Thermodynamic Data on Oxides and Silicates

Thermodynamic Data on Oxides and Silicates PDF Author: Surendra K. Saxena
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 444

Book Description
During the last thirty years profound developments in expe- rimental techniques to measure high temperature and pressu- res and thermodynamic properties of minerals have occurred. This technical development has been matched by an increased sophistication in applying theoretical methods to obtain new data or improve the quality of existing data. Using these newtechniques, Assessed Thermodynamic Data on Oxides and Silicates represents the successful attempt of the authors to develop an internally systematized data base which satis- fies the constraints of calorimetric measurements, phase equilibrium data, measured thermophysical properties of a phase, and heat capacities and entropies estimated from lat- tice vibrational models.

Solid Solutions in Silicate and Oxide systems

Solid Solutions in Silicate and Oxide systems PDF Author: C.A. Geiger
Publisher: The Mineralogical Society of Great Britain and Ireland
ISBN: 9634631347
Category : Science
Languages : en
Pages : 410

Book Description


High-Temperature Chemistry of Silicates and Other Oxide Systems / Vysokotemperaturnaya Khimiya Silikatnykh I Drugikh Okisnykh Sistem / Bьicoкotemпepatуphaя Xиmия Cиликathьix И Дpугиx Oкиchьix | Cиctem

High-Temperature Chemistry of Silicates and Other Oxide Systems / Vysokotemperaturnaya Khimiya Silikatnykh I Drugikh Okisnykh Sistem / Bьicoкotemпepatуphaя Xиmия Cиликathьix И Дpугиx Oкиchьix | Cиctem PDF Author: N. A. Toropov
Publisher: Springer Science & Business Media
ISBN: 1468472097
Category : Science
Languages : en
Pages : 221

Book Description
The ever-increasing importance of chemical reactions at high and superhigh temperatures in crystalline, amorphous, and semicrystalline SOlids, as well as the reactions of these solids with gases, prompted the authors of this book to examine critically the literature available in this field and to present a general review of the subject. In this monograph we discuss those chemical and physicochemical points which we consider to be most important for solving a series of problems in the preparation and use of new inorganic materials. We hope that this book will be of interest to the many specialists working on inorganic materials. N. A. Toropov PREFACE Modem technology demands ever more materials with high mechanical strength, heat and chemical re sistance, fire resistance, special electrical properties, particular behavior toward active radiations, etc. The search for such materials requires the study of various chemical compounds, metallic alloys, and other fused in organic systems, especially oxide systems. Materials based on oxides begin to assume increasing importance in many fields of the new technology. In this connection the investigation of oxides and systems consisting of two and more oxides is expanding greatly.

High-Pressure Silicates and Oxides

High-Pressure Silicates and Oxides PDF Author: Masaki Akaogi
Publisher: Springer Nature
ISBN: 9811963630
Category : Science
Languages : en
Pages : 215

Book Description
This book presents a summary of high-pressure phase transitions of minerals and related inorganic compounds. The first part reviews the methods to investigate phase transitions by direct high-pressure and high-temperature experiments together with thermodynamic approaches that consist of calorimetric measurements and thermodynamic calculation. In the second part, phase relations and thermodynamic properties of olivine, pyroxene, garnet, spinel, perovskite, rutile, and related inorganic compounds with A2BO4, ABO3, AB2O4, and AO2 stoichiometries are described. Particular emphasis is placed on spinel- and perovskite-structured phases and their high-pressure polymorphs called post-spinel and post-perovskite phases. The last part of the book focuses on phase relations of mantle rocks and on natural high-pressure minerals from the Earth’s deep mantle and in shocked meteorites.

Structure, Dynamics, and Properties of Silicate Melts

Structure, Dynamics, and Properties of Silicate Melts PDF Author: Jonathan F. Stebbins
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 1501509381
Category : Science
Languages : en
Pages : 632

Book Description
Volume 32 of Reviews in Mineralogy introduces the basic concepts of melt physics and relaxation theory as applied to silicate melts, then to describe the current state of experimental and computer simulation techniques for exploring the detailed atomic structure and dynamic processes which occur at high temperature, and finally to consider the relationships between melt structure, thermodynamic properties and rheology within these liquids. These fundamental relations serve to bridge the extrapolation from often highly simplified melt compositions studied in the laboratory to the multicomponent systems found in nature. This volume focuses on the properties of simple model silicate systems, which are usually volatile-free. The behavior of natural magmas has been summarized in a previous Short Course volume (Nicholls and Russell, editors, 1990: Reviews in Mineralogy, Vol. 24), and the effect of volatiles on magmatic properties in yet another (Carroll and Holloway, editors, 1994: Vol. 30). The Mineralogical Society of America sponsored a short course for which this was the text at Stanford University December 9 and 10, 1995, preceding the Fall Meeting of the American Geophysical Union and MSA in San Fransisco, with about 100 professionals and graduate students in attendance.

