Strain Tuning of Electronic Structure in Bi4Ti3O12-LaCoO3 Epitaxial Thin Films PDF Download
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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
In this study, we investigated the crystal and electronic structures of ferroelectric Bi4Ti3O12 single-crystalline thin films site-specifically substituted with LaCoO3 (LCO). The epitaxial films were grown by pulsed laser epitaxy on NdGaO3 and SrTiO3 substrates to vary the degree of strain. With increasing the LCO substitution, we observed a systematic increase in the c-axis lattice constant of the Aurivillius phase related with the modification of pseudo-orthorhombic unit cells. These compositional and structural changes resulted in a systematic decrease in the band gap, i.e., the optical transition energy between the oxygen 2p and transition-metal 3d states, based on a spectroscopic ellipsometry study. In particular, the Co 3d state seems to largely overlap with the Ti t2g state, decreasing the band gap. Interestingly, the applied tensile strain facilitates the band-gap narrowing, demonstrating that epitaxial strain is a useful tool to tune the electronic structure of ferroelectric transition-metal oxides.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
In this study, we investigated the crystal and electronic structures of ferroelectric Bi4Ti3O12 single-crystalline thin films site-specifically substituted with LaCoO3 (LCO). The epitaxial films were grown by pulsed laser epitaxy on NdGaO3 and SrTiO3 substrates to vary the degree of strain. With increasing the LCO substitution, we observed a systematic increase in the c-axis lattice constant of the Aurivillius phase related with the modification of pseudo-orthorhombic unit cells. These compositional and structural changes resulted in a systematic decrease in the band gap, i.e., the optical transition energy between the oxygen 2p and transition-metal 3d states, based on a spectroscopic ellipsometry study. In particular, the Co 3d state seems to largely overlap with the Ti t2g state, decreasing the band gap. Interestingly, the applied tensile strain facilitates the band-gap narrowing, demonstrating that epitaxial strain is a useful tool to tune the electronic structure of ferroelectric transition-metal oxides.
Author: Alexander A. Demkov Publisher: Springer Science & Business Media ISBN: 146149320X Category : Technology & Engineering Languages : en Pages : 284
Book Description
This book describes the basic physical principles of the oxide/semiconductor epitaxy and offers a view of the current state of the field. It shows how this technology enables large-scale integration of oxide electronic and photonic devices and describes possible hybrid semiconductor/oxide systems. The book incorporates both theoretical and experimental advances to explore the heteroepitaxy of tuned functional oxides and semiconductors to identify material, device and characterization challenges and to present the incredible potential in the realization of multifunctional devices and monolithic integration of materials and devices. Intended for a multidisciplined audience, Integration of Functional Oxides with Semiconductors describes processing techniques that enable atomic-level control of stoichiometry and structure and reviews characterization techniques for films, interfaces and device performance parameters. Fundamental challenges involved in joining covalent and ionic systems, chemical interactions at interfaces, multi-element materials that are sensitive to atomic-level compositional and structural changes are discussed in the context of the latest literature. Magnetic, ferroelectric and piezoelectric materials and the coupling between them will also be discussed. GaN, SiC, Si, GaAs and Ge semiconductors are covered within the context of optimizing next-generation device performance for monolithic device processing.
Author: Narayanasamy Sabari Arul Publisher: Springer Nature ISBN: 9811512671 Category : Technology & Engineering Languages : en Pages : 320
Book Description
This volume presents advanced synthesis techniques for fabricating Perovskite materials with enhanced properties for applications such as energy storage devices, photovoltaics, electrocatalysis, electronic devices, photocatalysts, sensing, and biomedical instruments. The book attempts to fill a gap in the published literature and provide a detailed reference on Perovskite materials. This book will be of use to graduate students and academic and industrial researchers in the fields of solid-state chemistry, physics, materials science, and chemical engineering.
Author: Richard J. D. Tilley Publisher: John Wiley & Sons ISBN: 1118935632 Category : Technology & Engineering Languages : en Pages : 328
Book Description
Uniquely describes both the crystallography and properties of perovskite related materials. Practical applications in solar cells, microelectronics and telecommunications Interdisciplinary topic drawing on materials science, chemistry, physics, and geology Contains problems and answers to enhance knowledge retention
Author: Zuzeng Qin Publisher: CRC Press ISBN: 1000541304 Category : Technology & Engineering Languages : en Pages : 179
Book Description
MXene, a two-dimensional (2D) transition metal carbide, nitride, and carbonitride, was discovered in 2011. MXene has great potential as a cocatalyst in the field of photocatalysis due to its unique properties and structure. MXene-Based Photocatalysts: Fabrication and Applications introduces readers to the fundamentals, preparation, microstructure characterization, and a variety of applications of MXene-based photocatalysts. The book is a comprehensive reference for MXene materials and provides an overview of the current literature on MXene-based photocatalysts. FEATURES Discusses preparation methods of MXenes Describes the morphology and microstructure of MXenes Offers strategies for fabricating MXene-based photocatalysts Details the reaction mechanism of MXene-based photocatalysts Covers applications in photocatalytic water-splitting, photocatalytic CO2 reduction, photocatalytic degradation, photocatalytic nitrogen fixation, and photocatalytic H2O2 production This book serves as an invaluable guide for advanced students, industry professionals, professors, and researchers in the field of materials science and engineering, photocatalysis, energy, and environmental applications.
Author: Aimé Peláiz-Barranco Publisher: BoD – Books on Demand ISBN: 9535121472 Category : Technology & Engineering Languages : en Pages : 258
Book Description
Ferroelectric materials receive great attention from the scientific international community because of the interesting phenomena they exhibit and their multiple applications such as transducers, capacitors, pyroelectric sensors, sonars, random access memories, etc. The demand for ferroelectric materials for technological applications enforced the in-depth research, in addition to the improvement of processing and characterization techniques. This book contains nine chapters and offers the results of several researches covering fabrication, properties, theoretical topics, and phenomena at the nanoscale.
Author: Theodor Schneller Publisher: Springer Science & Business Media ISBN: 3211993118 Category : Technology & Engineering Languages : en Pages : 801
Book Description
This is the first text to cover all aspects of solution processed functional oxide thin-films. Chemical Solution Deposition (CSD) comprises all solution based thin- film deposition techniques, which involve chemical reactions of precursors during the formation of the oxide films, i. e. sol-gel type routes, metallo-organic decomposition routes, hybrid routes, etc. While the development of sol-gel type processes for optical coatings on glass by silicon dioxide and titanium dioxide dates from the mid-20th century, the first CSD derived electronic oxide thin films, such as lead zirconate titanate, were prepared in the 1980’s. Since then CSD has emerged as a highly flexible and cost-effective technique for the fabrication of a very wide variety of functional oxide thin films. Application areas include, for example, integrated dielectric capacitors, ferroelectric random access memories, pyroelectric infrared detectors, piezoelectric micro-electromechanical systems, antireflective coatings, optical filters, conducting-, transparent conducting-, and superconducting layers, luminescent coatings, gas sensors, thin film solid-oxide fuel cells, and photoelectrocatalytic solar cells. In the appendix detailed “cooking recipes” for selected material systems are offered.
Author: Juan Bisquert Publisher: CRC Press ISBN: 1439836027 Category : Science Languages : en Pages : 356
Book Description
Due to the pressing needs of society, low cost materials for energy devices have experienced an outstanding development in recent times. In this highly multidisciplinary area, chemistry, material science, physics, and electrochemistry meet to develop new materials and devices that perform required energy conversion and storage processes with high efficiency, adequate capabilities for required applications, and low production cost. Nanostructured Energy Devices: Equilibrium Concepts and Kinetics introduces the main physicochemical principles that govern the operation of energy devices. It includes coverage of the physical principles that control energy devices made of nanostructured and bulk materials, with the main attention focused on solution processed thin film technologies. The book analyzes the fundamental concepts, main properties, and key applications of energy devices that are made using nanostructured materials and innovative thin film low cost technologies. This includes hybrid and organic solar cells, electrochemical batteries, diodes, LEDs and OLEDs, transistors, and the direct conversion of solar radiation to chemical fuels. It decodes rigorous formulation of thermodynamic concepts to establish energy diagrams, and explains also the fundamental kinetic models that determine the flow of electrons and ions in the device. The author lays out the main properties of semiconductors and their junctions for applications in solar cell and solar fuel devices. He emphasizes a unified view of the device operation principles that covers well-known examples but also enables you to discuss original research topics on a solid ground. Although a challenging field of science and technology, energy devices such as solar cells and batteries have the potential to impact the creation of a carbon-free energy economy. However, the field draws scientists from a broad set of backgrounds, united towards common goals. This text presents the main concepts that apply to several types of devices, from a very basic level so that you can gain insight into the general view of principles of operation of the energy devices. It pulls together the views and terminologies used by several communities to create better communication and increased collaboration among them.
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Author: Vladimir Mikhaĭlovich Fridkin
Author: Alexander A. Demkov
Author: Narayanasamy Sabari Arul
Author: Richard J. D. Tilley
Author: Zuzeng Qin
Author: Aimé Peláiz-Barranco
Author: Theodor Schneller
Author: Juan Bisquert
Author: Thomas Brückel