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Proton Transfer Reaction Mass Spectrometry

Proton Transfer Reaction Mass Spectrometry PDF Author: Andrew M. Ellis
Publisher: John Wiley & Sons
ISBN: 1118683579
Category : Science
Languages : en
Pages : 361

Book Description
Proton Transfer Reaction Mass Spectrometry (PTR-MS) is a rapidly growing analytical technique for detecting and identifying very small quantities of chemical compounds in air. It has seen widespread use in atmospheric monitoring and food science and shows increasing promise in applications such as industrial process monitoring, medical science and in crime and security scenarios. Written by leading researchers, this is the first book devoted to PTR-MS and it provides a comprehensive account of the basic principles, the experimental technique and various applications, thus making this book essential reading for researchers, technicians, postgraduate students and professionals in industry. The book contains nine chapters and is divided into two parts. The first part describes the underlying principles of the PTR-MS technique, including • the relevant ion-molecule chemistry • thermodynamics and reaction kinetics • a discussion of ion sources, drift tubes and mass spectrometers • practical aspects of PTR-MS, including calibration. The second part of the book turns its attention to some of the many applications of PTR-MS, demonstrating the scope and benefits, as well as the limitations, of the technique. The chapters that make up the second part of the book build upon the material presented in the first part and are essentially self-contained reviews focusing on the following topics: • environmental science • food science • medicine • homeland security, and • applications of PTR-MS in liquid analysis.

Proton Transfer Reaction Mass Spectrometry

Proton Transfer Reaction Mass Spectrometry PDF Author: Andrew M. Ellis
Publisher: John Wiley & Sons
ISBN: 1118683579
Category : Science
Languages : en
Pages : 361

Book Description
Proton Transfer Reaction Mass Spectrometry (PTR-MS) is a rapidly growing analytical technique for detecting and identifying very small quantities of chemical compounds in air. It has seen widespread use in atmospheric monitoring and food science and shows increasing promise in applications such as industrial process monitoring, medical science and in crime and security scenarios. Written by leading researchers, this is the first book devoted to PTR-MS and it provides a comprehensive account of the basic principles, the experimental technique and various applications, thus making this book essential reading for researchers, technicians, postgraduate students and professionals in industry. The book contains nine chapters and is divided into two parts. The first part describes the underlying principles of the PTR-MS technique, including • the relevant ion-molecule chemistry • thermodynamics and reaction kinetics • a discussion of ion sources, drift tubes and mass spectrometers • practical aspects of PTR-MS, including calibration. The second part of the book turns its attention to some of the many applications of PTR-MS, demonstrating the scope and benefits, as well as the limitations, of the technique. The chapters that make up the second part of the book build upon the material presented in the first part and are essentially self-contained reviews focusing on the following topics: • environmental science • food science • medicine • homeland security, and • applications of PTR-MS in liquid analysis.

Photodissociation Dynamics

Photodissociation Dynamics PDF Author: Reinhard Schinke
Publisher: Cambridge University Press
ISBN: 9780521484145
Category : Science
Languages : en
Pages : 446

Book Description
Photodissociation induced by the absorption of single photons permits the detailed study of molecular dynamics such as the breaking of bonds, internal energy transfer and radiationless transitions. The availability of powerful lasers operating over a wide frequency range has stimulated rapid development of new experimental techniques which make it possible to analyse photodissociation processes in unprecedented detail. This text elucidates the achievements in calculating photodissociation cross-sections and fragment state distributions from first principles, starting from multi-dimensional potential energy surfaces and the Schrödinger equation of nuclear motion. Following an extended introduction in which the various types of observables are outlined, the book summarises the basic theoretical tools, namely the time-independent and the time-dependent quantum mechanical approaches as well as the classical picture of photodissociation. The discussions of absorption spectra, diffuse vibrational structures, the vibrational and rotational state distributions of the photofragments form the core of the book. More specific topics such as the dissociation of vibrationally excited molecules, emission during dissociation, or nonadiabatic effects are also discussed. It will be of interest to graduate students and senior scientists working in molecular physics, spectroscopy, molecular collisions and molecular kinetics.

