Reactions of Metal Ions and Their Clusters in the Gas Phase Using Laser Ionization PDF Download
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Author: Publisher: ISBN: Category : Languages : en Pages : 13
Book Description
This report focuses on three areas we have made substantial new progress in over the past several months: (1) Infrared multiphoton photoinduced ion molecule reactions; (2) The use of SF[sub 6] to detect excited state metal ion behavior; and (3) Cluster ion chemistry.
Author: Publisher: ISBN: Category : Languages : en Pages : 13
Book Description
This report focuses on three areas we have made substantial new progress in over the past several months: (1) Infrared multiphoton photoinduced ion molecule reactions; (2) The use of SF[sub 6] to detect excited state metal ion behavior; and (3) Cluster ion chemistry.
Author: Publisher: ISBN: Category : Languages : en Pages : 13
Book Description
This report focuses on three areas we have made substantial new progress in over the past several months: (1) Infrared multiphoton photoinduced ion molecule reactions; (2) The use of SF6 to detect excited state metal ion behavior; and (3) Cluster ion chemistry.
Author: Publisher: ISBN: Category : Languages : en Pages : 16
Book Description
This report focuses on progress in seven areas: (1) Gas-Phase Reactions of Fe(Benzyne) with Simple Alkyl Halides; (2) Photodissociation and Collision-Induced Dissociation of Molecular Ions From Methylphenol and Chloromethylphenol; (3) Isotopomer Differentiation Using Metal Ion Chemical Ionization Reagents; (4) Multiple Excitation Collisional Activation (MECA) in Fourier Transform Mass Spectrometry; (5) Chemistry of Fe-Arene Ions with Halobenzenes; (6) Gas-Phase Photodissociaton Study of Ag(Benzene)+ and Ag(Toluene)+; and (7) Reactivity of Ti{sup 2+} and V{sup 2+} with Small Alkanes.
Author: Publisher: ISBN: Category : Languages : en Pages : 11
Book Description
Carbon clusters of the form C{sub N}− are observed at least out to N = 30 confirming that cluster formation is occurring in the high pressure ''waiting room'' of the supersonic cluster source. This can be stated unequivocally, since only up to N = 13 is observed by direct laser desorption of a carbon target in the absence of supersonic expansion. Currently underway is a systematic investigation of a wide variety of M-C{sub n}H{sub 2n} species with n = 2--10 and M = first and second row transition metal ions. In addition we will shortly apply this methodology to doubly charged ions and metal cluster ions. All indications are that this area will be highly productive.
Author: David H. Russell Publisher: Springer Science & Business Media ISBN: 146845529X Category : Science Languages : en Pages : 422
Book Description
The field of gas phase inorganic ion chemistry is relatively new; the early studies date back approximately twenty years, but there has been intense interest and development in the field in the last ten years. As with much of modern chemistry, the growth in gas phase inorganic ion chemistry can be traced to the development of instrumentation and new experimental methods. Studies in this area require sophisticated instruments and sample introduc tion/ ionization methods, and often these processes are complicated by the need for state-selecting (or collisionally stabilizing) the reactive species in order to assign the chemistry unequivocally. At the present level of experimental development, a wide range of experiments on diverse ionic systems are possible and many detailed aspects of the chemistry can be studied. Gas Phase Inorganic Chemistry focuses on the reactions of metal ions and metal clusters, and on the study of these species using the available modern spectroscopic methods. Three of the twelve chapters cover the chemistry of ionic monometal transition metal ions and the chemistry of these species with small diatomics and model organics. Two of the chapters focus on the studies of the chemical and physical properties of (primarily) transition metal clusters, and these chapters review experimental methods and capabilities. Two chapters also deal with the chemistry of transition metal carbonyl clusters, and these chapters address issues important to cluster growth and activation as well as the characterization of such species.
Author: Alex. G. Harrison Publisher: Taylor & Francis ISBN: 1351461540 Category : Science Languages : en Pages : 221
Book Description
The only comprehensive guide to CIMS applications in structural elucidation and analytical studies Chemical Ionization Mass Spectrometry, 2nd Edition, provides a comprehensive, up-to-date review of CIMS applications in structural elucidation and quantitative analytical studies. For the benefit of readers without a background in gaseous ion chemistry, a thorough review is presented in Chapter 2. Other chapters discuss such topics as reagent ion systems within the context of the thermochemistry and kinetics of the ionization process, including reactions and the type of information obtained; isotopic exchange reactions; stereochemical effects in chemical ionization; and reactive ion/molecule collisions in quadrupole cells. Chemical ionization mass spectra of 13 classes of compounds are discussed in detail to illustrate the influence of different functional groups on the spectra observed. Chemical Ionization Mass Spectrometry, 2nd Edition will be a valuable reference for anyone interested in mass spectrometry and gaseous ion chemistry in general.
Author: United States. Congress. House. Committee on Science and Technology. Subcommittee on Energy Development and Applications Publisher: ISBN: Category : Fossil fuels Languages : en Pages : 1160
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Author: David H. Russell
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Author: Alex. G. Harrison
Author: United States. Congress. House. Committee on Science and Technology. Subcommittee on Energy Development and Applications
Author: National Science Foundation (U.S.)