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Author: Konstantin N. Mikhelson Publisher: Springer Science & Business Media ISBN: 3642368867 Category : Science Languages : en Pages : 170
Book Description
Ion-selective electrodes (ISEs) have a wide range of applications in clinical, environmental, food and pharmaceutical analysis as well as further uses in chemistry and life sciences. Based on his profound experience as a researcher in ISEs and a course instructor, the author summarizes current knowledge for advanced teaching and training purposes with a particular focus on ionophore-based ISEs. Coverage includes the basics of measuring with ISEs, essential membrane potential theory and a comprehensive overview of the various classes of ion-selective electrodes. The principles of constructing ISEs are outlined, and the transfer of methods into routine analysis is considered. Advanced students, researchers, and practitioners will benefit from this expedient introduction.
Author: Konstantin N. Mikhelson Publisher: Springer Science & Business Media ISBN: 3642368867 Category : Science Languages : en Pages : 170
Book Description
Ion-selective electrodes (ISEs) have a wide range of applications in clinical, environmental, food and pharmaceutical analysis as well as further uses in chemistry and life sciences. Based on his profound experience as a researcher in ISEs and a course instructor, the author summarizes current knowledge for advanced teaching and training purposes with a particular focus on ionophore-based ISEs. Coverage includes the basics of measuring with ISEs, essential membrane potential theory and a comprehensive overview of the various classes of ion-selective electrodes. The principles of constructing ISEs are outlined, and the transfer of methods into routine analysis is considered. Advanced students, researchers, and practitioners will benefit from this expedient introduction.
Author: Henry Freiser Publisher: Springer Science & Business Media ISBN: 1468437763 Category : Science Languages : en Pages : 300
Book Description
We continue in this second volume the plan evident in the first; i.e., of presenting a number of well-rounded up-to-date reviews of important developments in the exciting field of ion-selective electrodes in analytical chemistry. In this volume, in addition to the exciting applications of ISE'S to biochemistry systems represented by the description of enzyme electrodes, there is featured the most recent development in ISE'S, namely, the joining of the electrochemical and solid state expertise, resulting in CHEMFETS. The scholarly survey of the current status of ISE'S will undoubtedly be welcomed by all workers in the field. Tucson, Arizona Henry Freiser vii Contents Chapter 1 Potentiometric Enzyme Methods Robert K. Kobos 1. Introduction . . . . . . 1 2. Soluble Enzyme Systems . . . 5 2.1. Substrate Determinations 5 2.2. Enzyme Determinations . 13 2.3. Inhibitor Determinations. 18 3. Immobilized Enzyme Systems . 19 3.1. Methods of Immobilization. 19 3.2. Characteristics of Immobilized Enzymes 23 3.3. Analytical Applications with Ion-Selective Electrodes 23 4. Enzyme Electrodes 31 4.1. Urea Electrodes 35 4.2. Amygdalin Electrodes 39 4.3. Glucose Electrodes . 40 4.4. Penicillin Electrodes 40 4.5. Amino Acid Electrodes 41 4.6. Nucleotide Electrodes 46 4.7. Uric Acid Electrode 47 4.8. Creatinine Electrode 48 48 4.9. Acetylcholine Electrodes. 4.10. D-Gluconate Electrode 49 4.11. Lactate Electrode 49 4.12. Inhibitor Determination 50 4.13. Substrate Electrodes 50 4.14. Current Trends . . . .
Author: Joseph Wang Publisher: John Wiley & Sons ISBN: 0471460796 Category : Science Languages : en Pages : 228
Book Description
The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays
Author: K. Cammann Publisher: Springer Science & Business Media ISBN: 3642672760 Category : Science Languages : en Pages : 239
Book Description
The first section introduces the electrochemical nomenclature necessary for under standing the literature on ion-selective electrodes and discusses the general principles behind all electrodes. The second section is concerned with the problems which arise in any accurate elec trode potential measurement in practice. Here the most important reference electrodes are discussed with special reference to their use in conjunction with ion-selective elec trodes. From experience, almost 75% of all problems which arise when working with ion-selective electrodes are on account of the reference electrode. After the reader is aquainted with the basic problems involved, the third section deals with individual ion-selective electrodes; their properties, handling and methods of pre paration. Here the discussion of these electrodes is not arranged according to the spe cies detected, but rather according to the kind of construction, since from this view point characteristic properties are much the same and handling procedures need only be described once for an entire series of similar electrodes. The fourth section discusses amplifiers. Here the problems of high-ohmic EMF meas urements such as noise level, insulation, static charging and ground loops are discussed. The fifth section is devoted to the various evaluation methods. Here a few schemes and examples are provided to indicate optimum practical procedures and the accura cies attainable with the various methods are discussed. The last section describes special set-ups such as clinical flow-thru cells, microelec trodes for measuring intracellular ionic activities, industrial on-line techniques and continuous environmental protection monitors.
