Tandem Organic Reactions

Tandem Organic Reactions PDF Author: Tse-Lok Ho
Publisher: John Wiley & Sons
ISBN: 9780471570226
Category : Science
Languages : en
Pages : 516

Book Description
The importance of tandem reactions is evident--besides their pragmatic value, they have an aesthetic appeal. The author presents a survey of these reactions that will rivet the attention of numerous chemists to their merits and utility as well as stimulate design and discovery of new sets of tandem reactions. Coverage includes Aldol condensation, Michael Reaction, Dieckmann cyclization, thermal and free radical processes, stitching reactions and much more.

Organic Reactions, Volume 60

Organic Reactions, Volume 60 PDF Author: Larry E. Overman
Publisher: John Wiley & Sons
ISBN: 0471235814
Category : Science
Languages : en
Pages : 579

Book Description
Organic Reactions is a comprehensive series devoted to important synthetic reactions, each volume having wide applicability. Each chapter focuses on a single reaction or a definitive phase of a reaction, and each is written by world-renowned chemists with extensive hands-on experience in their specialties. The material is presented from a preparative point of view, and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each reaction includes information about its conditions, products, and yields, where available, and is fully referenced to the primary literature. The authors also include detailed procedures illustrating the significant modifications of the chemical reaction, as well as tables featuring all pertinent data about the reaction. Volume 60 contains two chapters: "Epoxide Migration (Payne Rearrangement) and Related Reactions," by Robert M. Hanson, and "The Intramolecular Heck Reaction," by J.T. Link. The most comprehensive and highly focused treatment of important organic reactions currently available, this series represents an important addition to chemistry libraries in both academic and industrial settings, and is a valuable resource for both students and professionals in the field.

Domino Reactions in Organic Synthesis

Domino Reactions in Organic Synthesis PDF Author: Lutz F. Tietze
Publisher: John Wiley & Sons
ISBN: 3527608680
Category : Science
Languages : en
Pages : 631

Book Description
Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates- a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type - an approach for an efficiant, economically benificial and ecological benign synthesis. A definite must for every organic chemist.

Reactive Intermediates in Organic Chemistry

Reactive Intermediates in Organic Chemistry PDF Author: Maya Shankar Singh
Publisher: John Wiley & Sons
ISBN: 3527678271
Category : Science
Languages : en
Pages : 362

Book Description
Most reactions in organic chemistry do not proceed in a single step but rather take several steps to yield the desired product. In the course of these multi-step reaction sequences, short-lived intermediates can be generated that quickly convert into other intermediates, reactants, products or side products. As these intermediates are highly reactive, they cannot usually be isolated, but their existence and structure can be proved by theoretical and experimental methods. Using the information obtained, researchers can better understand the underlying reaction mechanism of a certain organic transformation and thus develop novel strategies for efficient organic synthesis. The chapters are clearly structured and are arranged according to the type of intermediate, providing information on the formation, characterization, stereochemistry, stability, and reactivity of the intermediates. Additionally, representative examples and a problem section with different levels of difficulty are included for self-testing the newly acquired knowledge. By providing a deeper understanding of the underlying concepts, this is a musthave reference for PhD and Master Students in organic chemistry, as well as a valuable source of information for chemists in academia and industry working in the field. It is also ideal as primary or supplementary reading for courses on organic chemistry, physical organic chemistry or analytical chemistry.

Organic Reactions, Volume 111

Organic Reactions, Volume 111 PDF Author: P. Andrew Evans
Publisher: John Wiley & Sons
ISBN: 1119982235
Category : Science
Languages : en
Pages : 837

Book Description
The 111th volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular steps of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method. Volume contents: RING-OPENING REACTIONS OF EPOXIDES WITH TITANIUM(III) REAGENTS T. V. (Babu) RajanBabu, William A. Nugent, and Sandipan Halder REDUCTIVE CYCLIZATION OF 2-NITRO- AND β-NITROSTYRENES, 2-NITROBIPHENYLS, AND 1-NITRO-1,3-DIENES TO INDOLES, CARBAZOLES, AND PYRROLES Björn C. G. Söderberg and William F. Berkowitz

Organic Reactions, Volume 89

Organic Reactions, Volume 89 PDF Author:
Publisher: John Wiley & Sons
ISBN: 1119211212
Category : Science
Languages : en
Pages : 1354

Book Description
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Rhodium Catalyzed Hydroformylation

Rhodium Catalyzed Hydroformylation PDF Author: Piet W.N.M. van Leeuwen
Publisher: Springer Science & Business Media
ISBN: 0306469472
Category : Science
Languages : en
Pages : 291

Book Description
In the last decade there have been numerous advances in the area of rhodium-catalyzed hydroformylation, such as highly selective catalysts of industrial importance, new insights into mechanisms of the reaction, very selective asymmetric catalysts, in situ characterization and application to organic synthesis. The views on hydroformylation which still prevail in the current textbooks have become obsolete in several respects. Therefore, it was felt timely to collect these advances in a book. The book contains a series of chapters discussing several rhodium systems arranged according to ligand type, including asymmetric ligands, a chapter on applications in organic chemistry, a chapter on modern processes and separations, and a chapter on catalyst preparation and laboratory techniques. This book concentrates on highlights, rather than a concise review mentioning all articles in just one line. The book aims at an audience of advanced students, experts in the field, and scientists from related fields. The didactic approach also makes it useful as a guide for an advanced course.

Green Organic Reactions

Green Organic Reactions PDF Author: Gopinathan Anilkumar
Publisher: Springer Nature
ISBN: 9813368977
Category : Technology & Engineering
Languages : en
Pages : 349

Book Description
This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.

Stereochemistry and Organic Reactions

Stereochemistry and Organic Reactions PDF Author: Dipak Kumar Mandal
Publisher: Academic Press
ISBN: 0128240938
Category : Science
Languages : en
Pages : 640

Book Description
Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. - Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes - Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs - Features novel rules and mnemonics to delineate product stereochemistry - Includes up-to-date coverage with over 1300 selective references

Organic Reaction Mechanisms 2014

Organic Reaction Mechanisms 2014 PDF Author: A. C. Knipe
Publisher: John Wiley & Sons
ISBN: 1118941799
Category : Science
Languages : en
Pages : 1023

Book Description
Organic Reaction Mechanisms 2014, the 50th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2014. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. This volume includes a 5-year cumulative index.