Author: Leopold Gmelin
Publisher: Springer
ISBN: 9783540937449
Category : Science
Languages : en
Pages : 0
Book Description
The volume contains all available information on mononuclear organomolybdenum compounds with one 6L ligand, an additional nD electron donor, and up to three 1L ligands. The main part of the volume deals with the numerous complexes where 6L is benzene or a substituted benzene. The properties, including the spectroscopy, and the reactivity of these complexes are described in detail. A large number of compounds is known where the Mo(CO)3 moiety is bonded to 6L ligands such as cycloheptatriene, cyclooctatriene, cyclooctatetraene, higher carbocycles, or more or less complicated polycyclic carbocycles. C7H8Mo(CO)3 is a versatile starting material for the synthesis of a considerable number of Mo complexes, and these reactions are summarized.
Mo-Organische Verbindungen / Organomolybdenum Compounds 13
Author: Leopold Gmelin
Publisher: Springer
ISBN: 9783540937449
Category : Science
Languages : en
Pages : 0
Book Description
The volume contains all available information on mononuclear organomolybdenum compounds with one 6L ligand, an additional nD electron donor, and up to three 1L ligands. The main part of the volume deals with the numerous complexes where 6L is benzene or a substituted benzene. The properties, including the spectroscopy, and the reactivity of these complexes are described in detail. A large number of compounds is known where the Mo(CO)3 moiety is bonded to 6L ligands such as cycloheptatriene, cyclooctatriene, cyclooctatetraene, higher carbocycles, or more or less complicated polycyclic carbocycles. C7H8Mo(CO)3 is a versatile starting material for the synthesis of a considerable number of Mo complexes, and these reactions are summarized.
Publisher: Springer
ISBN: 9783540937449
Category : Science
Languages : en
Pages : 0
Book Description
The volume contains all available information on mononuclear organomolybdenum compounds with one 6L ligand, an additional nD electron donor, and up to three 1L ligands. The main part of the volume deals with the numerous complexes where 6L is benzene or a substituted benzene. The properties, including the spectroscopy, and the reactivity of these complexes are described in detail. A large number of compounds is known where the Mo(CO)3 moiety is bonded to 6L ligands such as cycloheptatriene, cyclooctatriene, cyclooctatetraene, higher carbocycles, or more or less complicated polycyclic carbocycles. C7H8Mo(CO)3 is a versatile starting material for the synthesis of a considerable number of Mo complexes, and these reactions are summarized.
Gmelin Handbook of Inorganic and Organometallic Chemistry, System Number 53
Author: Leopold Gmelin
Publisher:
ISBN: 9783540936923
Category : Chemistry, Inorganic
Languages : en
Pages : 333
Book Description
Publisher:
ISBN: 9783540936923
Category : Chemistry, Inorganic
Languages : en
Pages : 333
Book Description
Mo-Organische Verbindungen / Organomolybdenum Compounds 10
Author: Lutz Dahlenburg
Publisher: Springer
ISBN: 9783540937241
Category : Science
Languages : en
Pages : 296
Book Description
Publisher: Springer
ISBN: 9783540937241
Category : Science
Languages : en
Pages : 296
Book Description
Mo Organomolybdenum Compounds
Author: Hans Schumann
Publisher: Springer Science & Business Media
ISBN: 3662088576
Category : Science
Languages : en
Pages : 409
Book Description
This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds covered. Volume 5 describes mononuclear organomolybdenum compounds with isocyanide, 3 4 carbene, carbyne, alkynyl, alkene, alkyne, L, and L ligands with and without additional CO groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with 5 one L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the 5 description of L-molybdenum compounds containing two CO groups, but no additional nl 5 ligands. This volume describes L-molybdenum compounds with two CO groups and additional 1 4 L to L ligands. Following the nomenclature used in this series of organomolybdenum com pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron 2 donor Ligand with m donor electrons. Thus 0 denotes a Ligand such as PR . 3 Many of the data, particular those in tables, are given in an abbreviated form without units; for explanations see p. X. Additional information, if necessary, is given before the individual table. Frankfurt am Main Manfred Winter November 1992 Wolfgang Petz X Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarifications.
