Author: Yoshiharu Izumi
Publisher: Elsevier
ISBN: 0323155030
Category : Science
Languages : en
Pages : 345
Book Description
Stereo-Differentiating Reactions: The Nature of Asymmetric Reactions provides an introduction to asymmetric reactions. It brings together synthetic organic chemistry, stereochemistry, group theory, the theory of optical rotation, experimental methods, etc., all of which are basic to the study of stereo-differentiating reactions, to form a unified approach based on the new concept of "differentiation." The authors hope that the value of the new concept, which is rather more complex than conventional treatments of asymmetric reactions, will become clear in the present book. This new concept should be useful in many fields of study, not only the development of stereo-differentiating reactions, but also in the study of general reaction mechanisms in organic chemistry. The book contains nine chapters and begins with a historical background of studies on asymmetric reactions. This is followed by separate chapters on molecular symmetry and chirality; nomenclature for chirality, prochirality, and stereo-differentiating reactions; the mechanisms of stereo-differentiating reactions; methods for studying stereo-differentiating reactions; and the basic principle of optical activity.
Stereo-Differentiating reactions
Author: Yoshiharu Izumi
Publisher: Elsevier
ISBN: 0323155030
Category : Science
Languages : en
Pages : 345
Book Description
Stereo-Differentiating Reactions: The Nature of Asymmetric Reactions provides an introduction to asymmetric reactions. It brings together synthetic organic chemistry, stereochemistry, group theory, the theory of optical rotation, experimental methods, etc., all of which are basic to the study of stereo-differentiating reactions, to form a unified approach based on the new concept of "differentiation." The authors hope that the value of the new concept, which is rather more complex than conventional treatments of asymmetric reactions, will become clear in the present book. This new concept should be useful in many fields of study, not only the development of stereo-differentiating reactions, but also in the study of general reaction mechanisms in organic chemistry. The book contains nine chapters and begins with a historical background of studies on asymmetric reactions. This is followed by separate chapters on molecular symmetry and chirality; nomenclature for chirality, prochirality, and stereo-differentiating reactions; the mechanisms of stereo-differentiating reactions; methods for studying stereo-differentiating reactions; and the basic principle of optical activity.
Publisher: Elsevier
ISBN: 0323155030
Category : Science
Languages : en
Pages : 345
Book Description
Stereo-Differentiating Reactions: The Nature of Asymmetric Reactions provides an introduction to asymmetric reactions. It brings together synthetic organic chemistry, stereochemistry, group theory, the theory of optical rotation, experimental methods, etc., all of which are basic to the study of stereo-differentiating reactions, to form a unified approach based on the new concept of "differentiation." The authors hope that the value of the new concept, which is rather more complex than conventional treatments of asymmetric reactions, will become clear in the present book. This new concept should be useful in many fields of study, not only the development of stereo-differentiating reactions, but also in the study of general reaction mechanisms in organic chemistry. The book contains nine chapters and begins with a historical background of studies on asymmetric reactions. This is followed by separate chapters on molecular symmetry and chirality; nomenclature for chirality, prochirality, and stereo-differentiating reactions; the mechanisms of stereo-differentiating reactions; methods for studying stereo-differentiating reactions; and the basic principle of optical activity.
Stereo-differentiating Reactions
Stereochemistry
Author: David G. Morris
Publisher: Royal Society of Chemistry
ISBN: 9780854046027
Category : Education
Languages : en
Pages : 188
Book Description
This text for undergraduate students presents an introduction to stereochemistry--the study of the three-dimensional structure of molecules--with a focus on organic chemistry. In eight chapters, Morris (U. of Glasgow) discusses topics such as the hybridization, conformation, and configuration of simple molecules; chiral molecules; molecules with two or more stereogenic centers; stereoisomerism in cyclic structures; and substitution reactions at saturated carbon. Coverage extends to the use of NMR spectroscopy in stereochemistry. c. Book News Inc.
Publisher: Royal Society of Chemistry
ISBN: 9780854046027
Category : Education
Languages : en
Pages : 188
Book Description
This text for undergraduate students presents an introduction to stereochemistry--the study of the three-dimensional structure of molecules--with a focus on organic chemistry. In eight chapters, Morris (U. of Glasgow) discusses topics such as the hybridization, conformation, and configuration of simple molecules; chiral molecules; molecules with two or more stereogenic centers; stereoisomerism in cyclic structures; and substitution reactions at saturated carbon. Coverage extends to the use of NMR spectroscopy in stereochemistry. c. Book News Inc.
