New Earth Abundant Materials for Thin Film Photovoltaics and RF Antennas on Flexible Substrates PDF Download

Author:
Publisher:
ISBN: 9781339134956
Category : Electrical engineering
Languages : en
Pages : 312

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Author: Udai P. Singh
Publisher: Springer
ISBN: 9789811937231
Category : Technology & Engineering
Languages : en
Pages : 0

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This book provides recent development in thin-film solar cells (TFSC). TFSC have proven the promising approach for terrestrial and space photovoltaics. TFSC have the potential to change the device design and produce high efficiency devices on rigid/flexible substrates with significantly low manufacturing cost. TFSC have several advantages in manufacturing compared to traditional crystalline Si-solar cells like less requirement of materials, can be prepared with earth’s abundant materials, less processing steps, easy to dispose, etc. Several universities/research institutes/industry in India and abroad are involved in the research area of thin-film solar cells. The book helps the readers to find the details about different thin-film technologies and its advancement at one place. Each chapter covers properties of materials, its suitability for PV applications, simple manufacturing processes and recent and past literature survey. The issues related to the development of high efficiency TFSC devices over large area and its commercial and future prospects are discussed.

Author: Ignacio Becerril Romero
Publisher:
ISBN:
Category :
Languages : en
Pages : 197

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"The development of sustainable energy sources with a high energy return on energy investment (EROI) that can substitute fossil fuels is a must in order to avoid the collapse of our current civilization. In this context, this work explores the feasibility of fabricating efficient Cu2ZnSn(Sx,Se1-x)4 (kesterite) solar cells on three strategic substrates: polyimide, ceramic and SnO2:F-coated soda-lime glass (SLG/FTO). These substrates present several advantages with respect to the standard SLG/Mo. Polyimide is compatible with roll-to-toll production processes and easily integrable in many applications thanks to its light weight and flexibility, ceramics have a direct application in building-integrated photovoltaics as solar tiles and the transparency of SLG/FTO enables advanced photovoltaic concepts like bifacial and tandem solar cells as well as the fabrication of semi-transparent devices. Their combination with a sustainable thin film photovoltaic technology based on Earth-abundant materials like kesterites has the potential of decreasing the energy fabrication cost and, thus, of increasing the EROI of photovoltaics through: 1) high throughput production, 2) integration and 3) advanced applications and functionality. However, these substrates also present several drawbacks. Alkalis, especially Na, are fundamental to achieve high efficiency devices but polyimide and ceramics are alkali-free materials. Likewise, FTO acts as a barrier for alkalis. In addition, polyimide presents a low thermal robustness that limits process temperatures below 500oC, ceramics are very rough and possess detrimental impurities and the use of FTO as back contact leads to a non-optimum p-kesterite/n-FTO interface. This work focuses on the implementation of specific strategies to adapt the kesterite solar cell fabrication process to the characteristics of the different substrates. A combination of alkaline doping and low-temperature annealings is studied for the fabrication of Cu2ZnSnSe4 solar cells on polyimide. While doping with NaF and KF is found to lead to critical improvements, working at low temperature is linked to the formation of SnSe2. This phase decreases the open-circuit voltage of the devices and is the main factor controlling their performance. Further experimentation leads to a 4.9% efficiency record device by combining NaF and Ge doping and a 480oC annealing. In the case of ceramic, vitreous enamels with controlled amounts of Na2O in their composition are used as surface smoothers, Na sources and impurity barriers, simultaneously. However, large amounts of Na2O in the enamel composition result in high densities of surface defects: undulations, pinholes and cracks. While undulations and pinholes are rather benign, cracks strongly deteriorate the back contact. In addition, the annealing time needs to be controlled to avoid the formation of SnSe2. Besides these issues, enamelled ceramic substrates are observed to behave similarly to SLG yielding a record Cu2ZnSnSe4 device with a 7.5% efficiency. Regarding SLG/FTO, the addition of transition metal oxides (TMOs) and/or Mo:Na nanolayers is studied as an approach to improve the back interface of the devices. Mo:Na is found to alleviate shunting and recombination issues and to protect FTO from degradation during annealing which leads to highly improved devices, especially for Cu2ZnSnS4. On the other hand, TMOs introduce a severe current blockage. However, the combination of the TiO2 and V2O5 with Mo:Na is observed to boost the beneficial effects of the latter in Cu2ZnSnSe4 and Cu2ZnSn(S,Se)4 devices. Although these multi-layered back interfaces exhibit a complex behaviour, this approach results in record efficiencies of 6.2%, 6.1% and 7.9% for Cu2ZnSnSe4, Cu2ZnSnS4 and Cu2ZnSn(S,Se)4 devices, respectively. These results represent the highest efficiencies ever reported for kesterite solar cells fabricated on polyimide, ceramic and transparent substrates and give proof of their large potential for sustainable kesterite-based photovoltaics." -- TDX.

Author: Tejas Prabhakar
Publisher:
ISBN:
Category :
Languages : en
Pages : 187

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In order to make photovoltaic power generation a sustainable venture, it is necessary to use cost-effective materials in the manufacture of solar cells. In this regard, AZO (Aluminum doped Zinc Oxide) and CZTS (Copper Zinc Tin Sulfide) have been studied for their application in thin film solar cells. While AZO is a transparent conducting oxide, CZTS is a photovoltaic absorber. Both AZO and CZTS consist of earth abundant elements and are non-toxic in nature. Highly transparent and conductive AZO thin films were grown using RF sputtering. The influence of deposition parameters such as working pressure, RF power, substrate temperature and flow rate on the film characteristics was investigated. The as-grown films had a high degree of preferred orientation along the (002) direction which enhanced at lower working pressures, higher RF powers and lower substrate temperatures. Williamson-Hall analysis on the films revealed that as the working pressure was increased, the nature of stress and strain gradually changed from being compressive to tensile. The fall in optical transmission of the films was a consequence of free carrier absorption resulting from enhanced carrier density due to incorporation of Al atoms or oxygen vacancies. The optical and electrical properties of the films were described well by the Burstein-Moss effect. CZTS absorber layers were grown using ultrasonic spray pyrolysis at a deposition temperature of 350 C and subsequently annealed in a sulfurization furnace. Measurements from XRD and Raman spectra confirmed the presence of pure single phase Cu2ZnSnS4 . Texture analysis of as-deposited and annealed CZTS films indicated that the (112) plane which is characteristic of the kesterite phase was preferred. The grain size increased from 50 nm to 100 nm on conducting post-deposition annealing. CZTS films with stoichiometric composition yielded a band gap of 1.5 eV, which is optimal for solar energy conversion. The variation of tin in the film changed its resistivity by several orders of magnitude and subsequently the tin free ternary chalcogenide Cu2ZnS2 having very low resistivity was obtained. By carefully optimization of concentrations of tin, zinc and copper, a zinc-rich/tin-rich/copper-poor composition was found to be most suitable for solar cell applications. Etching of CZTS films using KCN solution reduced their resistivity, possibly due to the elimination of binary copper sulfide phases. CZTS solar cells were fabricated both in the substrate and superstrate configurations.

Author: Jef Poortmans
Publisher: John Wiley & Sons
ISBN: 0470091266
Category : Science
Languages : en
Pages : 504

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Book Description
Thin-film solar cells are either emerging or about to emerge from the research laboratory to become commercially available devices finding practical various applications. Currently no textbook outlining the basic theoretical background, methods of fabrication and applications currently exist. Thus, this book aims to present for the first time an in-depth overview of this topic covering a broad range of thin-film solar cell technologies including both organic and inorganic materials, presented in a systematic fashion, by the scientific leaders in the respective domains. It covers a broad range of related topics, from physical principles to design, fabrication, characterization, and applications of novel photovoltaic devices.

Author: Travis S. Taylor
Publisher: Baen Books
ISBN: 1625795157
Category : Fiction
Languages : en
Pages : 413

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LOOMING DESTRUCTION FROM SPACE! It's the beginning of a new golden age of space exploration. Finally, humanity is taking the commercialization of space to the next level—mining asteroids. The new gold rush of the commercial space era has begun. Another commercial venture, an attempt to put a hotel on the Moon, is seeking the space tourism gold of the ultra wealthy. And it seems as if the dream of finally sending people to Mars is finally going to happen using a ship propelled by a powerful nuclear rocket. But space travel isn’t cut and dry, and there is nothing routine about it. In order to mine an asteroid the goal is to bring it closer to Earth, but orbital mechanics are tricky and close to Earth proves to be far too close for comfort—with looming destruction from space about to become a grim reality. Now astronauts, scientists, engineers, and people in all the burgeoning space businesses must team together to stop the asteroid before it is too late for humanity and the planet it calls home. At the publisher's request, this title is sold without DRM (Digital Rights Management). About Travis S. Taylor: “[E]xplodes with inventive action.”—Publishers Weekly on Travis S. Taylor’s The Quantum Connection. “[Warp Speed] reads like Doc Smith writing Robert Ludlum. . .You won’t want to put it down.”—John Ringo About Rescue Mode by Ben Bova and Les Johnson: "... a suspenseful and compelling narrative of the first human spaceflight to Mars."—Booklist

Author: Goutam Kumar Dalapati
Publisher: Elsevier
ISBN: 0128221038
Category : Technology & Engineering
Languages : en
Pages : 318

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Energy Saving Coating Materials: Design, Process, Implementation and Developments provides comprehensive information regarding recent materials advancements and design aspects and integration for infra-red radiation regulators, along with future developments of zero emission buildings. The key opportunities and challenges for the usage of existing heat regulation materials and their implementation for commercial aspects are explored. The fundamental interaction between electromagnetic waves and materials are discussed, along with materials synthesis, design and integration of coatings for smart window applications. This book presents recent developments of innovative technologies comprising energy saving materials and coatings which are key considerations for achieving vital energy saving milestones. Provides knowledge-based information on the optical properties of materials and their utility for solar energy harvesting and energy saving applications Discusses innovative coatings for smart windows applications, including the progressive development of radiative cooling and cool paint Previews future developments for the synthesis, design and integration of heat regulative materials

Author: William A. Imbriale
Publisher: John Wiley & Sons
ISBN: 0470052775
Category : Technology & Engineering
Languages : en
Pages : 594

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JPL spacecraft antennas-from the first Explorer satellite in 1958 to current R & D Spaceborne Antennas for Planetary Exploration covers the development of Jet Propulsion Laboratory (JPL) spacecraft antennas, beginning with the first Explorer satellite in 1958 through current research and development activities aimed at future missions. Readers follow the evolution of all the new designs and technological innovations that were developed to meet the growing demands of deep space exploration. The book focuses on the radio frequency design and performance of antennas, but covers environmental and mechanical considerations as well. There is additionally a thorough treatment of all the analytical and measurement techniques used in design and performance assessment. Each chapter is written by one or more leading experts in the field of antenna technology. The presentation of the history and technology of spaceborne antennas is aided by several features: * Photographs and drawings of JPL spacecraft * Illustrations to help readers visualize concepts and designs * Tables highlighting and comparing the performance of the antennas * Bibliographies at the end of each chapter leading to a variety of primary and secondary source material This book complements Large Antennas of the Deep Space Network (Wiley 2002), which surveys the ground antennas covered in support of spacecraft. Together, these two books completely cover all JPL antenna technology, in keeping with the JPL Deep Space Communications and Navigation Series mission to capture and present the many innovations in deep space telecommunications over the past decades. This book is a fascinating and informative read for all individuals working in or interested in deep space telecommunications.

Author: Fabian I. Ezema
Publisher: Springer Nature
ISBN: 3030684628
Category : Technology & Engineering
Languages : en
Pages : 926

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Book Description
This book guides beginners in the areas of thin film preparation, characterization, and device making, while providing insight into these areas for experts. As chemically deposited metal oxides are currently gaining attention in development of devices such as solar cells, supercapacitors, batteries, sensors, etc., the book illustrates how the chemical deposition route is emerging as a relatively inexpensive, simple, and convenient solution for large area deposition. The advancement in the nanostructured materials for the development of devices is fully discussed.

Author: Wenyi Huang
Publisher: William Andrew
ISBN: 0323480209
Category : Science
Languages : en
Pages : 272

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Book Description
Nanopapers: From Nanochemistry and Nanomanufacturing to Advanced Applications gives a comprehensive overview of the emerging technology of nanopapers. Exploring the latest developments on nanopapers in nanomaterials chemistry and nanomanufacturing technologies, this book outlines the unique properties of nanopapers and their advanced applications. Nanopapers are thin sheets or films made of nanomaterials such as carbon nanotubes, carbon nanofibers, nanoclays, cellulose nanofibrils, and graphene nanoplatelets. Noticeably, nanopapers allow highly concentrated nanoparticles to be tightly packed in a thin film to reach unique properties such as very high electrical and thermal conductivities, very low diffusivity, and strong corrosion resistance that are shared by conventional polymer nanocomposites. This book presents a concise introduction to nanopapers, covering concepts, terminology and applications. It outlines both current applications and future possibilities, and will be of great use to nanochemistry and nanomanufacturing researchers and engineers who want to learn more about how nanopapers can be applied. - Outlines the main uses of nanopapers, showing readers how this emerging technology should best be applied - Shows how the unique properties of nanopapers make them adaptable for use in a wide range of applications - Explores methods for the nanomanufacture of nanopapers