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Vibrational Spectroscopy at Electrified Interfaces

Vibrational Spectroscopy at Electrified Interfaces PDF Author: Andrzej Wieckowski
Publisher: John Wiley & Sons
ISBN: 1118658965
Category : Science
Languages : en
Pages : 396

Book Description
Reviews the latest theory, techniques, and applications Surface vibrational spectroscopy techniques probe the structure and composition of interfaces at the molecular level. Their versatility, coupled with their non-destructive nature, enables in-situ measurements of operating devices and the monitoring of interface-controlled processes under reactive conditions. Vibrational Spectroscopy at Electrified Interfaces explores new and emerging applications of Raman, infrared, and non-linear optical spectroscopy for the study of charged interfaces. The book draws from hundreds of findings reported in the literature over the past decade. It features an internationally respected team of authors and editors, all experts in the field of vibrational spectroscopy at surfaces and interfaces. Content is divided into three parts: Part One, Nonlinear Vibrational Spectroscopy, explores properties of interfacial water, ions, and biomolecules at charged dielectric, metal oxide, and electronically conductive metal catalyst surfaces. In addition to offering plenty of practical examples, the chapters present the latest measurement and instrumental techniques. Part Two, Raman Spectroscopy, sets forth highly sensitive approaches for the detection of biomolecules at solid-liquid interfaces as well as the use of photon depolarization strategies to elucidate molecular orientation at surfaces. Part Three, IRRAS Spectroscopy (including PM-IRRAS), reports on wide-ranging systems from small fuel molecules at well-defined surfaces to macromolecular complexes that serve as the building blocks for functional interfaces in devices designed for chemical sensing and electric power generation. The Wiley Series on Electrocatalysis and Electrochemistry is dedicated to reviewing important advances in the field, exploring how these advances affect industry. The series defines what we currently know and can do with our knowledge of electrocatalysis and electrochemistry as well as forecasts where we can expect the field to be in the future.

Vibrational Spectroscopy at Electrified Interfaces

Vibrational Spectroscopy at Electrified Interfaces PDF Author: Andrzej Wieckowski
Publisher: John Wiley & Sons
ISBN: 1118658965
Category : Science
Languages : en
Pages : 396

Book Description
Reviews the latest theory, techniques, and applications Surface vibrational spectroscopy techniques probe the structure and composition of interfaces at the molecular level. Their versatility, coupled with their non-destructive nature, enables in-situ measurements of operating devices and the monitoring of interface-controlled processes under reactive conditions. Vibrational Spectroscopy at Electrified Interfaces explores new and emerging applications of Raman, infrared, and non-linear optical spectroscopy for the study of charged interfaces. The book draws from hundreds of findings reported in the literature over the past decade. It features an internationally respected team of authors and editors, all experts in the field of vibrational spectroscopy at surfaces and interfaces. Content is divided into three parts: Part One, Nonlinear Vibrational Spectroscopy, explores properties of interfacial water, ions, and biomolecules at charged dielectric, metal oxide, and electronically conductive metal catalyst surfaces. In addition to offering plenty of practical examples, the chapters present the latest measurement and instrumental techniques. Part Two, Raman Spectroscopy, sets forth highly sensitive approaches for the detection of biomolecules at solid-liquid interfaces as well as the use of photon depolarization strategies to elucidate molecular orientation at surfaces. Part Three, IRRAS Spectroscopy (including PM-IRRAS), reports on wide-ranging systems from small fuel molecules at well-defined surfaces to macromolecular complexes that serve as the building blocks for functional interfaces in devices designed for chemical sensing and electric power generation. The Wiley Series on Electrocatalysis and Electrochemistry is dedicated to reviewing important advances in the field, exploring how these advances affect industry. The series defines what we currently know and can do with our knowledge of electrocatalysis and electrochemistry as well as forecasts where we can expect the field to be in the future.

