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Techniques and Applications of Fast Reactions in Solution

Techniques and Applications of Fast Reactions in Solution PDF Author: W.J. Gettins
Publisher: Springer Science & Business Media
ISBN: 9400994907
Category : Science
Languages : en
Pages : 585

Book Description
As a result of the pioneering efforts of Eigen, de Maeyer, Norrish and Porter, the kinetics of fast reactions in solution can now be studied using chemical relaxation methods, as well as many other fast reactions techniques. These methods have been applied successfully in many branches of the natural sciences. The simultaneous growth in the number of investiga tors and the diversity of their research interests has inevitably led to communication problems. The purpose of the NATO Advanced Study Institute entitled "New Applications of Chemical Relaxation Spectrometry and Other Fast Reaction Methods in Solution", was to create a forum so that research scientists working in different areas concerned with fast reactions could interact. This meeting was held at the Llandinam Building, University College of Wales, Aberystwyth from September 10th-20th, 1978. In addition to lectures on techniques and theory, two days of the NATO Advanced Study Institute, were spent discussing the current state of the art in this field. This two day meeting was also run under the auspices of the Chemical Society, Fast Reactions in Solution Group. The papers in this volume are the result of the contribu tions given in the Aberystwyth meeting. We have attempted to make this volume useful for the non-expert and a comprehensive introduction to theory, as well as the instrumentation used in the studies are discussed in detail.

Selectivity in Chemical Reactions

Selectivity in Chemical Reactions PDF Author: J.C. Whitehead
Publisher: Springer Science & Business Media
ISBN: 940093047X
Category : Science
Languages : en
Pages : 562

Book Description
The aim of this Workshop on "Selectivity in Chemical Reactions" was to examine the specific preferences exhibited by simple chemical reactions with regards to reagents having particular energy states, symmetries, alignment and orientation and the resulting formation of certain products with their corresponding energies, states, alignment and polarisation. Such problems come close to the ultimate goal of reaction dynamics of being able to determine experimentally and theoretically state-to-state cross sections and stereochemical effects under well defined and characterised conditions. There are many examples of highly selective and specific processes to be found in atmospheric and combustion chemistry and the production of population inversions amongst vibrational and electronic states lies at the heart of the development of chemical laser systems. Only when we can understand the fundamental processes that underlie the selectivity in the formation of products in a chemical reaction and the specific requirements of initial states of the reagents, can we expect to be able to develop the explanatory and predictive tools necessary to apply the subject to the development of new laser systems, efficient combustion schemes and specific methods of chemical synthesis, to the control of atmospheric pollution and to all problems in which it is necessary to direct the outcome of a chemical reaction in a specific way. The brief given to the Workshop was to critically review the field, to discuss the present limitations and difficulties and to identify new directions.

Reaction Injection Molding and Fast Polymerization Reactions

Reaction Injection Molding and Fast Polymerization Reactions PDF Author: Jiri E. Kresta
Publisher: Springer Science & Business Media
ISBN: 1468487337
Category : Science
Languages : en
Pages : 303

Book Description
The emergence of reaction injection molding (RIM) has been fol lowed by the industry with mounting interest. RIM technology has brought to polymer processing a new flexibility and savings in both energy and capital investment. The new developments and the number of engineers and scientists working in RIM is growing at so fast a rate that there is need for sharing information on progress in this area. This book is based on papers presented at the International Symposium on Reaction Injection Molding which was held in 1981 in Atlanta, Georgia, and was sponsored by the American Chemical Society, Division of Organic Coatings and Plastics Chemistry. The book is divided into four parts covering different areas of RIM development. The first part is devoted to the future trends of RIM develop ment in the United States and Japan. The structure-properties relationship and effects of annealing on properties of RIM elastomers are covered in the second part. New non-urethane polymers such as polyamides, polyisocyanurates and polystyrene suitable for RIM processing are discussed in the third part. In the last part the engineering and technological aspects of RIM, such as glass reinforcement, mixing, flow and moldability are covered in detail. Finally I would like to thank Mrs. Iris Glebe for typing this book and for help with editing, and K. Zielinski for his assistance v vi PREFACE in reviewing and, when necessary, correcting some of the papers. Thanks is also due to the editors of Plenum for their patience and helpfulness.

