Metastability

Metastability PDF Author: Anton Bovier
Publisher: Springer
ISBN: 3319247778
Category : Mathematics
Languages : en
Pages : 578

Book Description
This monograph provides a concise presentation of a mathematical approach to metastability, a wide-spread phenomenon in the dynamics of non-linear systems - physical, chemical, biological or economic - subject to the action of temporal random forces typically referred to as noise, based on potential theory of reversible Markov processes. The authors shed new light on the metastability phenomenon as a sequence of visits of the path of the process to different metastable sets, and focuses on the precise analysis of the respective hitting probabilities and hitting times of these sets. The theory is illustrated with many examples, ranging from finite-state Markov chains, finite-dimensional diffusions and stochastic partial differential equations, via mean-field dynamics with and without disorder, to stochastic spin-flip and particle-hop dynamics and probabilistic cellular automata, unveiling the common universal features of these systems with respect to their metastable behaviour. The monograph will serve both as comprehensive introduction and as reference for graduate students and researchers interested in metastability.

Large Deviations and Metastability

Large Deviations and Metastability PDF Author: Enzo Olivieri
Publisher: Cambridge University Press
ISBN: 9780521591638
Category : Mathematics
Languages : en
Pages : 540

Book Description
Publisher Description

Metastability and Markov State Models in Molecular Dynamics

Metastability and Markov State Models in Molecular Dynamics PDF Author: Christof Schütte
Publisher: American Mathematical Soc.
ISBN: 0821843591
Category : Mathematics
Languages : en
Pages : 141

Book Description
Applications in modern biotechnology and molecular medicine often require simulation of biomolecular systems in atomic representation with immense length and timescales that are far beyond the capacity of computer power currently available. As a consequence, there is an increasing need for reduced models that describe the relevant dynamical properties while at the same time being less complex. In this book the authors exploit the existence of metastable sets for constructing such a reduced molecular dynamics model, the so-called Markov state model (MSM), with good approximation properties on the long timescales. With its many examples and illustrations, this book is addressed to graduate students, mathematicians, and practical computational scientists wanting an overview of the mathematical background for the ever-increasing research activity on how to construct MSMs for very different molecular systems ranging from peptides to proteins, from RNA to DNA, and via molecular sensors to molecular aggregation. This book bridges the gap between mathematical research on molecular dynamics and its practical use for realistic molecular systems by providing readers with tools for performing in-depth analysis of simulation and data-analysis methods. Titles in this series are co-published with the Courant Institute of Mathematical Sciences at New York University.

Collapse of Metastability

Collapse of Metastability PDF Author: Seiji Miyashita
Publisher: Springer Nature
ISBN: 9811966680
Category : Science
Languages : en
Pages : 260

Book Description
To understand phenomena in nature, it is important to focus not only on properties of stationary states, but also their changes in time, that is, the dynamics between bistable states. This book reviews the mechanics of first-order phase transitions and discusses relaxation and collapses of metastable states from various viewpoints, including Kramers' method for the lifetime of metastability, Langer’s analysis on the singularity, effects of thermal fluctuation studied by Néel and Brown, and eigenvalue structures of the transfer-matrix for the phase transitions. The book also goes into the mechanics of metastability in quantum systems from the viewpoints of the eigenvalue problem of the Hamiltonian and the Liouvillian for a dynamical process and discusses relations between quantum tunneling processes and metastability therein. Lastly, the coercivity of magnets consisting of an ensemble of grains is reviewed. The book is beneficial for those new in the field as a primer on first-order phase transition from modern perspectives. The comprehensive content offers overviews of related topics and allows readers to quickly catch up with developments in the field.

Metastable Liquids

Metastable Liquids PDF Author: Pablo G. Debenedetti
Publisher: Princeton University Press
ISBN: 9780691085951
Category : Science
Languages : en
Pages : 432

Book Description
Building on the interplay of kinetics and thermodynamics that determines the thermophysical properties and structural relaxation of metastable liquids, it offers an in-depth treatment of thermodynamic stability theory, the statistical mechanics of metastability, nucleation, spinodal decomposition, supercooled liquids, and the glass transition.