Compendium of Surface and Interface Analysis

Compendium of Surface and Interface Analysis PDF Author: The Surface Science Society of Japan
Publisher: Springer
ISBN: 9811061564
Category : Technology & Engineering
Languages : en
Pages : 807

Book Description
This book concisely illustrates the techniques of major surface analysis and their applications to a few key examples. Surfaces play crucial roles in various interfacial processes, and their electronic/geometric structures rule the physical/chemical properties. In the last several decades, various techniques for surface analysis have been developed in conjunction with advances in optics, electronics, and quantum beams. This book provides a useful resource for a wide range of scientists and engineers from students to professionals in understanding the main points of each technique, such as principles, capabilities and requirements, at a glance. It is a contemporary encyclopedia for selecting the appropriate method depending on the reader's purpose.

Encyclopedia of Interfacial Chemistry

Encyclopedia of Interfacial Chemistry PDF Author:
Publisher: Elsevier
ISBN: 0128098945
Category : Science
Languages : en
Pages : 5276

Book Description
Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions

Fundamentals of Sum-Frequency Spectroscopy

Fundamentals of Sum-Frequency Spectroscopy PDF Author: Y. R. Shen
Publisher: Cambridge University Press
ISBN: 131647304X
Category : Science
Languages : en
Pages : 570

Book Description
The first book on the topic, and written by the founder of the technique, this comprehensive resource provides a detailed overview of sum-frequency spectroscopy, its fundamental principles, and the wide range of applications for surfaces, interfaces, and bulk. Beginning with an overview of the historical context, and introductions to the basic theory of nonlinear optics and surface sum-frequency generation, topics covered include discussion of different experimental arrangements adopted by researchers, notes on proper data analysis, an up-to-date survey commenting on the wide range of successful applications of the tool, and a valuable insight into current unsolved problems and potential areas to be explored in the future. With the addition of chapter appendices that offer the opportunity for more in-depth theoretical discussion, this is an essential resource that integrates all aspects of the subject and is ideal for anyone using, or interested in using, sum-frequency spectroscopy.

Interfacial Water: A Physical Chemistry Perspective, Volume II

Interfacial Water: A Physical Chemistry Perspective, Volume II PDF Author: Motomu Tanaka
Publisher: Frontiers Media SA
ISBN: 2889747026
Category : Science
Languages : en
Pages : 97

Book Description
Topic Editor Harada receives financial support from AGC Research Collaboration System with the title “Research on the control of biocompatibility based on the analysis of substrate surface”. The other Topic Editors declare no competing interests

Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry

Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry PDF Author: Izabella Brand
Publisher: Springer Nature
ISBN: 3030421643
Category : Science
Languages : en
Pages : 129

Book Description
This book describes the physical basis of polarization modulation infrared reflection-absorption spectroscopy and its application in electrochemical studies. It provides a concise yet comprehensive review of the research done in this field in the last 20 years. Electrochemical methods are used to determine the rate and mechanism of charge transfer reactions between an electrode and species adsorbed or diffusing to its surface. In the past two decades PM-IRRAS has grown to be one of the most important vibrational spectroscopy techniques applied to investigate structural changes taking place at the electrochemical interface. The monograph presents foundations of this technique and reviews in situ studies of redox-inactive and redox-active films adsorbed on electrode surfaces. It also discusses experimental conditions required in electrochemical and spectroscopic studies and presents practical solutions to perform efficient experiments. As such, it offers an invaluable resource for graduate and postgraduate students, as well as for all researchers in academic and industrial laboratories.

In-situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis

In-situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis PDF Author: Shi-Gang Sun
Publisher: Elsevier
ISBN: 0080489060
Category : Science
Languages : en
Pages : 559

Book Description
In-Situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis is a new reference on in-situ spectroscopic techniques/applications, fundamentals of electrocatalysis at molecule level, and progresses within electrochemical surface science. Presenting both essential background knowledge at graduate level and original research within the fields of spectroscopy, electrochemistry, and surface science. Featuring 15 chapters by prominent worldwide scholars, based on their recent progress in different aspects of in-situ spectroscopy studies, this book will appeal to a wide audience of scientists. In summary this book is highly suitable for graduates learning basic concepts and advanced applications of in-situ spectroscopy, electrocatalysis and electrode adsorptions.* Written by the most active scientists in the fields of spectroscopy, electrochemistry and surface science* Essential background knowledge for graduate students* A modern reference of cutting-edge scientific research

