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Kinetics of the Thermal Decomposition of Uranyl Fluoride

Kinetics of the Thermal Decomposition of Uranyl Fluoride PDF Author: L. M. Ferris
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 30

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Kinetics of the Thermal Decomposition of Uranyl Fluoride

Kinetics of the Thermal Decomposition of Uranyl Fluoride PDF Author: L. M. Ferris
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 30

Book Description


Kinetics of the Thermal Decomposition of Uranyl Fluoride. I. Preliminary Results

Kinetics of the Thermal Decomposition of Uranyl Fluoride. I. Preliminary Results PDF Author:
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Category :
Languages : en
Pages :

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The thermal decomposition of uranyl fluoride was studied by a thermogravimetric technique between 750 and 880 deg C. The decomposition reaction at atmospheric pressure is 3 UO/sub 2/F/sub 2/ yields 2/3 U/sub 3/O/sub 8/ + UF/ sub 6/ + 1/3 O/sub 2/. In dry helium the rate of reaction was first order with respect to the mass of UO/sub 2/F/sub 2/, with indications that it also was dependent on the gas flow rate. The rate constants, determined with a constant flow rate of dry helium, may be expressed as log k (min/sup -1/) = 11.57--15700/T. In preliminary experiments with dry air and oxygen the rate decreased with increasing oxygen partial pressure; however, data were insufficient for a quantitative relation to be derived. UO/sub 2/F/sub 2/ sublimed, as a parallel first-order proccss, at temperatures above 825 deg C. (auth).

Nuclear Science Abstracts

Nuclear Science Abstracts PDF Author:
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ISBN:
Category : Nuclear energy
Languages : en
Pages : 988

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Recycle of UO2F2 in the Fluorox Process

Recycle of UO2F2 in the Fluorox Process PDF Author: L. M. Ferris
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Category : Hydrogen
Languages : en
Pages : 22

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Articles Published in Technical Journals, Reports Published, Papers Presented at the Geneva Conference, at Scientific Meetings, and Inventions Disclosed During 1958 by ORNL Staff Members

Articles Published in Technical Journals, Reports Published, Papers Presented at the Geneva Conference, at Scientific Meetings, and Inventions Disclosed During 1958 by ORNL Staff Members PDF Author: Oak Ridge National Laboratory
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Category : Atomic energy research
Languages : en
Pages : 96

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Uranium Production Technology

Uranium Production Technology PDF Author: Charles D. Harrington
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Category : Nuclear fuels
Languages : en
Pages : 600

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Articles Published in Technical Journals and Reports Published During 1958 by ORNL Staff Members

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Category : Nuclear physics
Languages : en
Pages : 52

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Uranium: Alloys and compounds. 1936-1958

Uranium: Alloys and compounds. 1936-1958 PDF Author: United States Dept. of Commerce. Office of Technical Services
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Category : Uranium
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Category : Nuclear energy
Languages : en
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ISBN:
Category : Science
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