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Author: Ingmar Grenthe Publisher: Elsevier Science & Technology ISBN: Category : Science Languages : en Pages : 744
Book Description
This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.
Author: Ingmar Grenthe Publisher: Elsevier Science & Technology ISBN: Category : Science Languages : en Pages : 744
Book Description
This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.
Author: Robert J. Lemire Publisher: Elsevier ISBN: 9780444503794 Category : Medical Languages : en Pages : 876
Book Description
Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.
Author: J.A. Rard Publisher: North Holland ISBN: Category : Science Languages : en Pages : 578
Book Description
This volume in the series Chemical Thermodynamics provides a comprehensive review and critical evaluation of experimental data available for the chemical thermodynamics of inorganic compounds and aqueous species and complexes of technetium. The objective of the reviews in the series Chemical Thermodynamics is to provide a set of reliable thermodynamic data that can be used to describe the behaviour of the elements reviewed under conditions relevant for radioactive waste disposal systems and various geochemical environments. Data and their uncertainty limits are recommended for the formation energies, enthalpies and entropies of selected aqueous complexes, solids and gaseous compounds containing technetium. The data are internally consistent and compatible with the CODATA Key Values, as well as with the data in the earlier volumes in the series Chemical Thermodynamics. The book contains a detailed discussion of the selection procedures used
Author: R.C. Newton Publisher: Springer Science & Business Media ISBN: 1461258715 Category : Science Languages : en Pages : 312
Book Description
Today large numbers of geoscientists apply thermodynamic theory to solu tions of a variety of problems in earth and planetary sciences. For most problems in chemistry, the application of thermodynamics is direct and rewarding. Geoscientists, however, deal with complex inorganic and organic substances. The complexities in the nature of mineralogical substances arise due to their involved crystal structure and multicomponental character. As a result, thermochemical solutions of many geological-planetological problems should be attempted only with a clear understanding of the crystal-chemical and thermochemical character of each mineral. The subject of physical geochemistry deals with the elucidation and application of physico-chemical principles to geosciences. Thermodynamics of mineral phases and crystalline solutions form an integral part of it. Developments in mineralogic thermody namics in recent years have been very encouraging, but do not easily reach many geoscientists interested mainly in applications. This series is to provide geoscientists and planetary scientists with current information on the develop ments in thermodynamics of mineral systems, and also provide the active researcher in this rapidly developing field with a forum through which he can popularize the important conclusions of his work. In the first several volumes, we plan to publish original contributions (with an abundant supply of back ground material for the uninitiated reader) and thoughtful reviews from a number of researchers on mineralogic thermodynamics, on the application of thermochemistry to planetary phase equilibria (including meteorites), and on kinetics of geochemical reactions.
Author: M.E. Minas da Piedade Publisher: Springer ISBN: 9780792357414 Category : Science Languages : en Pages : 0
Book Description
Covers the major experimental and theoretical methods currently used to study the energetics of stable molecules and reactive intermediates. Reviews the ate of the art and shows the interplay of experimental and theoretical methods used to probe bonding energetics and reactivity and a wide range of chemical species. A modern and invaluable introduction to the study of molecular energetics. A reference for workers currently involved in the field.
Author: Ingmar Grenthe
Author: Ingmar Grenthe
Author: Robert J. Lemire
Author: OECD Nuclear Energy Agency
Author: Irving Myron Klotz
Author: J.A. Rard
Author: 
Author: R.C. Newton
Author: L. B. Pankratz
Author: M.E. Minas da Piedade
Author: M. H. Rand