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Thermodynamic Equilibrium and Stability of Materials

Thermodynamic Equilibrium and Stability of Materials PDF Author: Long-Qing Chen
Publisher: Springer Nature
ISBN: 9811386919
Category : Science
Languages : en
Pages : 464

Book Description
This is a textbook on thermodynamics of materials for junior/senior undergraduate students and first-year graduate students as well as a reference book for researchers who would like to refresh their understanding of thermodynamics. The textbook employs a plain language to explain the thermodynamic concepts and quantities. It embraces the mathematical beauty and rigor of Gibbs thermodynamics through the fundamental equation of thermodynamics from which all thermodynamic properties of a material can be derived. However, a reader with basic first-year undergraduate calculus skills will be able to get through the book without difficulty. One unique feature of this textbook is the descriptions of the step-by-step procedures for computing all the thermodynamic properties from the fundamental equation of thermodynamics and all the thermodynamic energies from a set of common, experimentally measurable thermodynamic properties, supplemented with ample numerical examples. Another unique feature of this textbook is its emphasis on the concept of chemical potential and its applications to phase equilibria in single component systems and binary solutions, chemical reaction equilibria, and lattice and electronic defects in crystals. The concept of chemical potential is introduced at the very beginning of the book together with temperature and pressure. It avoids or minimizes the use of terms such as molar Gibbs free energy, partial molar Gibbs free energy, or Gibbs potential because molar Gibbs free energy or partial molar Gibbs free energy is precisely the chemical potential of a material or a component. It is the chemical potential that determines the stability of chemical species, compounds, and phases and their tendency to chemically react to form new species, transform to new physical state, and migrate from one spatial location to another. Therefore, it is the chemical potential differences or gradients that drive essentially all materials processes of interest. A reader after finishing reading the book is expected to not only achieve a high-level fundamental understanding of thermodynamics but also acquire the analytical skills of applying thermodynamics to determining materials equilibrium and driving forces for materials processes.

Thermodynamic Equilibrium and Stability of Materials

Thermodynamic Equilibrium and Stability of Materials PDF Author: Long-Qing Chen
Publisher: Springer Nature
ISBN: 9811386919
Category : Science
Languages : en
Pages : 464

Book Description
This is a textbook on thermodynamics of materials for junior/senior undergraduate students and first-year graduate students as well as a reference book for researchers who would like to refresh their understanding of thermodynamics. The textbook employs a plain language to explain the thermodynamic concepts and quantities. It embraces the mathematical beauty and rigor of Gibbs thermodynamics through the fundamental equation of thermodynamics from which all thermodynamic properties of a material can be derived. However, a reader with basic first-year undergraduate calculus skills will be able to get through the book without difficulty. One unique feature of this textbook is the descriptions of the step-by-step procedures for computing all the thermodynamic properties from the fundamental equation of thermodynamics and all the thermodynamic energies from a set of common, experimentally measurable thermodynamic properties, supplemented with ample numerical examples. Another unique feature of this textbook is its emphasis on the concept of chemical potential and its applications to phase equilibria in single component systems and binary solutions, chemical reaction equilibria, and lattice and electronic defects in crystals. The concept of chemical potential is introduced at the very beginning of the book together with temperature and pressure. It avoids or minimizes the use of terms such as molar Gibbs free energy, partial molar Gibbs free energy, or Gibbs potential because molar Gibbs free energy or partial molar Gibbs free energy is precisely the chemical potential of a material or a component. It is the chemical potential that determines the stability of chemical species, compounds, and phases and their tendency to chemically react to form new species, transform to new physical state, and migrate from one spatial location to another. Therefore, it is the chemical potential differences or gradients that drive essentially all materials processes of interest. A reader after finishing reading the book is expected to not only achieve a high-level fundamental understanding of thermodynamics but also acquire the analytical skills of applying thermodynamics to determining materials equilibrium and driving forces for materials processes.

Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis

Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis PDF Author: V. Parmon
Publisher: Elsevier
ISBN: 0080931960
Category : Technology & Engineering
Languages : en
Pages : 340

Book Description
Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis consists of materials adapted from lectures on the thermodynamics of nonequilibrium processes that have been taught at the Department of Natural Sciences of Novosibirsk State University since 1995. The thermodynamics of nonequilibrium processes traditionally required students to have a strong background in physics. However, the materials featured in this volume allow anyone with knowledge in classical thermodynamics of equilibrium processes and traditional chemical kinetics to understand the subject. Topics discussed include systems in the thermodynamics of irreversible processes; thermodynamics of systems that are close to and far from equilibrium; thermodynamics of catalysts; the application of nonequilibrium thermodynamics to material science; and the relationship between entropy and information. This book will be helpful for research into complex chemical transformations, particularly catalytic transformations. - Applies simple approaches of non-equilibrium thermodynamics to analyzing properties of chemically reactive systems - Covers systems far from equilibrium, allowing the consideration of most chemically reactive systems of a chemical or biological nature - This approach resolves many complicated problems in the teaching of chemical kinetics

Computational Thermodynamics of Materials

Computational Thermodynamics of Materials PDF Author: Zi-Kui Liu
Publisher: Cambridge University Press
ISBN: 0521198968
Category : Science
Languages : en
Pages : 261

Book Description
Integrates fundamental concepts with experimental data and practical applications, including worked examples and end-of-chapter problems.

Thermodynamics in Materials Science

Thermodynamics in Materials Science PDF Author: Robert DeHoff
Publisher: CRC Press
ISBN: 1420005855
Category : Science
Languages : en
Pages : 606

Book Description
Thermodynamics in Materials Science, Second Edition is a clear presentation of how thermodynamic data is used to predict the behavior of a wide range of materials, a crucial component in the decision-making process for many materials science and engineering applications. This primary textbook accentuates the integration of principles, strategies, a

Phase Equilibria, Phase Diagrams and Phase Transformations

Phase Equilibria, Phase Diagrams and Phase Transformations PDF Author: Mats Hillert
Publisher: Cambridge University Press
ISBN: 1139465864
Category : Technology & Engineering
Languages : en
Pages : 525

Book Description
Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.

Thermodynamic Equilibrium and Stability of Materials

Thermodynamic Equilibrium and Stability of Materials PDF Author: Long-Qing Chen
Publisher: Springer
ISBN: 9789811386909
Category : Science
Languages : en
Pages : 455

Book Description
This is a textbook on thermodynamics of materials for junior/senior undergraduate students and first-year graduate students as well as a reference book for researchers who would like to refresh their understanding of thermodynamics. The textbook employs a plain language to explain the thermodynamic concepts and quantities. It embraces the mathematical beauty and rigor of Gibbs thermodynamics through the fundamental equation of thermodynamics from which all thermodynamic properties of a material can be derived. However, a reader with basic first-year undergraduate calculus skills will be able to get through the book without difficulty. One unique feature of this textbook is the descriptions of the step-by-step procedures for computing all the thermodynamic properties from the fundamental equation of thermodynamics and all the thermodynamic energies from a set of common, experimentally measurable thermodynamic properties, supplemented with ample numerical examples. Another unique feature of this textbook is its emphasis on the concept of chemical potential and its applications to phase equilibria in single component systems and binary solutions, chemical reaction equilibria, and lattice and electronic defects in crystals. The concept of chemical potential is introduced at the very beginning of the book together with temperature and pressure. It avoids or minimizes the use of terms such as molar Gibbs free energy, partial molar Gibbs free energy, or Gibbs potential because molar Gibbs free energy or partial molar Gibbs free energy is precisely the chemical potential of a material or a component. It is the chemical potential that determines the stability of chemical species, compounds, and phases and their tendency to chemically react to form new species, transform to new physical state, and migrate from one spatial location to another. Therefore, it is the chemical potential differences or gradients that drive essentially all materials processes of interest. A reader after finishing reading the book is expected to not only achieve a high-level fundamental understanding of thermodynamics but also acquire the analytical skills of applying thermodynamics to determining materials equilibrium and driving forces for materials processes.