Publisher: Springer Science & Business Media
ISBN: 3662088576
Category : Science
Languages : en
Pages : 409
Book Description
This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds covered. Volume 5 describes mononuclear organomolybdenum compounds with isocyanide, 3 4 carbene, carbyne, alkynyl, alkene, alkyne, L, and L ligands with and without additional CO groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with 5 one L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the 5 description of L-molybdenum compounds containing two CO groups, but no additional nl 5 ligands. This volume describes L-molybdenum compounds with two CO groups and additional 1 4 L to L ligands. Following the nomenclature used in this series of organomolybdenum com pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron 2 donor Ligand with m donor electrons. Thus 0 denotes a Ligand such as PR . 3 Many of the data, particular those in tables, are given in an abbreviated form without units; for explanations see p. X. Additional information, if necessary, is given before the individual table. Frankfurt am Main Manfred Winter November 1992 Wolfgang Petz X Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarifications.
Mo-Organische Verbindungen / Organomolybdenum Compounds 5
Author: SPRINGER VERLAG
Publisher: Springer
ISBN: 9783540936619
Category : Science
Languages : en
Pages : 430
Book Description
This volume deals with mononuclear organomolybdenum compounds with organic ligands bonded by one to four carbon atoms to molybdenum with and without additional CO groups. These compounds can contain neutral donor ligands (e.g. amines, phosphanes, or nitriles) or ionic ligands (e.g. halides or pyrazolyl derivatives). The combination of these ligands leads to a great number of different types of compounds. The first sections describe compounds with isocyanide, carbene, carbyne, and acetylide ligands, e.g. compounds of the types (CO3)Mo(CNR)N2C10H8, RC(O)C(R')=MO(CO)5, RChMo(CO)4X, or K3 Ä(RChC)3Mo(CO=)3Ü. The following sections deal with compounds having alkene, alkyne, and allyl derivatives as ligands. The volume concludes with a description of compounds with ligands forming four Mo-C bonds. Most of these ligands are dienes. Compounds with trimethylene methane ligands, e.g. (CH2)3CMo(CO)4, are included. Among the many types of reactions described displacement of the diene ligand is the most common one. In particular, the norbarnadiene complex, C7H8Mo(CO)4, is the most widely used for the preparation of tetracarbonylmolybdenum compounds. An empirical formula and ligand index completes the volume.
Publisher: Springer
ISBN: 9783540936619
Category : Science
Languages : en
Pages : 430
Book Description
This volume deals with mononuclear organomolybdenum compounds with organic ligands bonded by one to four carbon atoms to molybdenum with and without additional CO groups. These compounds can contain neutral donor ligands (e.g. amines, phosphanes, or nitriles) or ionic ligands (e.g. halides or pyrazolyl derivatives). The combination of these ligands leads to a great number of different types of compounds. The first sections describe compounds with isocyanide, carbene, carbyne, and acetylide ligands, e.g. compounds of the types (CO3)Mo(CNR)N2C10H8, RC(O)C(R')=MO(CO)5, RChMo(CO)4X, or K3 Ä(RChC)3Mo(CO=)3Ü. The following sections deal with compounds having alkene, alkyne, and allyl derivatives as ligands. The volume concludes with a description of compounds with ligands forming four Mo-C bonds. Most of these ligands are dienes. Compounds with trimethylene methane ligands, e.g. (CH2)3CMo(CO)4, are included. Among the many types of reactions described displacement of the diene ligand is the most common one. In particular, the norbarnadiene complex, C7H8Mo(CO)4, is the most widely used for the preparation of tetracarbonylmolybdenum compounds. An empirical formula and ligand index completes the volume.