Practice, Fatigue and Oscillation

Practice, Fatigue and Oscillation PDF Author: John Carl Flugel
Publisher:
ISBN:
Category : Fatigue
Languages : en
Pages : 552

Book Description


Metal-water Reactions

Metal-water Reactions PDF Author: Leo F. Epstein
Publisher:
ISBN:
Category : Heavy water reactors
Languages : en
Pages : 84

Book Description


Organometallic Reactions and Polymerization

Organometallic Reactions and Polymerization PDF Author: Kohtaro Osakada
Publisher: Springer
ISBN: 366243539X
Category : Technology & Engineering
Languages : en
Pages : 307

Book Description
This compilation provides advanced graduate students and researchers with a structured overview of olefin polymerization. Divided into eight chapters written by international experts, this book covers polymerization using various organotransition-metal catalysts, including early and late transition metal complexes, new trends in olefin oligomerization and related reactions. All authors address the historic and scientific backgrounds of the field as well as current research progress and potential for further research. The complete book is designed to present eight independent lectures and, because all authors are well versed in organometallic chemistry, each is based on a profound understanding of the reactions and structures of organotransition metal complexes. This book is an ideal accompaniment for researchers taking courses in olefin polymerization and also serves as a valuable resource for teachers and lecturers of chemistry when planning and researching material for advanced lecture courses.

The Mechanisms of Fast Reactions in Solution

The Mechanisms of Fast Reactions in Solution PDF Author: Edward Caldin
Publisher: IOS Press
ISBN: 9781586031039
Category : Science
Languages : en
Pages : 348

Book Description
Published a few years after the author's death, this volume is a sequel to his 1964 book, Fast Reactions in Solution; the material is entirely new, extending investigation beyond now well-established fast-reaction techniques to consider their contribution to understanding events on the molecular scale. After an introductory chapter on origins, methods, mechanisms, and rate constants, coverage includes the rates of diffusion-controlled reactions, mathematical theory of diffusion, flash photolysis techniques, fluorescence quenching, Marcus theory involving proton-transfer and group-transfer reactions in solutions, and electron-transfer reactions. Annotation copyrighted by Book News, Inc., Portland, OR.

Mechanisms of Reactions of Metal Complexes

Mechanisms of Reactions of Metal Complexes PDF Author: Debabrata Banerjea
Publisher: Royal Society of Chemistry
ISBN: 1839163607
Category : Science
Languages : en
Pages : 539

Book Description
Reaction Mechanisms of Metal Complexes in Solution provides a comprehensive overview of an often-overlooked research area. Despite its importance and recent reshaping of the field, many inorganic chemists have lost an appreciation for the significance of stability constants and the thermodynamic aspects of complex formation. Ideal for newcomers and established researchers in the field this book is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas. The book will be of particular interest to postgraduates with an interest in coordination chemistry, catalysis, supramolecular chemistry, metallobiology and related aspects of biochemistry.

Kinetics of Heterogeneous Catalytic Reactions

Kinetics of Heterogeneous Catalytic Reactions PDF Author: Michel Boudart
Publisher: Princeton University Press
ISBN: 1400853338
Category : Science
Languages : en
Pages : 241

Book Description
This book is a critical account of the principles of the kinetics of heterogeneous catalytic reactions in the light of recent developments in surface science and catalysis science. Originally published in 1984. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

Kinetics of Chemical Gas Reactions

Kinetics of Chemical Gas Reactions PDF Author: Viktor Nikolaevich KondratĀ£ev
Publisher:
ISBN:
Category : Chemical reactions
Languages : en
Pages : 466

Book Description


Fast Reactions in Energetic Systems

Fast Reactions in Energetic Systems PDF Author: Christos Capellos
Publisher: Springer Science & Business Media
ISBN: 9400985118
Category : Science
Languages : en
Pages : 747

Book Description
This book presents the formal lectures and contributed papers given at the NATO Advanced Study Institute on Fast Reactions in Energetic Systems, which took place in Preveza, Greece, during the period 6-19 July 1980. The material describes experimental observations and the more advanced theoretical aspects of certain types of fast reactions and energy or charge transfer processes which are usually complete 6 12 in periods of 10- - 10- seconds. Furthermore, it discusses the role of macroscopic and molecular processes in the ignition, combustion, deflagration, and detonation of solid, liquid, and gaseous chemical systems. Various papers deal with the ability of molecules to absorb and transmit the different forms of energy provided by shock, light, thermal, or electron pulses, and to contribute to the propagation of reactions under high temperatures and pressures. The role of energy pumped or transferred to electronic or vibrational states is discussed in terms of excitation, ionization, bond scission, and the formation of free radicals. The dynamics and reactivity of ionic species, electronically and vibrationally excited states, and free radicals are described for various gaseous, liquid, and solid systems. The proceedings include presentations of theoretical and experimental techniques to describe and observe the phenomena.