The Effects of Internal Stress and Lithium Transport on Fracture in Storage Materials in Lithium-Ion Batteries PDF Download
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Author: Klinsmann, Markus Publisher: KIT Scientific Publishing ISBN: 3731504553 Category : Technology (General) Languages : en Pages : 246
Book Description
Fracture of storage particles is considered to be one of the major reasons for capacity fade and increasing power loss in Li-ion batteries. In this work, we tackle the problem by merging a coupled model of mechanical stress and diffusion of Li-ions with a phase field description of an evolving crack. The novel approach allows us to study the evolution of the Li concentration together with the initiation and growth of a crack in an arbitrary geometry and without presuming a specific crack path.
Author: Klinsmann, Markus Publisher: KIT Scientific Publishing ISBN: 3731504553 Category : Technology (General) Languages : en Pages : 246
Book Description
Fracture of storage particles is considered to be one of the major reasons for capacity fade and increasing power loss in Li-ion batteries. In this work, we tackle the problem by merging a coupled model of mechanical stress and diffusion of Li-ions with a phase field description of an evolving crack. The novel approach allows us to study the evolution of the Li concentration together with the initiation and growth of a crack in an arbitrary geometry and without presuming a specific crack path.
Author: Markus Klinsmann Publisher: ISBN: 9781013282676 Category : Science Languages : en Pages : 234
Book Description
Fracture of storage particles is considered to be one of the major reasons for capacity fade and increasing power loss in Li-ion batteries. In this work, we tackle the problem by merging a coupled model of mechanical stress and diffusion of Li-ions with a phase field description of an evolving crack. The novel approach allows us to study the evolution of the Li concentration together with the initiation and growth of a crack in an arbitrary geometry and without presuming a specific crack path. This work was published by Saint Philip Street Press pursuant to a Creative Commons license permitting commercial use. All rights not granted by the work's license are retained by the author or authors.
Author: Birkholz, Oleg Publisher: KIT Scientific Publishing ISBN: 373151172X Category : Science Languages : en Pages : 246
Book Description
Hierarchically structured active materials in electrodes of lithium-ion cells are promising candidates for increasing gravimetric energy density and improving rate capability of the system. To investigate the influence of cathode structures on the performance of the whole cell, efficient tools for calculating effective transport properties of granular systems are developed and their influence on the electrochemical performance is investigated in specially adapted cell models.
Author: Zhang, Tao Publisher: KIT Scientific Publishing ISBN: 3731510022 Category : Technology & Engineering Languages : en Pages : 224
Book Description
Most storage materials exhibit phase changes, which cause stresses and, thus, lead to damage of the electrode particles. In this work, a phase-field model for the cathode material NaxFePO4 of Na-ion batteries is studied to understand phase changes and stress evolution. Furthermore, we study the particle size and SOC dependent miscibility gap of the nanoscale insertion materials. Finally, we introduce the nonlocal species concentration theory, and show how the nonlocality influences the results.
Author: Schwark, Tabea Gisela Publisher: KIT Scientific Publishing ISBN: 3731507595 Category : Grinding and polishing Languages : en Pages : 178
Book Description
Soft Magnetic Composites (SMCs) typically consist of large iron particles coated with a fairly thin inorganic layer. The combination of soft particles with a brittle layer causes, however, a rather poor mechanical behaviour of the SMCs. The particle boundaries of the specific SMC Somaloy 700 3P can be classified into four different types according to the complexity of their layers. Tests on both micro- and macroscale showed that the particle-boundary interface is critical in terms of failure.
Author: Straub, Thomas Publisher: KIT Scientific Publishing ISBN: 3731504715 Category : Technology (General) Languages : en Pages : 234
Book Description
This book investigates the fatigue mechanisms and crack initiation of Ni, Al and Cu on a small-scale in the Very High Cycle Fatigue regime by means of innovative fatigue experimentation. A novel custom-built resonant fatigue setup showed that the sample resonant frequency changes with increasing cycle number due to fatigue damage. Mechanisms such as slip band formation have been observed. Cyclic hardening, vacancy and oxidation formation may be considered as early fatigue mechanisms.
Author: Ganser, Markus Publisher: KIT Scientific Publishing ISBN: 3731510472 Category : Technology & Engineering Languages : en Pages : 272
Book Description
Solid state batteries with a lithium metal electrode are considered the next generation of high energy battery technology. Unfortunately, lithium metal is prone to harmful protrusion or dendrite growth which causes dangerous cell failure. Within this work the problem of protrusion growth is tackled by deriving a novel electro-chemo-mechanical theory tailored for binary solid state batteries which is then used to discuss the impact of mechanics on interface stability by numerical studies.
Author: Wobrock, Mark Publisher: KIT Scientific Publishing ISBN: 3731506823 Category : Diffraction Languages : en Pages : 252
Book Description
Single crystalline, μm-sized cantilevers are fabricated out of epitaxially grown Ag thin films by a lithography-based procedure and are deflected by a nanoindenter system. The microstructure of the plastically deformed cantile-vers is investigated using transmission Kikuchi diffraction (TKD) on the cantilever cross section. 3D discrete dislocation dynamics simulations (DDD) are performed for further analysis. A mechanism to explain the formation of dislocation networks upon loading is suggested.
Author: Zhang, Kuo Publisher: KIT Scientific Publishing ISBN: 3731505037 Category : Technology (General) Languages : en Pages : 224
Book Description
In this work, the ratcheting-behavior of 9%Cr-1%Mo ferritic-martensitic steel is studied with uniaxial cyclic loading. To describe the ratcheting-behavior of this steel, a visco-plastic constitutive model with consideration of cyclic softening of Reduced Activation Ferritic Martensitic steels is further modified, based on the analysis of back stress.
Author: Klinsmann, Markus
Author: Klinsmann, Markus
Author: Markus Klinsmann
Author: Birkholz, Oleg
Author: Zhang, Tao
Author: Schwark, Tabea Gisela
Author: Straub, Thomas
Author: Ganser, Markus
Author: Kumar, Amritesh
Author: Wobrock, Mark
Author: Zhang, Kuo