Mo Organomolybdenum Compounds
Author: Hans Schumann
Publisher: Springer
ISBN: 9783662088593
Category : Science
Languages : en
Pages : 396
Book Description
This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds covered. Volume 5 describes mononuclear organomolybdenum compounds with isocyanide, 3 4 carbene, carbyne, alkynyl, alkene, alkyne, L, and L ligands with and without additional CO groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with 5 one L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the 5 description of L-molybdenum compounds containing two CO groups, but no additional nl 5 ligands. This volume describes L-molybdenum compounds with two CO groups and additional 1 4 L to L ligands. Following the nomenclature used in this series of organomolybdenum com pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron 2 donor Ligand with m donor electrons. Thus 0 denotes a Ligand such as PR . 3 Many of the data, particular those in tables, are given in an abbreviated form without units; for explanations see p. X. Additional information, if necessary, is given before the individual table. Frankfurt am Main Manfred Winter November 1992 Wolfgang Petz X Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarifications.
Publisher: Springer
ISBN: 9783662088593
Category : Science
Languages : en
Pages : 396
Book Description
This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds covered. Volume 5 describes mononuclear organomolybdenum compounds with isocyanide, 3 4 carbene, carbyne, alkynyl, alkene, alkyne, L, and L ligands with and without additional CO groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with 5 one L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the 5 description of L-molybdenum compounds containing two CO groups, but no additional nl 5 ligands. This volume describes L-molybdenum compounds with two CO groups and additional 1 4 L to L ligands. Following the nomenclature used in this series of organomolybdenum com pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron 2 donor Ligand with m donor electrons. Thus 0 denotes a Ligand such as PR . 3 Many of the data, particular those in tables, are given in an abbreviated form without units; for explanations see p. X. Additional information, if necessary, is given before the individual table. Frankfurt am Main Manfred Winter November 1992 Wolfgang Petz X Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarifications.
Gmelin Handbook of Inorganic and Organometallic Chemistry
Author: Leopold Gmelin
Publisher: Springer-Verlag
ISBN: 9783540937432
Category : Science
Languages : en
Pages : 395
Book Description
The C5H5Mo(CO)3 unit is among the most ubiquitous fragments in organometallic chemistry. The present volume first describes neutal compounds of the type C5H5Mo(CO)31L (1L = alkyl, vinyl, aryl, and alkynyl) and the C5H5Mo(CO)3=CR2 + cations. Many of the C5H5Mo(CO)31L compounds are important precursors in organometallic synthesis. Typical reactions are the insertion of electrophiles into the Mo-1L bond, e.g., the insertion of SO2 with the formation of sulfinato derivatives. The kind of products formed in substitution reactions of the CO groups by nucleophiles depends strongly on the 1L ligand. The second part of the volume deals with compounds with one 5LMo(CO)3 fragment (5L is a general organic ligand bonded by five carbon atoms to the metal, e.g., substituted cyclopentadienyl or open-chain pentadienyl derivatives).
Publisher: Springer-Verlag
ISBN: 9783540937432
Category : Science
Languages : en
Pages : 395
Book Description
The C5H5Mo(CO)3 unit is among the most ubiquitous fragments in organometallic chemistry. The present volume first describes neutal compounds of the type C5H5Mo(CO)31L (1L = alkyl, vinyl, aryl, and alkynyl) and the C5H5Mo(CO)3=CR2 + cations. Many of the C5H5Mo(CO)31L compounds are important precursors in organometallic synthesis. Typical reactions are the insertion of electrophiles into the Mo-1L bond, e.g., the insertion of SO2 with the formation of sulfinato derivatives. The kind of products formed in substitution reactions of the CO groups by nucleophiles depends strongly on the 1L ligand. The second part of the volume deals with compounds with one 5LMo(CO)3 fragment (5L is a general organic ligand bonded by five carbon atoms to the metal, e.g., substituted cyclopentadienyl or open-chain pentadienyl derivatives).
Molybdenum: Mononuclear compounds
Author: Irene Kersting
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 274
Book Description
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 274
Book Description
Mo Organomolybdenum Compounds
Author: Lutz Dahlenburg
Publisher:
ISBN: 9780387937243
Category : Chemistry, Inorganic
Languages : en
Pages : 296
Book Description
Publisher:
ISBN: 9780387937243
Category : Chemistry, Inorganic
Languages : en
Pages : 296
Book Description