Author: D Pletcher Publisher: Elsevier ISBN: 1782420541 Category : Science Languages : en Pages : 444
Book Description
Using 372 references and 211 illustrations, this book underlines the fundamentals of electrochemistry essential to the understanding of laboratory experiments. It treats not only the fundamental concepts of electrode reactions, but also covers the methodology and practical application of the many versatile electrochemical techniques available. - Underlines the fundamentals of electrochemistry essential to the understanding of laboratory experiments - Treats the fundamental concepts of electrode reactions - Covers the methodology and practical application of the many versatile electrochemical techniques available
Author: W.E. Morf Publisher: Elsevier ISBN: 0444597557 Category : Science Languages : en Pages : 446
Book Description
The Principles of Ion Selective Electrodes and of Membrane Transport is a collection of research works on the theory, principles, and fundamentals of ion-selective electrodes and of membrane transport. This book is organized into two parts encompassing 15 chapters that highlight the application of the membrane model. Part A is a general discussion of membrane potentials and membrane transport. This part describes the formulations of the interfacial potential contribution due to phase boundaries. This part also explores the diffusion potential, the nonideality of diffusion layers or membrane phases, the liquid-junction potential arising in conventional potentiometric measuring cells. Other topics covered in this part include the practical solution for the membrane potential; the ion-transport and the electrical properties of bulk membranes; and the characteristics of lipid bilayer membranes. Part B considers the fundamentals of ion-selective electrodes. This part begins with discussions of the principles, response behavior, ion selectivity, and detection limits of solid-state membrane electrodes. This part also examines several important extensions and modifications of the Sandblom-Eisenman-Walker theory; the characteristics of neutral carrier membrane electrodes; and the theory of glass electrodes.
Author: N Lakshminarayanaiah Publisher: Elsevier ISBN: 0323153291 Category : Science Languages : en Pages : 379
Book Description
Membrane Electrodes considers the significant developments in the field of sensing probes, with an emphasis on membrane electrodes. This book is organized into three parts encompassing 11 chapters. Part I is an introduction to the variety of ion-selective membrane electrodes that have been constructed and with which experiments have been conducted. This part deals first with the thermodynamic principles and other concepts underlying the description of the behavior of electrolyte solutions, followed by a discussion on the various theories of membrane potential applicable to a variety of solid and liquid membrane electrodes. Part II describes the preparation, properties, and uses of the various solid and liquid membrane electrodes. Part III presents glass membrane electrodes as a prelude to the description of other membrane systems in which glass electrodes are invariably used as the primary sensing device. This book will prove useful to students, technologists, and researchers in various fields of science and technology.
Author: Alun Evans Publisher: John Wiley & Sons ISBN: 9788126517329 Category : Languages : en Pages : 328
Book Description
The book provides a basic introduction to potentiometry and the use of ion-selective electrodes in chemical analysis. Written largely from first principles, this self-contained treatment develops the ideas behind the practice and explains the techniques of potentiometry in language the practitioner or student can understand. The author explains procedures step by step, and makes liberal use of worked examples and problems. Thus, the text is best ``worked through'', rather than just read or memorized.· Summary of Basic Principles· General Principles of Potentiometry· Method of Operation of Ion-Selective Electrodes· Applications
Author: Xueji Zhang Publisher: Academic Press ISBN: 008055489X Category : Science Languages : en Pages : 625
Book Description
This book broadly reviews the modem techniques and significant applications of chemical sensors and biosensors. Chapters are written by experts in the field – including Professor Joseph Wang, the most cited scientist in the world and renowned expert on sensor science who is also co-editor. Each chapter provides technical details beyond the level found in typical journal articles, and explores the application of chemical sensors and biosensors to a significant problem in biomedical science, also providing a prospectus for the future.This book compiles the expert knowledge of many specialists in the construction and use of chemical sensors and biosensors including nitric oxide sensors, glucose sensors, DNA sensors, hydrogen sulfide sensors, oxygen sensors, superoxide sensors, immuno sensors, lab on chip, implatable microsensors, et al. Emphasis is laid on practical problems, ranging from chemical application to biomedical monitoring and from in vitro to in vivo, from single cell to animal to human measurement. This provides the unique opportunity of exchanging and combining the expertise of otherwise apparently unrelated disciplines of chemistry, biological engineering, and electronic engineering, medical, physiological. - Provides user-oriented guidelines for the proper choice and application of new chemical sensors and biosensors - Details new methodological advancements related to and correlated with the measurement of interested species in biomedical samples - Contains many case studies to illustrate the range of application and importance of the chemical sensors and biosensors
Author: Henry Freiser Publisher: Springer Science & Business Media ISBN: 1468425927 Category : Science Languages : en Pages : 448
Book Description
Ion-selective electrodes continue to be one of the more excIting developments in electro analytical chemistry in the last 10 years. This is evidenced in the large and continually growing literature in the field. It is important and necessary in such a rapidly growing area to be able to "take stock," i. e. , to present a well-rounded, up-to-date review of important developments. In this volume, reviews by many of the leading practitioners and pioneers in this field contribute to what we consider to be a generous coverage of both fundamental aspects of ion-selective electrodes and their applications to analytical chemistry. Although this volume is not intended to be exhaustive, we have attempted to produce a "stand alone" text dealing with all major current developments. Indeed, since some of the theoretical approaches are not yet universally agreed on, each of the first five chapters deals with theory and principles of the nature and behavior of ion-selective electrodes from the vantage point of the authors' own experience and understanding. In view of the rapid expansion of this field, plans for future volumes are now being formulated. Henry Freiser Tucson, Arizona vii Contents Chapter 1 Theory and Principles of Membrane Electrodes R. P. Buck 1. Potential Generating Processes . . . . . . . . . . . . . . . . 1 1. 1. Interfaces, Fixed Charges, Charged Sites, and Charge Carriers 1 1. 2. Ion Exchange as a Potential-Generating Process 5 1. 3. Diffusion and Migration . . . . . . . . . . . . 8 1. 4. Electrochemical Potentials, Fluxes, and Mobility . . 10 1. 5.
Author: Konstantin N. Mikhelson
Author: Konstantin N. Mikhelson
Author: Henry Freiser
Author: Joseph Wang
Author: K. Cammann
Author: D Pletcher
Author: W.E. Morf
Author: N Lakshminarayanaiah
Author: Alun Evans
Author: Xueji Zhang
Author: Henry Freiser