Phase Transitions in Polymers: The Role of Metastable States

Phase Transitions in Polymers: The Role of Metastable States PDF Author: Stephen Z.D. Cheng
Publisher: Elsevier
ISBN: 0080558208
Category : Science
Languages : en
Pages : 325

Book Description
A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics.* Written by a leading scholar and industry expert* Presents new and cutting edge material encouraging innovation and future research* Connects hot topics and leading research in one concise volume

Photo-Induced Metastability in Amorphous Semiconductors

Photo-Induced Metastability in Amorphous Semiconductors PDF Author: Alexander V. Kolobov
Publisher: John Wiley & Sons
ISBN: 3527608664
Category : Science
Languages : en
Pages : 436

Book Description
A review summarising the current state of research in the field, bridging the gaps in the existing literature. All the chapters are written by world leaders in research and development and guide readers through the details of photo-induced metastability and the results of the latest experiments and simulations not found in standard monographs on this topic. A useful reference not only for graduates but also for scientific and industrial researchers. With a foreword of Kazunobu Tanaka

Chalcogenides

Chalcogenides PDF Author: Alexander V. Kolobov
Publisher: Springer Science & Business Media
ISBN: 3642287050
Category : Technology & Engineering
Languages : en
Pages : 288

Book Description
A state-of-the-art description of metastability observed in chalcogenide alloys is presented with the accent on the underlying physics. A comparison is made between sulphur(selenium)-based chalcogenide glasses, where numerous photo-induced phenomena take place entirely within the amorphous phase, and tellurides where a reversible crystal-to-amorphous phase-change transformation is a major effect. Applications of metastability in devices¿optical memories and nonvolatile electronic phase-change random-access memories among others are discussed, including the latest trends. Background material essential for understanding current research in the field is also provided.

Adaptive Techniques for Dynamic Processor Optimization

Adaptive Techniques for Dynamic Processor Optimization PDF Author: Alice Wang
Publisher: Springer Science & Business Media
ISBN: 0387764720
Category : Technology & Engineering
Languages : en
Pages : 312

Book Description
This book is about various adaptive and dynamic techniques used to optimize processor power and performance. It is based on a very successful forum at ISSCC which focused on Adaptive Techniques. The book looks at the underlying process technology for adaptive designs and then examines different circuits, architecture and software that address the different aspects. The chapters are written by people both in academia and the industry to show the scope of alternative practices.

All-Digital Frequency Synthesizer in Deep-Submicron CMOS

All-Digital Frequency Synthesizer in Deep-Submicron CMOS PDF Author: Robert Bogdan Staszewski
Publisher: John Wiley & Sons
ISBN: 0470041943
Category : Technology & Engineering
Languages : en
Pages : 281

Book Description
A new and innovative paradigm for RF frequency synthesis and wireless transmitter design Learn the techniques for designing and implementing an all-digital RF frequency synthesizer. In contrast to traditional RF techniques, this innovative book sets forth digitally intensive design techniques that lead the way to the development of low-cost, low-power, and highly integrated circuits for RF functions in deep submicron CMOS processes. Furthermore, the authors demonstrate how the architecture enables readers to integrate an RF front-end with the digital back-end onto a single silicon die using standard ASIC design flow. Taking a bottom-up approach that progressively builds skills and knowledge, the book begins with an introduction to basic concepts of frequency synthesis and then guides the reader through an all-digital RF frequency synthesizer design: Chapter 2 presents a digitally controlled oscillator (DCO), which is the foundation of a novel architecture, and introduces a time-domain model used for analysis and VHDL simulation Chapter 3 adds a hierarchical layer of arithmetic abstraction to the DCO that makes it easier to operate algorithmically Chapter 4 builds a phase correction mechanism around the DCO such that the system's frequency drift or wander performance matches that of the stable external frequency reference Chapter 5 presents an application of the all-digital RF synthesizer Chapter 6 describes the behavioral modeling and simulation methodology used in design The final chapter presents the implementation of a full transmitter and experimental results. The novel ideas presented here have been implemented and proven in two high-volume, commercial single-chip radios developed at Texas Instruments: Bluetooth and GSM. While the focus of the book is on RF frequency synthesizer design, the techniques can be applied to the design of other digitally assisted analog circuits as well. This book is a must-read for students and engineers who want to learn a new paradigm for RF frequency synthesis and wireless transmitter design using digitally intensive design techniques.