Proton-Transfer Reactions

Proton-Transfer Reactions PDF Author: E. F. Caldin
Publisher: Springer
ISBN: 1489930132
Category : Science
Languages : en
Pages : 446

Book Description


Kinetics of Ion-Molecule Reactions

Kinetics of Ion-Molecule Reactions PDF Author: Pierre J. Ausloos
Publisher: Springer Science & Business Media
ISBN: 1461329310
Category : Science
Languages : en
Pages : 507

Book Description
The investigation of the elementary reactions of reactive intermediate species began about half a centruy ago with the advent of free radical kinetics as an active area of chemical research. In spite of the relatively greater ease of detection of a species carrying an electrical charge, and the fact that organic chemists had for decades postulated mechanisms involving ionic intermediates, the systematic study of the elementary reactions of ions was delayed for more than twenty years after the first beginnings of free radical kinetics. Even at this writing, in 1978, the word "kinetics" is considered by many chemists to be synomomous with "kinetics of neutral species". Yet in spite of the relatively late start and separation from the mainstream of kinetics, the field of ion physics and chemistry is fluorishing, and growing at an ever faster pace. Instrumentalists devise ever more sophisticated apparatuses with capabilities of delving into nearly every aspect of the interactions between ions and molecules. Even satellites orbiting the earth are now being used effectively to determine rate coefficients of ionospheric ion-neutral reactions, some of which can not as yet be measured in the laboratory.

Frontier Orbitals and Reaction Paths

Frontier Orbitals and Reaction Paths PDF Author: Kenichi Fukui
Publisher: World Scientific
ISBN: 9810222416
Category : Science
Languages : en
Pages : 563

Book Description
This book is a collection of selected papers on the Frontier Orbital Theory by Nobel prizewinner Kenichi Fukui (Chemistry 1981), with introductory notes. It provides the basic concept and formulation of the theory, and the physical and chemical significance of the frontier orbital interactions in chemistry, together with many practical applications. The formulation of the Intrinsic Reaction Coordinate and applications to some simple systems are also presented. The aim of this volume is to show by what forces chemical reactions are driven and to demonstrate how the regio- and stereo-selectivities are determined in chemical reactions. Students and senior investigators will gain insight into the nature of chemical reactions and find out how quantum chemical calculations are connected with chemical intuition.

Isaiah Shavitt

Isaiah Shavitt PDF Author: Ron Shepard
Publisher: Springer
ISBN: 3662481480
Category : Science
Languages : en
Pages : 346

Book Description
In this Festschrift dedicated to the late Isaiah Shavitt (1925-2012) , selected researchers in theoretical chemistry present research highlights on major developments in the field. Originally published in the journal Theoretical Chemistry Accounts, these outstanding contributions are now available in a hardcover print format, as well as a special electronic edition. This volume provides valuable content for all researchers in theoretical chemistry, and will especially benefit those research groups and libraries with limited access to the journal.

Proton Transfer Reactions in Dihydrogen Bonded Systems

Proton Transfer Reactions in Dihydrogen Bonded Systems PDF Author: Simona Marincean
Publisher:
ISBN:
Category : Hydrogen bonding
Languages : en
Pages : 238

Book Description


Organic Reaction Mechanisms 1995

Organic Reaction Mechanisms 1995 PDF Author: A. C. Knipe
Publisher: John Wiley & Sons
ISBN: 0470865458
Category : Science
Languages : en
Pages : 622

Book Description
The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1995 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1995. The 31st annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.

Reaction Dynamics in Clusters and Condensed Phases

Reaction Dynamics in Clusters and Condensed Phases PDF Author: Joshua Jortner
Publisher: Springer Science & Business Media
ISBN: 9401107866
Category : Science
Languages : en
Pages : 562

Book Description
The Twenty Sixth Jerusalem Symposium reflected the high standards of these distinguished scientific meetings, which convene once a year at the Israel Academy of Sciences and Humanities in Jerusalem to discuss a specific topic in the broad area of quantum chemistry and biochemistry. The topic at this year's Jerusalem Symposium was reaction dynamics in clusters and condensed phases, which constitutes a truly interdisciplinary subject of central interest in the areas of chemical dynamics, kinetics, photochemistry and condensed matter chemical physics. The main theme of the Symposium was built around the exploration of the interrelationship between the dynamics in large finite clusters and in infinite bulk systems. The main issues addressed microscopic and macroscopic sol vation phenomena, cluster and bulk spectroscopy, photodissociation and vibrational predissociation, cage effects, interphase dynamics, reaction dynamics and energy transfer in clusters, dense fluids, liquids, solids and biophysical systems. The interdisciplinary nature of this research area was deliberated by intensive and extensive interactions between modern theory and advanced experimental methods. This volume provides a record of the invited lectures at the Symposium.

State Selected and State-to-State Ion-Molecule Reaction Dynamics, Volume 82, Part 2

State Selected and State-to-State Ion-Molecule Reaction Dynamics, Volume 82, Part 2 PDF Author: Michael Baer
Publisher: John Wiley & Sons
ISBN: 047014193X
Category : Science
Languages : en
Pages : 578

Book Description
The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.