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Author: Isabelle Catto Publisher: Oxford University Press ISBN: 9780198501619 Category : Mathematics Languages : en Pages : 300
Book Description
The thermodynamic limit is a mathematical technique for modeling crystals or other macroscopic objects by considering them as infinite periodic arrays of molecules. The technique allows models in solid state physics to be derived directly from models in quantum chemistry. This book presents new results, many previously unpublished, for a large class of models and provides a survey of the mathematics of thermodynamic limit problems. The authors both work closely with Fields Medal-winner Pierre-Louis Lion, and the book will be a valuable tool for applied mathematicians and mathematical physicists studying nonlinear partial differential equations.
Author: Isabelle Catto Publisher: Oxford University Press ISBN: 9780198501619 Category : Mathematics Languages : en Pages : 300
Book Description
The thermodynamic limit is a mathematical technique for modeling crystals or other macroscopic objects by considering them as infinite periodic arrays of molecules. The technique allows models in solid state physics to be derived directly from models in quantum chemistry. This book presents new results, many previously unpublished, for a large class of models and provides a survey of the mathematics of thermodynamic limit problems. The authors both work closely with Fields Medal-winner Pierre-Louis Lion, and the book will be a valuable tool for applied mathematicians and mathematical physicists studying nonlinear partial differential equations.
Author: David Ruelle Publisher: Cambridge University Press ISBN: 9781139455282 Category : Science Languages : en Pages : 198
Book Description
Reissued in the Cambridge Mathematical Library this classic book outlines the theory of thermodynamic formalism which was developed to describe the properties of certain physical systems consisting of a large number of subunits. It is aimed at mathematicians interested in ergodic theory, topological dynamics, constructive quantum field theory, the study of certain differentiable dynamical systems, notably Anosov diffeomorphisms and flows. It is also of interest to theoretical physicists concerned with the conceptual basis of equilibrium statistical mechanics. The level of the presentation is generally advanced, the objective being to provide an efficient research tool and a text for use in graduate teaching. Background material on mathematics has been collected in appendices to help the reader. Extra material is given in the form of updates of problems that were open at the original time of writing and as a new preface specially written for this new edition by the author.
Author: Bernard H. Lavenda Publisher: Courier Dover Publications ISBN: 0486839842 Category : Science Languages : en Pages : 225
Book Description
This book develops in detail the statistical foundations of nonequilibrium thermodynamics, based on the mathematical theory of Brownian motion. Author Bernard H. Lavenda demonstrates that thermodynamic criteria emerge in the limit of small thermal fluctuations and in the Gaussian limit where means and modes of the distribution coincide. His treatment assumes the theory of Brownian motion to be a general and practical model of irreversible processes that are inevitably influenced by random thermal fluctuations. This unifying approach permits the extraction of widely applicable principles from the analysis of specific models. Arranged by argument rather than theory, the text is based on the premises that random thermal fluctuations play a decisive role in governing the evolution of nonequilibrium thermodynamic processes and that they can be viewed as a dynamic superposition of many random events. Intended for nonmathematicians working in the areas of nonequilibrium thermodynamics and statistical mechanics, this book will also be of interest to chemical physicists, condensed matter physicists, and readers in the area of nonlinear optics.
Author: Luigi Accardi Publisher: Springer Science & Business Media ISBN: 3662049295 Category : Science Languages : en Pages : 485
Book Description
Well suited as a textbook in the emerging field of stochastic limit, which is a new mathematical technique developed for solving nonlinear problems in quantum theory.
Author: Sacha Friedli Publisher: Cambridge University Press ISBN: 1107184827 Category : Mathematics Languages : en Pages : 643
Book Description
A self-contained, mathematical introduction to the driving ideas in equilibrium statistical mechanics, studying important models in detail.
Author: Colin J. Thompson Publisher: Princeton University Press ISBN: 1400868688 Category : Science Languages : en Pages : 289
Book Description
While most introductions to statistical mechanics are either too mathematical or too physical, Colin Thompson's book combines mathematical rigor with familiar physical materials. Following introductory chapters on kinetic theory, thermodynamics, the Gibbs ensembles, and the thermodynamic limit, later chapters discuss the classical theories of phase transitions, the Ising model, algebraic methods and combinatorial methods for solving the two-dimensional model in zero field, and some applications of the Ising model to biology. Originally published in 1979. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
Author: Eric Cancès Publisher: Springer Nature ISBN: 3031223403 Category : Mathematics Languages : en Pages : 595
Book Description
Density functional theory (DFT) provides the most widely used models for simulating molecules and materials based on the fundamental laws of quantum mechanics. It plays a central role in a huge spectrum of applications in chemistry, physics, and materials science.Quantum mechanics describes a system of N interacting particles in the physical 3-dimensional space by a partial differential equation in 3N spatial variables. The standard numerical methods thus incur an exponential increase of computational effort with N, a phenomenon known as the curse of dimensionality; in practice these methods already fail beyond N=2. DFT overcomes this problem by 1) reformulating the N-body problem involving functions of 3N variables in terms of the density, a function of 3 variables, 2) approximating it by a pioneering hybrid approach which keeps important ab initio contributions and re-models the remainder in a data-driven way. This book intends to be an accessible, yet state-of-art text on DFT for graduate students and researchers in applied and computational mathematics, physics, chemistry, and materials science. It introduces and reviews the main models of DFT, covering their derivation and mathematical properties, numerical treatment, and applications.
Author: D.Ya. Petrina Publisher: CRC Press ISBN: 9780415273541 Category : Science Languages : en Pages : 352
Book Description
This monograph considers systems of infinite number of particles, in particular the justification of the procedure of thermodynamic limit transition. The authors discuss the equilibrium and non-equilibrium states of infinite classical statistical systems. Those states are defined in terms of stationary and nonstationary solutions to the Bogolyubov equations for the sequences of correlation functions in the thermodynamic limit. This is the first detailed investigation of the thermodynamic limit for non-equilibrium systems and of the states of infinite systems in the cases of both canonical and grand canonical ensembles, for which the thermodynamic equivalence is proved. A comprehensive survey of results is also included; it concerns the properties of correlation functions for infinite systems and the corresponding equations. For this new edition, the authors have made changes to reflect the development of theory in the last ten years. They have also simplified certain sections, presenting them more systematically, and greatly increased the number of references. The book is aimed at theoretical physicists and mathematicians and will also be of use to students and postgraduate students in the field.