Electrified Interfaces in Physics, Chemistry and Biology

Electrified Interfaces in Physics, Chemistry and Biology PDF Author: R Guidelli
Publisher: Springer Science & Business Media
ISBN: 940112566X
Category : Science
Languages : en
Pages : 604

Book Description
Electrified interfaces span from metaVsemiconductor and metaVelectrolyte interfaces to disperse systems and biological membranes, and are notably important in so many physical, chemical and biological systems that their study has been tackled by researchers with different scientific backgrounds using different methodological approaches. The various electrified interfaces have several common features. The equilibrium distribution of positive and negative ions in an electrolytic solution is governed by the same Poisson-Boltzmann equation independent of whether the solution comes into contact with a metal, a colloidal particle or a biomembrane, and the same is true for the equilibrium distribution of free electrons and holes of a semiconductor in contact with a different conducting phase. Evaluation of electric potential differences across biomembranes is based on the same identity of electrochemical potentials which holds for a glass electrode and which yields the Nernst equation when applied to a metal/solution interface. The theory of thermally activated electron tunneling, which was developed by Marcus, Levich, Dogonadze and others to account for electron transfer across metaVelectrolyte interfaces, is also applied to light induced charge separation and proton translocation reactions across intercellular membranes. From an experimental viewpoint, the same electrochemical and in situ spectroscopic techniques can equally well be employed for the study of apparently quite different electrified interfaces.

Handbook of Infrared Spectroscopy of Ultrathin Films

Handbook of Infrared Spectroscopy of Ultrathin Films PDF Author: Valeri P. Tolstoy
Publisher: John Wiley & Sons
ISBN: 0471461830
Category : Technology & Engineering
Languages : en
Pages : 710

Book Description
Because of the rapid increase in commercially available Fouriertransform infrared spectrometers and computers over the past tenyears, it has now become feasible to use IR spectrometry tocharacterize very thin films at extended interfaces. At the sametime, interest in thin films has grown tremendously because ofapplications in microelectronics, sensors, catalysis, andnanotechnology. The Handbook of Infrared Spectroscopy of UltrathinFilms provides a practical guide to experimental methods,up-to-date theory, and considerable reference data, critical forscientists who want to measure and interpret IR spectra ofultrathin films. This authoritative volume also: Offers informationneeded to effectively apply IR spectroscopy to the analysis andevaluation of thin and ultrathin films on flat and rough surfacesand on powders at solid-gaseous, solid-liquid, liquid-gaseous,liquid-liquid, and solid-solid interfaces. Provides full discussion of theory underlying techniques Describes experimental methods in detail, including optimumconditions for recording spectra and the interpretation ofspectra Gives detailed information on equipment, accessories, andtechniques Provides IR spectroscopic data tables as appendixes, includingthe first compilation of published data on longitudinal frequenciesof different substances Covers new approaches, such as Surface Enhanced IR spectroscopy(SEIR), time-resolved FTIR spectroscopy, high-resolutionmicrospectroscopy and using synchotron radiation

Diffraction and Spectroscopic Methods in Electrochemistry

Diffraction and Spectroscopic Methods in Electrochemistry PDF Author: Richard C. Alkire
Publisher: John Wiley & Sons
ISBN: 9783527313174
Category : Science
Languages : en
Pages : 456

Book Description
This ninth volume in the series concentrates on in situ spectroscopic methods and combines a balanced mixture of theory and applications, making it highly readable for chemists and physicists, as well as for materials scientists and engineers. As with the previous volumes, all the chapters continue the high standards of this series, containing numerous references to further reading and the original literature, for easy access to this new field. The editors have succeeded in selecting highly topical areas of research and in presenting authors who are leaders in their fields, covering such diverse topics as diffraction studies of the electrode-solution interface, thin organic films at electrode surfaces, linear and non-linear spectroscopy as well as sum frequency generation studies of the electrified solid-solution interface, plus quantitative SNIFTIRS and PM-IRRAS. Special attention is paid to recent advances and developments, which are critically and thoroughly discussed. The result is a compelling set of reviews, serving equally well as an excellent and up-to-date source of information for experienced researchers in the field, as well as as an introduction for newcomers.