Uranium Isotope Measurements by Quadrupole ICP-MS for Process Monitoring of Enrichment PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Uranium Isotope Measurements by Quadrupole ICP-MS for Process Monitoring of Enrichment PDF full book. Access full book title Uranium Isotope Measurements by Quadrupole ICP-MS for Process Monitoring of Enrichment by RN. Bolin. Download full books in PDF and EPUB format.
Author: RN. Bolin Publisher: ISBN: Category : Isotope ratio Languages : en Pages : 13
Book Description
Historically, uranium isotopic ratio measurements in the nuclear industry have been performed using Thermal Ionization Mass Spectrometry (TIMS); primarily due to the high level of precision that can be achieved. TIMS analysis, however, requires sample purification and intricate sample loading. Quadrupole (low resolution, single detector) inductively coupled plasma -- mass spectrometry, Q-ICP-MS, overcomes these disadvantages and is a cost-effective alternative, i.e., in terms of initial capital, maintenance, and operating costs. This paper presents a simple, single standard approach for measuring uranium isotope content in various solid and liquid nuclear materials along with some comparison data of Q-ICP-MS and TIMS. Intensity ratios of 234U, 235U, 236U, and 238U to total U intensity are produced, providing the enrichment level or percent 235U. A detailed description of the instrument and data collection parameters is also provided. Optimal precision and accuracy are achieved through the use of a single standard which is closely matched to the enrichment and concentration of the samples. Depending upon the standard chosen, enrichments between depleted and 97% can be quantified. Standard deviations for the major uranium isotopes are typically within 0.02 absolute and at least an order of magnitude lower for the minor U isotope abundances.
Author: RN. Bolin Publisher: ISBN: Category : Isotope ratio Languages : en Pages : 13
Book Description
Historically, uranium isotopic ratio measurements in the nuclear industry have been performed using Thermal Ionization Mass Spectrometry (TIMS); primarily due to the high level of precision that can be achieved. TIMS analysis, however, requires sample purification and intricate sample loading. Quadrupole (low resolution, single detector) inductively coupled plasma -- mass spectrometry, Q-ICP-MS, overcomes these disadvantages and is a cost-effective alternative, i.e., in terms of initial capital, maintenance, and operating costs. This paper presents a simple, single standard approach for measuring uranium isotope content in various solid and liquid nuclear materials along with some comparison data of Q-ICP-MS and TIMS. Intensity ratios of 234U, 235U, 236U, and 238U to total U intensity are produced, providing the enrichment level or percent 235U. A detailed description of the instrument and data collection parameters is also provided. Optimal precision and accuracy are achieved through the use of a single standard which is closely matched to the enrichment and concentration of the samples. Depending upon the standard chosen, enrichments between depleted and 97% can be quantified. Standard deviations for the major uranium isotopes are typically within 0.02 absolute and at least an order of magnitude lower for the minor U isotope abundances.
Author: Roy W. Morrow Publisher: ASTM International ISBN: 0803124961 Category : Inductively coupled plasma mass spectrometry Languages : en Pages : 153
Author: T. Hodgson Publisher: ISBN: Category : Analysis of uranium hexafluoride Languages : en Pages : 6
Book Description
An inductively coupled plasma-multiple collector-mass spectrometer (ICP-MC-MS) has been used to measure the isotopic composition of uranium in three solutions of uranium hexafluoride. The 235U: 238U ratio of each sample solution ranged from approximately 0.007 to 0.03 to 1.0. The measurements are linear over this range and the precision and accuracy are comparable, if not superior, to that obtained by thermal ionization mass spectrometry (TIMS). However, acceptable isotopic ratio measurement of uranium hexafluoride solutions is not possible by TIMS because the presence of fluoride ions severely limits analytical precision. Hence, the fluoride must be removed prior to analysis. This necessitates a chemical purification stage which adds both time and expense to the measurement process. This study reports direct, high precision, accurate uranium isotope ratio measurements on solutions of uranium hexafluoride. The instrumental time required for the analysis of 15 uranium samples with the ICP-MC-MS totals 135 min. This compares with an estimated time requirement of 600 min by TIMS and a time of 900 min by UF6 gas mass spectrometry.
Author: Sabine Becker Publisher: John Wiley & Sons ISBN: 9780470517208 Category : Science Languages : en Pages : 514
Book Description
Providing an exhaustive review of this topic, Inorganic Mass Spectrometry: Principles and Applications provides details on all aspects of inorganic mass spectrometry, from a historical overview of the topic to the principles and functions of mass separation and ion detection systems. Offering a comprehensive treatment of inorganic mass spectrometry, topics covered include: Recent developments in instrumentation Developing analytical techniques for measurements of trace and ultratrace impurities in different materials This broad textbook in inorganic mass spectrometry, presents the most important mass spectrometric techniques used in all fields of analytical chemistry. By covering recent developments and advances in all fields of inorganic mass spectrometry, this text provides researchers and students with information to answer any questions on this topic as well as providing the basic fundamentals for understanding this potentially complex, but increasingly relevant subject.
Author: Publisher: ISBN: Category : Languages : en Pages : 18
Book Description
This report describes a standardized methodology used by researchers from the Center for Accelerator Mass Spectrometry (CAMS) (Energy and Environment Directorate) and the Environmental Radiochemistry Group (Chemistry and Materials Science Directorate) at the Lawrence Livermore National Laboratory (LLNL) for the full isotopic analysis of uranium from solution. The methodology has largely been developed for use in characterizing the uranium composition of selected nuclear materials but may also be applicable to environmental studies and assessments of public, military or occupational exposures to uranium using in-vitro bioassay monitoring techniques. Uranium isotope concentrations and isotopic ratios are measured using a combination of Multi Collector Inductively Coupled Plasma Mass Spectrometry (MC ICP-MS), Accelerator Mass Spectrometry (AMS) and Alpha Spectrometry.
Author: G. Bárdossy Publisher: Elsevier ISBN: 0444597530 Category : Nature Languages : en Pages : 450
Book Description
Karst Bauxites: Bauxite Deposits on Carbonate Rocks presents a comparison of bauxite regions using mathematical statistics methods. This book is divided into eight chapters that highlight the quantitative processing and assessment of the information available for bauxites. The opening chapters present observational and analytical evidence concerning karst bauxite, with particular emphasis on Hungarian bauxite deposits. The typical features of bauxites are analyzed from a variety of aspects and results from different bauxite regions are compared. Other chapters consider the feature of metamorphosed karst bauxites. The remaining chapters discuss the conditions of formation of karst bauxites and with the factors controlling their geographic and stratigraphic distribution. This book will prove useful to geologists, mineralogists, and researchers.
Author: RN. Bolin
Author: RN. Bolin
Author: V. L. Warren
Author: Roy W. Morrow
Author: V. L. Warren
Author: T. Hodgson
Author: Sabine Becker
Author: D. E. Fornwalt
Author: J. Ignacio Garcia Alonso
Author: 
Author: G. Bárdossy