chemistry and physicists involved in atomic or solid-state physics.