Thermodynamic Data

Thermodynamic Data PDF Author: Surendra K. Saxena
Publisher: Springer Science & Business Media
ISBN: 1461228425
Category : Science
Languages : en
Pages : 380

Book Description
With the rapid development of fast processors, the power of a mini-super computer now exists in a lap-top box. Quite sophisticated techniques are be coming accessible to geoscientists, thus making disciplinary boundaries fade. Chemists and physicists are no longer shying away from computational mineral ogical and material science problems "too complicated to handle." Geoscientists are willing to delve into quantitative physico-chemical methods and open those "black boxes" they had shunned for several decades but with which had learned to live. I am proud to present yet another volume in this series which is designed to break the disciplinary boundaries and bring the geoscientists closer to their chemist and physicist colleagues in achieving a common goal. This volume is the result of an international collaboration among many physical geochemists (chemists, physicists, and geologists) aiming to understand the nature of material. The book has one common theme: namely, how to determine quantitatively through theory the physico-chemical parameters of the state of a solid or fluid.

The Structure and Properties of Oxide Melts

The Structure and Properties of Oxide Melts PDF Author: Yoshio Waseda
Publisher: World Scientific
ISBN: 9789810233174
Category : Technology & Engineering
Languages : en
Pages : 252

Book Description
This book represents an extended introductory treatise on the atomic scale structure and physicochemical properties of oxide melts, mainly of silicates, from both the basic science and the applied engineering points of view. This helpful volume covers current experimental information on the structure of oxide melts and glasses and a convenient outline of their various physicochemical properties, including the subject "how structural data can be correlated with their macroscopic properties". This book also includes a fundamental introduction to the beneficial utilization of waste oxides largely produced from metal production in the world. This will be very useful for people working in the field of metallurgy and environmental science. Along with more than 300 references, numerous illustrations and tables, this is a unique source of information and guidance for specialists and non-specialists alike.

Thermodynamics of Silicates

Thermodynamics of Silicates PDF Author: V. Babuškin
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 488

Book Description
The intensification of the production of silicate materials and products makes a de tailed theoretical study of the processes underlying their manufacture and service more and more urgent. The thermodynamic method is of great importance for studying chemical reac tions of silicate technology. Together with a study of the rate and mechanism of sub stance transfer, it permits obtaining necessary data for the efficient operation of technological processes. The progress of science in recent years has solved numerous problems in the field of the physical chemistry of silicates. The great progress in deciphering silicate structures, and working out methods of the synthesis of minerals and studying their properties must be mentioned. New methods of determining thermic constants have appeared. In future these methods should be more widely used for determining the heats of the silicate forma tion and related compounds in crystalline and vitreous state. This concerns in par ticular the system - CaO - Ab03 - Fe203 - Si0 - H 0 -which is of great impor 2 2 tance for the technology of cement and concrete, ceramics, refractories and glass.

Chemical Thermodynamics of Zirconium

Chemical Thermodynamics of Zirconium PDF Author:
Publisher: Elsevier
ISBN: 0080457533
Category : Science
Languages : en
Pages : 545

Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.* Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.

Thermodynamics in Earth and Planetary Sciences

Thermodynamics in Earth and Planetary Sciences PDF Author: Jibamitra Ganguly
Publisher: Springer Nature
ISBN: 3030208796
Category : Science
Languages : en
Pages : 629

Book Description
Based on a university course, this book provides an exposition of a large spectrum of geological, geochemical and geophysical problems that are amenable to thermodynamic analysis. It also includes selected problems in planetary sciences, relationships between thermodynamics and microscopic properties, particle size effects, methods of approximation of thermodynamic properties of minerals, and some kinetic ramifications of entropy production. The textbook will enable graduate students and researchers alike to develop an appreciation of the fundamental principles of thermodynamics, and their wide ranging applications to natural processes and systems.