Thermodynamics

Thermodynamics PDF Author: Reinhard Hentschke
Publisher: Springer Science & Business Media
ISBN: 3642367119
Category : Science
Languages : en
Pages : 308

Book Description
The structure of this text is simple and transparent, enabling the easy mapping of the text onto a one-semester course syllabus and the attendant study. There are 8 chapters total and one three-part appendix. Throughout the text the student finds numerous examples (solved problems) reaching from cosmic to molecular evolution or from cloud formation to Bose condensation.

Advanced Thermodynamics for Engineers

Advanced Thermodynamics for Engineers PDF Author: D. Winterbone
Publisher: Butterworth-Heinemann
ISBN: 0080523366
Category : Science
Languages : en
Pages : 399

Book Description
Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.

Modern Thermodynamics

Modern Thermodynamics PDF Author: Dilip Kondepudi
Publisher: John Wiley & Sons
ISBN: 111837181X
Category : Science
Languages : en
Pages : 550

Book Description
Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition presents a comprehensive introduction to 20th century thermodynamics that can be applied to both equilibrium and non-equilibrium systems, unifying what was traditionally divided into ‘thermodynamics’ and ‘kinetics’ into one theory of irreversible processes. This comprehensive text, suitable for introductory as well as advanced courses on thermodynamics, has been widely used by chemists, physicists, engineers and geologists. Fully revised and expanded, this new edition includes the following updates and features: Includes a completely new chapter on Principles of Statistical Thermodynamics. Presents new material on solar and wind energy flows and energy flows of interest to engineering. Covers new material on self-organization in non-equilibrium systems and the thermodynamics of small systems. Highlights a wide range of applications relevant to students across physical sciences and engineering courses. Introduces students to computational methods using updated Mathematica codes. Includes problem sets to help the reader understand and apply the principles introduced throughout the text. Solutions to exercises and supplementary lecture material provided online at http://sites.google.com/site/modernthermodynamics/. Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition is an essential resource for undergraduate and graduate students taking a course in thermodynamics.

Chemical Thermodynamics

Chemical Thermodynamics PDF Author: W.J. Rankin
Publisher: CRC Press
ISBN: 1000703169
Category : Science
Languages : en
Pages : 345

Book Description
This book develops the theory of chemical thermodynamics from first principles, demonstrates its relevance across scientific and engineering disciplines, and shows how thermodynamics can be used as a practical tool for understanding natural phenomena and developing and improving technologies and products. Concepts such as internal energy, enthalpy, entropy, and Gibbs energy are explained using ideas and experiences familiar to students, and realistic examples are given so the usefulness and pervasiveness of thermodynamics becomes apparent. The worked examples illustrate key ideas and demonstrate important types of calculations, and the problems at the end of chapters are designed to reinforce important concepts and show the broad range of applications. Most can be solved using digitized data from open access databases and a spreadsheet. Answers are provided for the numerical problems. A particular theme of the book is the calculation of the equilibrium composition of systems, both reactive and non-reactive, and this includes the principles of Gibbs energy minimization. The overall approach leads to the intelligent use of thermodynamic software packages but, while these are discussed and their use demonstrated, they are not the focus of the book, the aim being to provide the necessary foundations. Another unique aspect is the inclusion of three applications chapters: heat and energy aspects of processing; the thermodynamics of metal production and recycling; and applications of electrochemistry. This book is aimed primarily at students of chemistry, chemical engineering, applied science, materials science, and metallurgy, though it will be also useful for students undertaking courses in geology and environmental science. A solutions manual is available for instructors.