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Photo-induced Electron Transfer in Dye-sulphydryl Protein Complex

Photo-induced Electron Transfer in Dye-sulphydryl Protein Complex PDF Author: Eiji Fujimori
Publisher:
ISBN:
Category :
Languages : en
Pages : 7

Book Description
In a previous paper, the photobleaching and dark-regeneration of complexes containing sulphydryl compounds and a fluorescent dye were reported. Proteins were included in the sulphydryl compounds investiggated. The dye is a derivative of 3',6'-dichlorofluoran. It was proposed that photobleaching is due to an electron transfer within the complex from the sulphur to the excited conjugated dye molecule. A triplet state was considered to play some part in this electron transfer. This article presents experimental evidence confirming triplet formation and an electron transfer mechanism. Triplet formation of the dye is shown to be enhanced when complexed to the sulphur of a protein. The protein-dye complex shows greater photsensitivity than the simple dye -S-H complex. The phenomenon reported in this paper may shed light on the function of sulphydryl groups in proteins containinggvisual pigments and the phycobilin pigments which are present in photosynthetic organisms. (Author).

Photo-induced Electron Transfer in Dye-sulphydryl Protein Complex

Photo-induced Electron Transfer in Dye-sulphydryl Protein Complex PDF Author: Eiji Fujimori
Publisher:
ISBN:
Category :
Languages : en
Pages : 7

Book Description
In a previous paper, the photobleaching and dark-regeneration of complexes containing sulphydryl compounds and a fluorescent dye were reported. Proteins were included in the sulphydryl compounds investiggated. The dye is a derivative of 3',6'-dichlorofluoran. It was proposed that photobleaching is due to an electron transfer within the complex from the sulphur to the excited conjugated dye molecule. A triplet state was considered to play some part in this electron transfer. This article presents experimental evidence confirming triplet formation and an electron transfer mechanism. Triplet formation of the dye is shown to be enhanced when complexed to the sulphur of a protein. The protein-dye complex shows greater photsensitivity than the simple dye -S-H complex. The phenomenon reported in this paper may shed light on the function of sulphydryl groups in proteins containinggvisual pigments and the phycobilin pigments which are present in photosynthetic organisms. (Author).

Two Phosphorescences and Electron Transfer in Dye-disulfhydryl Compound Complex

Two Phosphorescences and Electron Transfer in Dye-disulfhydryl Compound Complex PDF Author: Eiji Fujimori
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 16

Book Description
Mercaptoethanol and dimercaptopropanol form a complex with a cationic dye. Two dyes interacting with two SH groups in the complex with dimercaptopropanol exhibit two different absorptions and two different phosphorescences. Each one of them, present at a shorter wave length, corresponds to an absorption and a phosphorescence of the complex with mercaptoethanol. The dye-dimercaptopropanol complex is more photosensitive than the dye-mercaptoethanol complex. A phototropism observed in the former complex is based on an electron transfer.

The Chemistry and Biochemistry of the Sulfhydryl Group in Amino Acids, Peptides, and Proteins

The Chemistry and Biochemistry of the Sulfhydryl Group in Amino Acids, Peptides, and Proteins PDF Author: Mendel Friedman
Publisher: Pergamon
ISBN:
Category : Science
Languages : en
Pages : 500

Book Description


Physics and Chemistry of the Organic Solid State

Physics and Chemistry of the Organic Solid State PDF Author: David Fox
Publisher:
ISBN:
Category : Chemistry, Organic
Languages : en
Pages : 544

Book Description


Photoinduced Electron Transfer

Photoinduced Electron Transfer PDF Author: Marye Anne Fox
Publisher: Elsevier Publishing Company
ISBN:
Category : Oxidation-reduction reaction
Languages : en
Pages : 780

Book Description


Photoinduced Electron Transfer in Native Proteins and Domain Forming Polymers

Photoinduced Electron Transfer in Native Proteins and Domain Forming Polymers PDF Author: Yue Sheng
Publisher:
ISBN:
Category : Oxidation-reduction reaction
Languages : en
Pages : 510

Book Description


Photoinduced Electron Transfer in Heme Proteins

Photoinduced Electron Transfer in Heme Proteins PDF Author: Rui-qin Liu
Publisher:
ISBN:
Category : Charge exchange
Languages : en
Pages : 264

Book Description


Guide to Fluorescence Literature

Guide to Fluorescence Literature PDF Author: Richard A. Passwater
Publisher:
ISBN:
Category : Fluorescence
Languages : en
Pages : 386

Book Description
In v.1 entries are arranged in chronological sections covering three to four years; in v.2 articles are grouped insix major classifications: (1) Analytical, organic; (2) Analytical, inorganic; (3) Theoretical; (4) Immunofluorescence; (5) Phosphors; (6) Addendum.

Photoinduced Electron Transfer: Photoinduced electron transfer reactions, organic substrates

Photoinduced Electron Transfer: Photoinduced electron transfer reactions, organic substrates PDF Author: Marye Anne Fox
Publisher:
ISBN:
Category : Oxidation-reducation reaction
Languages : en
Pages : 784

Book Description


Macromolecular Syntheses

Macromolecular Syntheses PDF Author: Charles Gilbert Overberger
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 180

Book Description
This book is an up-to-date collection of presentations and posters given at a tutorial and workshop sponsored by the Polymer Division of the American Chemical Society. The material included encompasses recent research results, overviews of critical areas and short presentations in the form of posters and preprints. The book is targeted at established workers in the field of fluoropolymers as well as those wishing to develop a quick understanding of current knowledge and trends in this important field.