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Oxidation of Ultra High Temperature Ceramics in Water Vapor

Oxidation of Ultra High Temperature Ceramics in Water Vapor PDF Author: National Aeronautics and Space Administration (NASA)
Publisher: Createspace Independent Publishing Platform
ISBN: 9781721650033
Category :
Languages : en
Pages : 34

Book Description
Ultra High Temperature Ceramics (UHTCs) including HfB2 + 20v/0 SiC (HS), ZrB2 + 20v/0 SiC (ZS), and ZrB2 + 30v/0 C + 14v/0 SiC (ZCS) have been investigated for use as potential aeropropulsion engine materials. These materials were oxidized in water vapor (90 percent) using a cyclic vertical furnace at 1 atm. The total exposure time was 10 h at temperatures of 1200, 1300, and 1400 C. CVD SiC was also evaluated as a baseline for comparison. Weight change, X-ray diffraction analyses, surface and cross-sectional SEM and EDS were performed. These results are compared with tests ran in a stagnant air furnace at temperatures of 1327 C for 100 min, and with high pressure burner rig (HPBR) results at 1100 and 1300 C at 6 atm for 50 h. Low velocity water vapor does not make a significant contribution to the oxidation rates of UHTCs when compared to stagnant air. The parabolic rate constants at 1300 C, range from 0.29 to 16.0 mg(sup 2)cm(sup 4)/h for HS and ZCS, respectively, with ZS results between these two values. Comparison of results for UHTCs tested in the furnace in 90 percent water vapor with HPBR results was difficult due to significant sample loss caused by spallation in the increased velocity of the HPBR. Total recession measurements are also reported for the two test environments. Nguyen, QuynhGiao N. and Opila, Elizabeth J. and Robinson, Raymond C. Glenn Research Center NASA/TM-2004-212923, E-14363

Oxidation of Ultra High Temperature Ceramics in Water Vapor

Oxidation of Ultra High Temperature Ceramics in Water Vapor PDF Author: National Aeronautics and Space Administration (NASA)
Publisher: Createspace Independent Publishing Platform
ISBN: 9781721650033
Category :
Languages : en
Pages : 34

Book Description
Ultra High Temperature Ceramics (UHTCs) including HfB2 + 20v/0 SiC (HS), ZrB2 + 20v/0 SiC (ZS), and ZrB2 + 30v/0 C + 14v/0 SiC (ZCS) have been investigated for use as potential aeropropulsion engine materials. These materials were oxidized in water vapor (90 percent) using a cyclic vertical furnace at 1 atm. The total exposure time was 10 h at temperatures of 1200, 1300, and 1400 C. CVD SiC was also evaluated as a baseline for comparison. Weight change, X-ray diffraction analyses, surface and cross-sectional SEM and EDS were performed. These results are compared with tests ran in a stagnant air furnace at temperatures of 1327 C for 100 min, and with high pressure burner rig (HPBR) results at 1100 and 1300 C at 6 atm for 50 h. Low velocity water vapor does not make a significant contribution to the oxidation rates of UHTCs when compared to stagnant air. The parabolic rate constants at 1300 C, range from 0.29 to 16.0 mg(sup 2)cm(sup 4)/h for HS and ZCS, respectively, with ZS results between these two values. Comparison of results for UHTCs tested in the furnace in 90 percent water vapor with HPBR results was difficult due to significant sample loss caused by spallation in the increased velocity of the HPBR. Total recession measurements are also reported for the two test environments. Nguyen, QuynhGiao N. and Opila, Elizabeth J. and Robinson, Raymond C. Glenn Research Center NASA/TM-2004-212923, E-14363

Oxidation of Ultra High Temperature Ceramics in Water Vapor

Oxidation of Ultra High Temperature Ceramics in Water Vapor PDF Author: Nasa Technical Reports Server (Ntrs)
Publisher: BiblioGov
ISBN: 9781289263522
Category :
Languages : en
Pages : 24

Book Description
Ultra High Temperature Ceramics (UHTCs) including HfB2 + 20v/0 SiC (HS), ZrB2 + 20v/0 SiC (ZS), and ZrB2 + 30v/0 C + 14v/0 SiC (ZCS) have been investigated for use as potential aeropropulsion engine materials. These materials were oxidized in water vapor (90 percent) using a cyclic vertical furnace at 1 atm. The total exposure time was 10 h at temperatures of 1200, 1300, and 1400 C. CVD SiC was also evaluated as a baseline for comparison. Weight change, X-ray diffraction analyses, surface and cross-sectional SEM and EDS were performed. These results are compared with tests ran in a stagnant air furnace at temperatures of 1327 C for 100 min, and with high pressure burner rig (HPBR) results at 1100 and 1300 C at 6 atm for 50 h. Low velocity water vapor does not make a significant contribution to the oxidation rates of UHTCs when compared to stagnant air. The parabolic rate constants at 1300 C, range from 0.29 to 16.0 mg(sup 2)cm(sup 4)/h for HS and ZCS, respectively, with ZS results between these two values. Comparison of results for UHTCs tested in the furnace in 90 percent water vapor with HPBR results was difficult due to significant sample loss caused by spallation in the increased velocity of the HPBR. Total recession measurements are also reported for the two test environments.

