Nuclear Quadrupole Coupling Constants PDF Download

Author: Edwin Anthony Charles Lucken
Publisher: Academic Press
ISBN:
Category : Science
Languages : en
Pages : 380

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Author: M. Witanowski
Publisher: Springer Science & Business Media
ISBN: 1468481754
Category : Science
Languages : en
Pages : 406

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Book Description
To date nitrogen NMR has been discussed in research papers and review articles throughout the scientific literature. It has been our aim in preparing this book to provide a comprehen sive account of the widely spread applications of nitrogen NMR. The relevant literature has been surveyed from the beginnings of NMR until early 1972. The steady annual growth in the number of references cited since 1965 is ample evidence of the ever increasing importance of the subject. Sufficient theoretical and experimental background is given for an understanding of the applications dealt with in later chapters. The basic principles of NMR are developed with a theoretical approach to chemical shifts and spin-spin coupling constants, particular emphasis being given to nitrogen nuclei. Following this the experimental aspects of nitrogen NMR are adequately described. Special emphasis is given to the observable effects of the nuclear quadrupole moment of the 14 N nucleus. It is appro priate that this topic be dealt with in depth since quadrupolar interactions frequently dominate the information available from a study of the 14 N nucleus and other nuclei spin coupled to it. The applications of nitrogen chemical shift data to organic and inorganic molecules are covered in two extensive chapters which include the effects of paramagnetism on nitrogen NMR.

Author: Charles P. Poole
Publisher: Elsevier
ISBN: 0080550487
Category : Science
Languages : en
Pages : 671

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Superconductivity, 2E is an encyclopedic treatment of all aspects of the subject, from classic materials to fullerenes. Emphasis is on balanced coverage, with a comprehensive reference list and significant graphicsfrom all areas of the published literature. Widely used theoretical approaches are explained in detail. Topics of special interest include high temperature superconductors, spectroscopy, critical states, transport properties, and tunneling.This book covers the whole field of superconductivity from both the theoretical and the experimental point of view. - Comprehensive coverage of the field of superconductivity - Very up-to date on magnetic properties, fluxons, anisotropies, etc. - Over 2500 references to the literature - Long lists of data on the various types of superconductors

Author: Ernö Pretsch
Publisher: Springer Science & Business Media
ISBN: 3662224550
Category : Science
Languages : en
Pages : 325

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Book Description
Although numerical data are, in principle, universal, the compilations presented in this book are extensively annotated and interleaved with text. This translation of the second German edition has been prepared to facilitate the use of this work, with all its valuable detail, by the large community of English-speaking scientists. Translation has also provided an opportunity to correct and revise the text, and to update the nomenclature. Fortunately, spectroscopic data and their relationship with structure do not change much with time so one can predict that this book will, for a long period of time, continue to be very useful to organic chemists involved in the identification of organic compounds or the elucidation of their structure. Klaus Biemann Cambridge, MA, April 1983 Preface to the First German Edition Making use of the information provided by various spectroscopic tech niques has become a matter of routine for the analytically oriented organic chemist. Those who have graduated recently received extensive training in these techniques as part of the curriculum while their older colleagues learned to use these methods by necessity. One can, therefore, assume that chemists are well versed in the proper choice of the methods suitable for the solution of a particular problem and to translate the experimental data into structural information.

Author: K. Schofield
Publisher: Springer
ISBN: 1489958924
Category : Science
Languages : en
Pages : 439

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Author: H Allcock
Publisher: Elsevier
ISBN: 0323147518
Category : Science
Languages : en
Pages : 513

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Book Description
Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems concerns itself with the chemistry of compounds containing alternating phosphorus - nitrogen atoms in the skeleton. The monograph aims to be an introduction to phosphorus-nitrogen chemistry, a review of advances in the field, and reference work. The text is divided into three parts. Part I covers the introduction, historical background, and nomenclature of phosphorus-nitrogen compounds and the theories in bonding and structure of phosphazenes and phosphazanes. Part II deals with reactions such as the synthesis of the phosphorus-nitrogen skeleton, hydrolysis of phosphazenes and phosphazanes, and the aminolysis of halophosphazenes. Part III discusses polymer chemistry and includes topics such as polymerization, depolymerization, and phosphazene polymers. The book is recommended for students and practitioners in the field of chemistry, especially those concerned with phosphorus nitrogen compounds and polymeric systems.

Author: J.B. Lambert
Publisher: Springer Science & Business Media
ISBN: 9400971303
Category : Mathematics
Languages : en
Pages : 552

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Book Description
The field of nuclear magnetic resonance has experienced a number of spectacular developments during the last decade. Fourier transform methodology revolutionized signal acquisition capabilities. Superconducting magnets enhanced sensitivity and produced considerable improvement in spectral dispersion. In areas of new applicat ions, the life sciences particularly bene fited from these developments and probably saw the largest increase in usage. NMR imaging promises to offer a noninvasive alternative to X rays. High resolution is now achievable with solids, through magic angle spinning and cross polarization, so that the powers of NMR are applicable to previously intractable materials such as polymers, coal, and other geochemicals. The ease of obtaining relaxation times brought an important fourth variable, after the chemical shift, the coupling constant, and the rate constant, to the examination of structural and kinetic problems i~ all fields. Software development, particularly in the area of pulse sequences, created a host of useful tech niques, including difference decoupling and difference nuclear Overhauser effect spectra, multidimensional displays, signal enhancement (INEPT), coupling constant analysis for connectivity (INADEQUATE), and observation of specific structural classes such as only quaternary carbons. Finally, hardware development gave us access to the entire Periodic Table, to the particular advan tage of the inorganic and organometallic chemist. At the NATO Advanced Study Institute at Stirling, Scotland, the participants endeavored to examine all these advances, except imaging, from a multidisciplinary point of view.

Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 1074

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Author: Kurt Niedenzu
Publisher: Springer Science & Business Media
ISBN: 3642858260
Category : Science
Languages : en
Pages : 184

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Although the chemistry of boron is still relatively young, it is developing at a pace where even specific areas of research are difficult to compile into a monograph. Besides the boron hydrides, boron-nitrogen compounds are among the most fascinating derivatives of boron. Nitrogen compounds exist in a wide variety of molecular structures and display many interesting properties. The combination of nitrogen and boron, however, has some unusual features that are hard to match in any other combination of elements. This situation was first recognized by ALFRED STOCK and it seems proper to pay tribute to his outstanding work in the area of boron chemistry. One should realize that about forty years ago, STOCK and his coworkers had to develop completely new experimental techniq'\les and that no guidance for the interpreta tion of their rather unusual data had been advanced by theoretical chemists. In this monograph an attempt has been made to explore the general characteristics of structure and the principles involved in the preparation and reactions of boron-nitroge~ compounds. It was a somewhat difficult task to select that information which appears to be of the most interest to "inorganic and general chemistry" since the electronic relationship between a boron-nitrogen and a carbon-carbon grouping is reflected in the "organic" character of many of the reactions and compounds.

Author: N N Greenwood
Publisher: Royal Society of Chemistry
ISBN: 1847554903
Category : Science
Languages : en
Pages : 682

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Book Description
Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr