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Author: Publisher: ISBN: Category : Languages : en Pages : 21
Book Description
Novel chemically bonded phosphate ceramics have been investigated for stabilization and solidification of chloride and nitrate salt wastes. Using low-temperature processing, we stabilized and solidified chloride and nitrate surrogate salts (with hazardous metals) in magnesium potassium phosphate ceramics up to waste loadings of 70-80 wt.%. A variety of characterizations, including strength, microstructure, and leaching, were then conducted on the waste forms. Leaching tests show that all heavy metals in the leachant are well below the EPAs universal treatment standard limits. Long-term leaching tests, per ANS 16. 1 procedure, yields leachability index for nitrate ions> 12. Chloride ions are expected to have an even higher (i.e., better) leachability index. Structural performance of these final waste forms, as indicated by compression strength and durability in aqueous environments, satisfies the regulatory criteria. Thus, based on the results of this study, it seems that phosphate ceramics are viable option for containment of salt wastes.
Author: Publisher: ISBN: Category : Languages : en Pages : 21
Book Description
Novel chemically bonded phosphate ceramics have been investigated for stabilization and solidification of chloride and nitrate salt wastes. Using low-temperature processing, we stabilized and solidified chloride and nitrate surrogate salts (with hazardous metals) in magnesium potassium phosphate ceramics up to waste loadings of 70-80 wt.%. A variety of characterizations, including strength, microstructure, and leaching, were then conducted on the waste forms. Leaching tests show that all heavy metals in the leachant are well below the EPAs universal treatment standard limits. Long-term leaching tests, per ANS 16. 1 procedure, yields leachability index for nitrate ions> 12. Chloride ions are expected to have an even higher (i.e., better) leachability index. Structural performance of these final waste forms, as indicated by compression strength and durability in aqueous environments, satisfies the regulatory criteria. Thus, based on the results of this study, it seems that phosphate ceramics are viable option for containment of salt wastes.
Author: Mark Shand Publisher: Newnes ISBN: 0123919312 Category : Technology & Engineering Languages : en Pages : 336
Book Description
There is an urgent need for innovative, cost-effective, and sustainable approaches to reduce the tremendous environmental impact of conventional cement and cement-based technologies. Consuming a significantly lower quantity of natural resources than conventional cements, with the added ability to effectively sequestering carbon, magnesia cements offer great potential in this area. Magnesia Cements: From Formulation to Application explores the latest developments in this exciting area, reviewing the unique properties offered by these cements, including superior strength, fire resistance, and exceptional ability to bond to a wide range of aggregates, and highlighting their potential role in making cement production and usage more sustainable. Providing detailed analysis of the chemistry, properties, manufacture, and both traditional and novel applications, Magnesia Cements: From Formulation to Application is ideally suited for materials scientists, cement chemists, ceramicists, and engineers involved with the design, development, application and impact assessment of magnesia cements across both academia and industry. - Provides formulary information research into more environmentally friendly cement systems - Discusses chemical phase analysis and the impact of formulation - Applies analysis and history of global uses to provide support for future environmentally stable industrial, building, and non-building applications
Author: Publisher: ISBN: Category : Languages : en Pages : 9
Book Description
During the last three years, Ceramicrete (chemically bonded phosphate ceramics) have been investigated at Argonne-East for low-temperature stabilization and solidification of U.S. Department of Energy (DOE's) mixed wastes, for which conventional high-temperature treatments cannot be used because of volatiles and pyrophorics present in these wastes. This paper summarizes the development of Ceramicrete and provides the current technology status. We discuss our early investigations with surrogates that are typical of DOE mixed wastes, subsequent testing with actual waste streams, and scale-up of the process to an operational level. Current efforts include testing the process at an operational level for an ash waste stream from the Idaho National Engineering Laboratory and obtaining sufficient information to prepare a technology performance report.
Author: Publisher: ISBN: Category : Languages : en Pages : 20
Book Description
Results of an initial investigation of low temperature setting chemically bonded magnesium ammonium phosphate (MAP) ceramics as waste form materials, for solidification and stabilization of radioactive and mixed waste, are reported. The suitability of MAP for solidifying and encapsulating waste materials was tested by encapsulating zeolites at loadings up to [approximately]50 wt%. The resulting composites exhibited very good compressive strength characteristics. Microstructure studies show that zeolite grains remain unreacted in the matrix. Potential uses for solidifying and stab wastes are discussed.
Author: Arun S. Wagh Publisher: Elsevier ISBN: 0080455670 Category : Technology & Engineering Languages : en Pages : 294
Book Description
The first chemically bonded phosphate ceramics (zinc phosphate dental cements) were developed over a century ago. However it has only been in the last 30 years that a new breed of materials has been discovered. Chemically Bonded Phosphate Ceramics brings together latest developments in this field including several novel ceramics, from Argonne and Brookhaven National Laboratories. Coupled with further advances in their use as biomaterials, these materials have found uses in diverse fields in recent years. Applications range from advanced structural materials to oil-well cements and stabilization and encapsulation of hazardous and radioactive waste. Such developments call a single source for their science and applications. This book provides the first comprehensive account to fulfil this need. - Provides a foundation into the latest developments in chemically bonded phosphate ceramics - Explores new CBPC's with a wide range of practical applications - Over 30 years worth of developments and applications in the field available in a single source
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Author: Mark Shand
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Author: Arun S. Wagh