Modern Methods in Stereoselective Aldol Reactions
Author: Rainer Mahrwald
Publisher: John Wiley & Sons
ISBN: 3527656731
Category : Science
Languages : en
Pages : 604
Book Description
The selective formation of bondings between molecules is one of the major challenges in organic chemistry, and the so-called aldol reaction is one of the most important for this purpose. These reactions are a highly useful tool for developing such novel substances as natural products and pharmaceuticals. Likes its highly successful and much appreciated predecessor, "Modern Aldol Reactions", this ready reference provides a systematic overview of methodologies for installing a required configuration during an aldol addition step, but shifts the focus so as to cover the latest developments. As such, it presents a set of brand new tools, including vinylogous Mukaiyama-aldol reactions and substrate-controlled aldol reactions, as well as asymmetric induction in aldol additions. Furthermore, new developments in existing stereoselective aldol additions are described, such as the deployment of supersilyl groups or organocatalyzed aldol additions. All of these methodologies are presented in the context of their deployment in the total synthesis of natural products.
Publisher: John Wiley & Sons
ISBN: 3527656731
Category : Science
Languages : en
Pages : 604
Book Description
The selective formation of bondings between molecules is one of the major challenges in organic chemistry, and the so-called aldol reaction is one of the most important for this purpose. These reactions are a highly useful tool for developing such novel substances as natural products and pharmaceuticals. Likes its highly successful and much appreciated predecessor, "Modern Aldol Reactions", this ready reference provides a systematic overview of methodologies for installing a required configuration during an aldol addition step, but shifts the focus so as to cover the latest developments. As such, it presents a set of brand new tools, including vinylogous Mukaiyama-aldol reactions and substrate-controlled aldol reactions, as well as asymmetric induction in aldol additions. Furthermore, new developments in existing stereoselective aldol additions are described, such as the deployment of supersilyl groups or organocatalyzed aldol additions. All of these methodologies are presented in the context of their deployment in the total synthesis of natural products.
Catalysis of Organic Reactions
Author: Dennis G. Morrell
Publisher: CRC Press
ISBN: 9780203911013
Category : Science
Languages : en
Pages : 868
Book Description
This text offers authoritative contributions from nearly 200 leaders in the field and new methods to enhance catalytic reactions. "Catalysis of Organic Reactions" covers approaches for designing, modifying, and altering catalysts for improved function, performance, and stability, procedures to reduce by-product formation, and cost-effective alterna
Publisher: CRC Press
ISBN: 9780203911013
Category : Science
Languages : en
Pages : 868
Book Description
This text offers authoritative contributions from nearly 200 leaders in the field and new methods to enhance catalytic reactions. "Catalysis of Organic Reactions" covers approaches for designing, modifying, and altering catalysts for improved function, performance, and stability, procedures to reduce by-product formation, and cost-effective alterna
Asymmetric Synthesis
Author: James D. Morrison
Publisher:
ISBN: 9780125077033
Category : Addisiereaksies
Languages : en
Pages : 600
Book Description
Publisher:
ISBN: 9780125077033
Category : Addisiereaksies
Languages : en
Pages : 600
Book Description
Asymmetric Synthesis
Author: James D. Morrison
Publisher:
ISBN: 9780125077033
Category : Addisiereaksies
Languages : en
Pages : 600
Book Description
Publisher:
ISBN: 9780125077033
Category : Addisiereaksies
Languages : en
Pages : 600
Book Description
Stereochemistry of Organic Compounds
Author: Ernest L. Eliel
Publisher: John Wiley & Sons
ISBN: 0471016705
Category : Science
Languages : en
Pages : 1296
Book Description
Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.
Publisher: John Wiley & Sons
ISBN: 0471016705
Category : Science
Languages : en
Pages : 1296
Book Description
Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.
Stereochemistry and Organic Reactions
Author: Dipak Kumar Mandal
Publisher: Academic Press
ISBN: 0128240938
Category : Science
Languages : en
Pages : 640
Book Description
Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. - Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes - Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs - Features novel rules and mnemonics to delineate product stereochemistry - Includes up-to-date coverage with over 1300 selective references
Publisher: Academic Press
ISBN: 0128240938
Category : Science
Languages : en
Pages : 640
Book Description
Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. - Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes - Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs - Features novel rules and mnemonics to delineate product stereochemistry - Includes up-to-date coverage with over 1300 selective references
Tailored Metal Catalysts
Author: Y. Iwasawa
Publisher: Springer Science & Business Media
ISBN: 9400952619
Category : Science
Languages : en
Pages : 343
Book Description
Publisher: Springer Science & Business Media
ISBN: 9400952619
Category : Science
Languages : en
Pages : 343
Book Description