Synthesis and Characterisation of Non-fullerene Small Molecule Acceptor for Organic Photovoltaics PDF Download

Author: Joshua Yuk Lin Lai
Publisher:
ISBN:
Category :
Languages : en
Pages : 120

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Author: Sarah Holliday
Publisher: Springer
ISBN: 3319770918
Category : Technology & Engineering
Languages : en
Pages : 119

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Book Description
This book reports on the design, synthesis and characterization of new small molecule electron acceptors for polymer solar cells. Starting with a detailed introduction to the science behind polymer solar cells, the author then goes on to review the challenges and advances made in developing non-fullerene acceptors so far. In the main body of the book, the author describes the design principles and synthetic strategy for a new family of acceptors, including detailed synthetic procedures and molecular modeling data used to predict physical properties. An indepth characterization of the photovoltaic performance, with transient absorption spectroscopy (TAS), photo-induced charge extraction, and grazing incidence X-ray diffraction (GIXRD) is also included, and the author uses this data to relate material properties and device performance. This book provides a useful overview for researchers beginning a project in this or related areas.

Author: Sarah Magaret Geneste Holliday
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Author: Man Hong Andy Cheung
Publisher:
ISBN:
Category : Fullerene polymers
Languages : en
Pages : 74

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Author: Neelima Kumari
Publisher: Mohammed Abdul Malik
ISBN:
Category : Science
Languages : en
Pages : 0

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Book Description
"Synthesis of Organic Electron Acceptors for Photovoltaics" by Neelima Kumari is an informative and insightful book that focuses on the development and evaluation of novel organic small molecule-based electron acceptors for use in organic photovoltaic applications. The book presents a comprehensive overview of the strategies that have been developed for the synthesis of these materials, as well as their properties and potential applications in photovoltaic devices. The book covers a range of topics, including the design and synthesis of new electron acceptors, the characterization of their properties, and their performance in organic photovoltaic devices. The author, Neelima Kumari, is a renowned researcher in the field of materials science, with extensive experience in the synthesis and evaluation of new materials for photovoltaic applications. The book is written in a clear and concise manner, making it accessible to readers from a range of backgrounds, including students, researchers, and professionals in the fields of materials science, chemistry, and physics. The author provides expert insights and practical guidance on the use of organic electron acceptors in photovoltaic devices, which can enable researchers to develop more efficient and cost-effective solar cells. Overall, "Synthesis of Organic Electron Acceptors for Photovoltaics" is an essential read for anyone interested in the development of new materials for photovoltaic applications. The book provides a comprehensive overview of the current state-of-the-art in this rapidly evolving field, and will be a valuable resource for researchers working in academia, industry, and government. The author's insights and guidance on the synthesis and evaluation of new organic electron acceptors will be of particular interest to researchers working in the field of organic photovoltaics.

Author: Inamuddin
Publisher: John Wiley & Sons
ISBN: 1119724708
Category : Science
Languages : en
Pages : 578

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Book Description
Solar cells are semiconductor devices that convert light photons into electricity in photovoltaic energy conversion and can help to overcome the global energy crisis. Solar cells have many applications including remote area power systems, earth-orbiting satellites, wristwatches, water pumping, photodetectors and remote radiotelephones. Solar cell technology is economically feasible for commercial-scale power generation. While commercial solar cells exhibit good performance and stability, still researchers are looking at many ways to improve the performance and cost of solar cells via modulating the fundamental properties of semiconductors. Solar cell technology is the key to a clean energy future. Solar cells directly harvest energy from the sun’s light radiation into electricity are in an ever-growing demand for future global energy production. Solar cell-based energy harvesting has attracted worldwide attention for their notable features, such as cheap renewable technology, scalable, lightweight, flexibility, versatility, no greenhouse gas emission, environment, and economy friendly and operational costs are quite low compared to other forms of power generation. Thus, solar cell technology is at the forefront of renewable energy technologies which are used in telecommunications, power plants, small devices to satellites. Aiming at large-scale implementation can be manipulated by various types used in solar cell design and exploration of new materials towards improving performance and reducing cost. Therefore, in-depth knowledge about solar cell design is fundamental for those who wish to apply this knowledge and understanding in industries and academics. This book provides a comprehensive overview on solar cells and explores the history to evolution and present scenarios of solar cell design, classification, properties, various semiconductor materials, thin films, wafer-scale, transparent solar cells, and so on. It also includes solar cells’ characterization analytical tools, theoretical modeling, practices to enhance conversion efficiencies, applications and patents.

Author: Xiaomei Ding
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
Molecular design and synthesis play critical roles in the development of organic semiconductors for organic photovoltaics (OPVs). This dissertation describes the design, synthesis, and characterization of three classes of organic semiconductors for OPVs: p-type semiconducting polymers, n-type semiconducting polymers, and non-fullerene small molecule acceptors. The relative merits of alternative building blocks and design strategies for organic semiconductors are investigated. Complex factors governing the underlying structure-property-processing-performance relationships are discussed in detail. The fundamentals of organic semiconductors and organic solar cells, state-of-the-art materials and devices, and challenges in the design and synthesis of materials are reviewed in Chapter 1. Chapter 2 discusses the strategy of selenophene substitution as a potential method to improve photovoltaic performance of the regular thiophene-based p-type semiconducting polymers. New selenophene-containing polymers were synthesized based on a widely used polymer, PBDB-T, where the original thiophene units at various side chain and backbone positions were substituted with selenophene. This study revealed the intramolecular and intermolecular interactions related with selenophene substitution, thus provided important guidelines in designing selenophene-containing polymers. Chapter 3 presents a comparative study of the alternating naphthalene diimide-thiophene copolymer, PNDIT-hd, and naphthalene diimide-selenophene copolymer, PNDIS-hd. The effects of selenophene substitution on the intrinsic and photovoltaic blend properties of n-type semiconducting naphthalene diimide-arylene copolymers with simple donor−acceptor architecture were investigated. This study demonstrated multiple advantages of selenophene substitution including enhancing light harvesting, formation of favorable morphology, and reducing charge recombination losses in all-polymer solar cell devices. Towards enhancing the intrinsic stability of small molecule acceptors, novel tridecacyclic ladder structure was designed and realized via Friedlander condensation reactions. The tridecacyclic ladder molecule acceptors (LMAs) described in Chapter 4 combined good solubility with enhanced stabilities and high photovoltaic performance. One of the new LMAs, LTX-4Cl, demonstrated a high PCE of 11.5% with high fill factor of 0.75. This study also unraveled the significant impact of side chains and halogenations on the molecular packing characteristics of the LMAs and the resulted photovoltaic performance. Finally, the results of the above studies are summarized in Chapter 5 and an outlook is given for future development of organic semiconductors and the organic photovoltaic technology.

