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Author: Demetrio Milea Publisher: World Scientific ISBN: 9811281106 Category : Science Languages : en Pages : 292
Book Description
Guest-edited by Dr Michel Meyer (CNRS, Université de Bourgogne, Dijon) and Prof. Demetrio Milea (Università degli Studi di Messina), Emerging Analytical Techniques for Chemical Speciation Studies focuses on a selection of valuable instrumental methods for investigating complex formation equilibria in solution, providing information on the speciation (stoichiometry and in some instances structure of the formed species) but also allowing the measurement of thermodynamic parameters (equilibrium constants, reaction enthalpy and entropy). The title is split into two volumes belonging to the Series on Chemistry, Energy and the Environment. Part 1 (Volume 15 of this series), discusses various electrochemical, electromigration, and thermophoresis-based methods. Authored by eminent practitioners in their field, each of the four chapters covers both the theoretical and the practical aspects with helpful experimental guidelines. The latest technical and computational advances are described in a way that unambiguously show the major contributions of the authors at the top of their field. Hence, this book is intended to be a valuable introduction to newcomers, while being at the same time a helpful companion to more experienced users of each instrumental techniques. It provides an up-to-date overview with useful tips and hints on the application of selected cutting-edge analytical methods that allow unravelling and modelling intricate complex formation equilibria. So far, there has been no such book focussing specifically on the measurement of thermodynamic parameters, while covering such a wide panel of techniques. This book will be of interest to a broad readership, including analytical, coordination, supramolecular, environmental, instrumental, and physical chemists, radiochemists, electrochemists, and biochemists among others.
Author: Arthur E. Martell Publisher: Springer Science & Business Media ISBN: 1489914862 Category : Science Languages : en Pages : 259
Book Description
Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.
Author: Jaroslav Heyrovský Publisher: Elsevier ISBN: 1483264785 Category : Science Languages : en Pages : 582
Book Description
Principles of Polarography is a revised and extended version of an original Czech edition that appeared in 1962 at the Publishing House of the Czechoslovak Academy of Sciences in Prague. Based on a one-term course of lectures for third-year students of chemistry at the Charles University it brings the fundamental results of more than forty years' research in the field of polarography. The book contains 22 chapters and opens with a discussion of the principles of polarography. This is followed by separate chapters on polarizable electrodes used in polarography; charging current; influence of the resistance of the electrolyte on polarographic curves; migration and diffusion-controlled currents; and equation of a reversible polarographic wave. Subsequent chapters deal with reversible processes controlled by diffusion of complex ions; reversible reduction of organic substances; deposition of mercury ions; irreversible electrode processes; applications of limiting currents; polarographic curves for the formation of semiquinones and dimers; and catalytic hydrogen currents.
Author: Demetrio Milea Publisher: World Scientific ISBN: 9811281106 Category : Science Languages : en Pages : 292
Book Description
Guest-edited by Dr Michel Meyer (CNRS, Université de Bourgogne, Dijon) and Prof. Demetrio Milea (Università degli Studi di Messina), Emerging Analytical Techniques for Chemical Speciation Studies focuses on a selection of valuable instrumental methods for investigating complex formation equilibria in solution, providing information on the speciation (stoichiometry and in some instances structure of the formed species) but also allowing the measurement of thermodynamic parameters (equilibrium constants, reaction enthalpy and entropy). The title is split into two volumes belonging to the Series on Chemistry, Energy and the Environment. Part 1 (Volume 15 of this series), discusses various electrochemical, electromigration, and thermophoresis-based methods. Authored by eminent practitioners in their field, each of the four chapters covers both the theoretical and the practical aspects with helpful experimental guidelines. The latest technical and computational advances are described in a way that unambiguously show the major contributions of the authors at the top of their field. Hence, this book is intended to be a valuable introduction to newcomers, while being at the same time a helpful companion to more experienced users of each instrumental techniques. It provides an up-to-date overview with useful tips and hints on the application of selected cutting-edge analytical methods that allow unravelling and modelling intricate complex formation equilibria. So far, there has been no such book focussing specifically on the measurement of thermodynamic parameters, while covering such a wide panel of techniques. This book will be of interest to a broad readership, including analytical, coordination, supramolecular, environmental, instrumental, and physical chemists, radiochemists, electrochemists, and biochemists among others.
Author: Ian S. Longmuir Publisher: Elsevier ISBN: 1483223485 Category : Science Languages : en Pages : 408
Book Description
Advances in Polarography, Volume 2 covers the proceedings of the Second International Congress held at Cambridge in 1959 in honor of the 70th birthday of Professor Heyrovsky. This volume is composed of 35 chapters and begins with intensive discussions on the theoretical and fundamental aspects, as well as pertinent equations in polarography. Considerable chapters are devoted to the chemical and metallurgical applications of the technique, with emphasis on the trace determination of certain compounds. The remaining chapters explore other application of specific polarographic technique, such as nicotinic acid, iso-benzpyrylium salts, and metal complex analysis.
Author: Alexander Apelblat Publisher: Springer ISBN: 3319112333 Category : Science Languages : en Pages : 365
Book Description
This monograph is devoted to different aspects associated with citric acid, inorganic citrates and their aqueous and organic solutions. It includes information about properties, occurrence and technological applications of citric acid and inorganic citrates. Phase equilibria - melting, freezing, boiling, vapour pressures, solubilities of citric acid in water, organic solvents and ternary systems are presented, correlated, and analyzed. Dynamic properties - viscosities, diffusion coefficients, electrical conductivities and surface tensions are examined. Mathematical representations of citric acid dissociation, in electrolyte solutions and in buffers are discussed. Citric acid chemistry - syntheses of citric acid, neutralization, degradation, oxidation, esterification, formation of anhydrides, amides and citrate-based siderophores is reviewed.
Author: Demetrio Milea
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Author: Arthur E. Martell
Author: Jaroslav Heyrovský
Author: Demetrio Milea
Author: Ian S. Longmuir
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Author: Alexander Apelblat
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