High Temperature Corrosion and Materials Chemistry IV

High Temperature Corrosion and Materials Chemistry IV PDF Author: Elizabeth J. Opila
Publisher: The Electrochemical Society
ISBN: 9781566773997
Category : Science
Languages : en
Pages : 588

Book Description
" ... papers presented at the Fourth International Symposium on High Temperature Corrosion and Materials Chemistry, held at the 203rd meeting of the Electrochemical Society, Inc., in Paris, France, April 30- May 2, 2003"--Preface.

MAX Phases and Ultra-High Temperature Ceramics for Extreme Environments

MAX Phases and Ultra-High Temperature Ceramics for Extreme Environments PDF Author: Low, I. M.
Publisher: IGI Global
ISBN: 1466640677
Category : Technology & Engineering
Languages : en
Pages : 679

Book Description
Ceramics are a versatile material, more so than is widely known. They are thermal resistant, poor electrical conductors, insulators against nuclear radiation, and not easily damaged, making ceramics a key component in many industrial processes. MAX Phases and Ultra-High Temperature Ceramics for Extreme Environments investigates a new class of ultra-durable ceramic materials, which exhibit characteristics of both ceramics and metals. Readers will explore recent advances in the manufacturing of ceramic materials that improve their durability and other physical properties, enhancing their overall usability and cost-effectiveness. This book will be of primary use to researchers, academics, and practitioners in chemical, mechanical, and electrical engineering. This book is part of the Research Essentials collection.

Ultra-High Temperature Ceramics

Ultra-High Temperature Ceramics PDF Author: William G. Fahrenholtz
Publisher: John Wiley & Sons
ISBN: 111892441X
Category : Technology & Engineering
Languages : en
Pages : 601

Book Description
The first comprehensive book to focus on ultra-high temperature ceramic materials in more than 20 years Ultra-High Temperature Ceramics are a family of compounds that display an unusual combination of properties, including extremely high melting temperatures (>3000°C), high hardness, and good chemical stability and strength at high temperatures. Typical UHTC materials are the carbides, nitrides, and borides of transition metals, but the Group IV compounds (Ti, Zr, Hf) plus TaC are generally considered to be the main focus of research due to the superior melting temperatures and stable high-melting temperature oxide that forms in situ. Rather than focusing on the latest scientific results, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications broadly and critically combines the historical aspects and the state-of-the-art on the processing, densification, properties, and performance of boride and carbide ceramics. In reviewing the historic studies and recent progress in the field, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications provides: Original reviews of research conducted in the 1960s and 70s Content on electronic structure, synthesis, powder processing, densification, property measurement, and characterization of boride and carbide ceramics. Emphasis on materials for hypersonic aerospace applications such as wing leading edges and propulsion components for vehicles traveling faster than Mach 5 Information on materials used in the extreme environments associated with high speed cutting tools and nuclear power generation Contributions are based on presentations by leading research groups at the conference "Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications II" held May 13-19, 2012 in Hernstein, Austria. Bringing together disparate researchers from academia, government, and industry in a singular forum, the meeting cultivated didactic discussions and efforts between bench researchers, designers and engineers in assaying results in a broader context and moving the technology forward toward near- and long-term use. This book is useful for furnace manufacturers, aerospace manufacturers that may be pursuing hypersonic technology, researchers studying any aspect of boride and carbide ceramics, and practitioners of high-temperature structural ceramics.

Oxidation of Non-oxide Ceramics by Water Vapour at High Temperature

Oxidation of Non-oxide Ceramics by Water Vapour at High Temperature PDF Author: T Sato
Publisher:
ISBN:
Category :
Languages : en
Pages : 13

Book Description


High Temperature Corrosion and Materials Chemistry ...

High Temperature Corrosion and Materials Chemistry ... PDF Author:
Publisher:
ISBN:
Category : Corrosion and anti-corrosives
Languages : en
Pages : 592

Book Description


High Temperature Materials and Mechanisms

High Temperature Materials and Mechanisms PDF Author: Yoseph Bar-Cohen
Publisher: CRC Press
ISBN: 1466566450
Category : Science
Languages : en
Pages : 586

Book Description
The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the application of high temperature materials to actuators and sensors, sensor design challenges, as well as various high temperature materials and mechanisms applications and challenges. Utilizing the knowledge of experts in the field, the book considers the multidisciplinary nature of high temperature materials and mechanisms, and covers technology related to several areas including energy, space, aerospace, electronics, and metallurgy. Supplies extensive references at the end of each chapter to enhance further study Addresses related science and engineering disciplines Includes information on drills, actuators, sensors and more A comprehensive resource of information consolidated in one book, this text greatly benefits students in materials science, aerospace and mechanical engineering, and physics. It is also an ideal resource for professionals in the industry.

High Temperature Ceramic Matrix Composites

High Temperature Ceramic Matrix Composites PDF Author: R. Naslain
Publisher: Woodhead Publishing Limited
ISBN:
Category : Reference
Languages : en
Pages : 864

Book Description


Journal of the Electrochemical Society

Journal of the Electrochemical Society PDF Author:
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 1066

Book Description