Author: Jon-Paul Sun
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
In recent decades the demand for low-cost and sustainable energy sources has fueled the growth of photovoltaic research. Among the various photovoltaic technologies, organic semiconductors offer a light-weight and inherently-flexible solution that can be fabricated in a roll-to-roll process, significantly reducing fabrication and installation costs. Additionally, due to their transparent nature a number of previously unutilized architectural surfaces such as windows, building facades, and vehicle panels can be employed for energy production. Among solution-processed organic photovoltaics, fullerenes have dominated as the highest performing electron acceptor materials. However, their low absorption in the solar spectrum and high-energy synthesis is undesirable. Non-fullerene acceptors have the potential for low-cost synthesis while providing complementary absorption to the donor material, enhancing photocurrent. This dissertation presents the design, characterization, and integration into solar cells of novel non-fullerene acceptors. A family of related push-pull chromophores with phthalimide or naphthalimide end-groups, as well as perylene diimide-based acceptors were characterized using a combination of ultraviolet-visible absorption spectroscopy and ultraviolet photoemission spectroscopy. The acceptor molecules were integrated into thin-film transistors to measure field-effect mobilities. Solution-processed bulk heterojunction photovoltaic devices were fabricated and characterized using atomic force microscopy and by measuring current density-voltage curves and external quantum efficiencies while under illumination. The best performing devices achieved power conversion efficiencies of 5.5 %, where overall performance was limited by domain sizes in the blend films. Difficulties in forming nanoscale domain sizes in blend films are presented and discussed. A low-cost nanoembossing technique utilizing anodized aluminum oxide templates is presented to address the associated challenges with bulk heterojunctions. Initial results show that small-molecule acceptor films can be nanostructured prior to donor material deposition. This presents a viable method for fabricating large-area modules with predetermined nanoscale domain sizes, that is compatible with roll-to-roll processing.

Author: Obum Kwon
Publisher:
ISBN: 9781303539312
Category :
Languages : en
Pages : 134

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Book Description
Solar energy harvested directly from sunlight using photovoltaic (PV) technology has become one of the most promising ways to meet growing global energy needs with a sustainable resource while minimizing environmental concerns. Especially, organic bulk heterojunction (BHJ) solar cells have been attracting a great deal of interest as a source of renewable energy because of their potential as low-cost, flexible, light-weight and large-scale devices. The choice of materials in a BHJ solar cell is very important for device performance because the power conversion efficiencies (PCEs) are determined by their some crucial characteristics such as energy levels, charge transfer mobilities and structural orders. In this dissertation, two carbazole-diketopyrrolopyrrole based conjugated polymers (P1 and P2) and three thieno-[3,4-c]pyrrole-4,6-dione (TPD) based small molecules (M1, SM1 and SM2) were synthesized and characterized to investigate their optical, electrical and photovoltaic properties. First, the substitution of alkyl and aryl side chains on the carbazole moiety of two push-pull conjugated polymers (P1 and P2) shows the significant differences in the optical, electrical and photovoltaic properties. Second, TPD-based conjugated small molecule with a donor-acceptor-donor-acceptor-donor (D-A-D-A-D) framework, M1 shows the relatively deep HOMO level resulting the relatively high Voc.(0.85 eV) Small molecule BHJ solar cells were fabricated and characterized using different M1:PC71BM blend ratios, solvents, and additives and the highest PCE achieved in this study was 1.86%. Lastly, different bridgehead atoms of SM1 and SM2 can affect their energy band levels and device performances. The PCE (2.5%) of the SM2-based SM-BHJ solar cell was higher than that of the SM1-based SM-BHJ solar cell (1.5%).

Author: Yongfang Li
Publisher: Springer
ISBN: 3319168622
Category : Technology & Engineering
Languages : en
Pages : 402

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Book Description
This volume reviews the latest trends in organic optoelectronic materials. Each comprehensive chapter allows graduate students and newcomers to the field to grasp the basics, whilst also ensuring that they have the most up-to-date overview of the latest research. Topics include: organic conductors and semiconductors; conducting polymers and conjugated polymer semiconductors, as well as their applications in organic field-effect-transistors; organic light-emitting diodes; and organic photovoltaics and transparent conducting electrodes. The molecular structures, synthesis methods, physicochemical and optoelectronic properties of the organic optoelectronic materials are also introduced and described in detail. The authors also elucidate the structures and working mechanisms of organic optoelectronic devices and outline fundamental scientific problems and future research directions. This volume is invaluable to all those interested in organic optoelectronic materials.