Author: E. T. Denisov Publisher: Springer Science & Business Media ISBN: 1468483005 Category : Science Languages : en Pages : 782
Book Description
The past 25 years in chemical kinetics have seen major advances in studyiqg the mechanisms of complex chemical re actions, in particular free radical reactions. Many differ ent methods have been developed for quantitative studies of elementary chemical reactions. Thousands of rate constants have been measured, for hundreds of diverse chemical reac tions. It is becoming more and more difficult for the chemist to orient himself in the voluminous and rapidly growing liter ature of chemical reaction kinetics. This leads to major expenditures of time in searching out, collecting. and eval uating quantitative kinetic data; to unnecessary repetition (duplication) of research; and to a situation in which the rich material already accumulated in the field of chemical kinetics is very often not fully utilized in comparing, interpreting, and analyzing new experimental data. There is a pressing need for the creation of a series of handbooks on reaction rate constants. Such work was begun several years ago at the initiative of V. N. Kondrat'ev, and is now going forward under his direction at the Institute of Chemical Physics of the USSR Academy of Sciences. This book is devoted to liquid-phase, homolytic reactions. Part One contains data on monomolecular reactions in which molecules decompose to form radicals, as well as data on bi molecular and trimolecular reactions that form free radicals.
Author: John B. Butt Publisher: CRC Press ISBN: 9780824777227 Category : Science Languages : en Pages : 760
Book Description
This text combines a description of the origin and use of fundamental chemical kinetics through an assessment of realistic reactor problems with an expanded discussion of kinetics and its relation to chemical thermodynamics. It provides exercises, open-ended situations drawing on creative thinking, and worked-out examples. A solutions manual is also available to instructors.
Author: Brian G. Cox Publisher: Oxford University Press on Demand ISBN: 9780198557449 Category : Science Languages : en Pages : 92
Book Description
The world is not at equilibrium, and the events that give vitality and movement are transitions towards equilibrium from the present state of imbalance. Chemical transformations often contribute fundamentally to this process and their study is challenging and important. The early chapters of this text provide a basic introduction to the kinetics of simple and complex reaction systems in solution. The remaining chapters present a treatment of the more advanced topics, comprising solvent effects, fast reaction techniques, and heterogeneous liquid - liquid two-phase systems. The last introduces currently active and important research areas in solution kinetics, including phase-transfer catalysis, and diffusion and transport in chemical and biological membranes.
Author: Brian G. Cox Publisher: ISBN: 9780191849046 Category : Chemical kinetics Languages : en Pages : 91
Book Description
The world is not at equilibrium, and the events that give vitality and movement are transitions towards equilibrium from the present state of imbalance. Chemical transformations often contribute fundamentally to this process and their study is challenging and important. The early chapters of this text provide a basic introduction to the kinetics of simple and complex reaction systems in solution. The remaining chapters present a treatment of the more advanced topics, comprising solvent effects, fast reaction techniques, and heterogeneous liquid - liquid two-phase systems. The final chapter introduces currently active and important research areas in solution kinetics, including phase-transfer catalysis, and diffusion and transport in chemical and biological membranes.
Author: G. Porter Publisher: Elsevier ISBN: 1483224953 Category : Science Languages : en Pages : 532
Book Description
Progress in Reaction Kinetics, Volume 4 is a 10-chapter text that focuses on the reactions of nitrogen atoms in the gas phase and some chemical factors in the kinetics of processes at electrodes. This volume describes first the free radical reactions dealing with halogenomethyl and alkoxyl radicals. The next chapters deal with electronically excited states, proton transfer, and kinetics of electrode processes. These topics are followed by discussions on the primary processes in the gas phase photochemistry of carbonyl compounds, as well as the mechanisms and rates of radiationless energy transfer. This book also looks into the methods used for the measurement of fluorescence lifetimes of aromatic compounds. A chapter examines the chemiluminescence in the oxidation of organic compounds and for other liquid-phase reactions. The last chapters discuss the role of the solvent in proton transfer reactions and some aspects of developments in the field of electrode processes. This book is of great value to reaction kinetics scientists and researchers.
Author: Gennadiĭ Efremovich Zaikov Publisher: Nova Publishers ISBN: 9781590338544 Category : Science Languages : en Pages : 212
Book Description
This collection examines the influence of liquid and solid states during radical, ionic, and molecular reactions, specifically how cage effect, diffusion hindrance, donor-acceptor interaction, electrostatic interaction, dispersion forces and other factors affect the rates, mechanism, and direction of chemical reactions. Topics of the 11 papers include spherical hydrogel particles for endovascular embolisation, the synthesis and thermal degradation of phenolic resins, mono-molecular chain termination in dimethacrylate postpolymerisation, and calculating the effect of chain deformation on macromolecule scission. Most of the researchers work in Russia.
Author: E. T. Denisov
Author: Sergeĭ Genrikhovich Ėntelis
Author: John B. Butt
Author: 
Author: Brian G. Cox
Author: Brian G. Cox
Author: United States. National Bureau of Standards
Author: United States. National Bureau of Standards
Author: G. Porter
Author: Gennadiĭ Efremovich Zaikov