The Thermochemical Properties of Uranium Compounds PDF Download

Author: M. H. Rand
Publisher:
ISBN:
Category : Thermochemistry
Languages : en
Pages : 116

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Author: Ingmar Grenthe
Publisher: Elsevier Science & Technology
ISBN:
Category : Science
Languages : en
Pages : 744

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Book Description
This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.

Author: I. Barin
Publisher: Springer Science & Business Media
ISBN: 3662022931
Category : Science
Languages : en
Pages : 950

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Book Description
For the practical application of thermochemistry to the development and control of tech nical processes, the data for as many substances as possible are needed in conjunction with rapid and simple methods of calculating equilibrium constants, heat balances and the EMF of galvanic cells. For these three types of calculation the following three ther modynamic functions are suitable: The Planck function, the enthalpy and the Gibbs free energy, which are here defined and tabulated as unambigous functions of temperature for pure substances. The first edition of the tables was published in 1973 under the title "Thermochemical Properties of Inorganic Substances". The present supplementary volume contains the data and functions for a further 800 inorganic substances. In addition, the data for about 250 substances from the first volume have been up-dated. These usually small corrections produce better consistency with the data from more recent publications. The comments of users and reviewers of the first volume have largely been concerned with the difference between the present thermodynamic functions and the system used in the JANAF tables, the somewhat unconventional handling of heat balances adopted here, the notation of cell reactions, the description of non-stoichiometric phases and the accuracy of the tabulated data. To answer these questions and criticims the theore tical concepts and the practical use of the tables are dealt with in more detail in the introduction, following the recommendation of some reviewers.

Author: R. Guillaumont
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 976

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Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency, and updates and expands the thermodynamic data on inorganic compounds and complexes of uranium, neptunium, plutonium, americium and technetium contained in the previous volumes of the series. A review team, composed of seven internationally recognized experts, has critically reviewed during five years all the scientific literature containing chemical thermodynamic information for the above mentioned systems that has appeared since the publication of the earlier volumes. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains new tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.

Author:
Publisher: Elsevier
ISBN: 0080457533
Category : Science
Languages : en
Pages : 545

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Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.* Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.

Author:
Publisher:
ISBN:
Category : Physical instruments
Languages : en
Pages : 208

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Author: International Atomic Energy Agency
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 122

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Author:
Publisher:
ISBN:
Category : Weights and measures
Languages : en
Pages : 684

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Book Description

Author: Gesina C. Carter
Publisher:
ISBN:
Category : Alloys
Languages : en
Pages : 204

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Book Description
The Alloy Data Center, part of the National Standard Reference Data System, has two primary functions. One is to stimulate cooperation and coordination among the existing data centers in the area of the physical properties of well characterized alloys. The final data generated by these centers for publication should be consistent with one another where correlation or possible overlap exists. The other purpose is the collection (from publications as well as private communications), evaluation, and publication of data in some areas where special competence exists in the Alloy Physics Section. Of interest to the center are metals, semimetals, intermetallic compounds, and alloys. Excluded are those materials which have ill-defined constitutions and heat treatments. An automated system was developed to meet the bibliographic needs of the center. This system will be described as well as the specific properties of interest. The system presently contains a complete annotated file dealing with NMR Knight shift measurements. The soft X-ray spectroscopy compilation is being kept up-to-date with the same system. (Author).

Author: Hans U. Borgstedt
Publisher: Springer Science & Business Media
ISBN: 3662056712
Category : Science
Languages : en
Pages : 354

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Book Description
Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups III and IV. The description of uranium and its compounds, for which the Gmelin Institute has started a series of volumes supplementing the main volume of 1936, follows in its arrangement closely the order chosen for the transuranium volumes. Part A treats "The Element", Part B "The Metal and its Alloys", Part C "The Compounds", Part D "The Chemistry in Solution", and finally Part E "The Coordination Compounds". Part E, "The Coordination Compounds" comprises two volumes which already have been finished and are available - completely written in English. Series A comprises 7 volumes which are all available. Series C will comprise 14 volumes of which only volume 6 is missing. Series D consists of 4 volumes dealing with the chemistry in solution, which already have been finished and are available. The present volume describes the alloys and the intermetallic compounds with the metals of main groups I to IV - those systems with semimetals such as boron and germanium are to be found in corresponding volumes in Uranium C series. In the volume B 2 main emphasis is given to the binary systems. The most frequently investigated systems are uranium-beryllium and uranium-aluminium because of their special scientific (U-Be) and technological (U-Al) importance.