Invariant Manifolds for Physical and Chemical Kinetics PDF Download

Author: Alexander N. Gorban
Publisher: Springer Science & Business Media
ISBN: 9783540226840
Category : Science
Languages : en
Pages : 524

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Book Description
By bringing together various ideas and methods for extracting the slow manifolds, the authors show that it is possible to establish a more macroscopic description in nonequilibrium systems. The book treats slowness as stability. A unifying geometrical viewpoint of the thermodynamics of slow and fast motion enables the development of reduction techniques, both analytical and numerical. Examples considered in the book range from the Boltzmann kinetic equation and hydrodynamics to the Fokker-Planck equations of polymer dynamics and models of chemical kinetics describing oxidation reactions. Special chapters are devoted to model reduction in classical statistical dynamics, natural selection, and exact solutions for slow hydrodynamic manifolds. The book will be a major reference source for both theoretical and applied model reduction. Intended primarily as a postgraduate-level text in nonequilibrium kinetics and model reduction, it will also be valuable to PhD students and researchers in applied mathematics, physics and various fields of engineering.

Author: Frédérique Battin-Leclerc
Publisher: Springer Science & Business Media
ISBN: 1447153073
Category : Technology & Engineering
Languages : en
Pages : 657

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Book Description
This overview compiles the on-going research in Europe to enlarge and deepen the understanding of the reaction mechanisms and pathways associated with the combustion of an increased range of fuels. Focus is given to the formation of a large number of hazardous minor pollutants and the inability of current combustion models to predict the formation of minor products such as alkenes, dienes, aromatics, aldehydes and soot nano-particles which have a deleterious impact on both the environment and on human health. Cleaner Combustion describes, at a fundamental level, the reactive chemistry of minor pollutants within extensively validated detailed mechanisms for traditional fuels, but also innovative surrogates, describing the complex chemistry of new environmentally important bio-fuels. Divided into five sections, a broad yet detailed coverage of related research is provided. Beginning with the development of detailed kinetic mechanisms, chapters go on to explore techniques to obtain reliable experimental data, soot and polycyclic aromatic hydrocarbons, mechanism reduction and uncertainty analysis, and elementary reactions. This comprehensive coverage of current research provides a solid foundation for researchers, managers, policy makers and industry operators working in or developing this innovative and globally relevant field.

Author: Alexander N. Gorban
Publisher: Springer Science & Business Media
ISBN: 3642149413
Category : Mathematics
Languages : en
Pages : 356

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Book Description
This volume contains the extended version of selected talks given at the international research workshop "Coping with Complexity: Model Reduction and Data Analysis", Ambleside, UK, August 31 – September 4, 2009. The book is deliberately broad in scope and aims at promoting new ideas and methodological perspectives. The topics of the chapters range from theoretical analysis of complex and multiscale mathematical models to applications in e.g., fluid dynamics and chemical kinetics.

Author: Johannes Janicka
Publisher: Springer Science & Business Media
ISBN: 9400753209
Category : Technology & Engineering
Languages : en
Pages : 495

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Book Description
With regard to both the environmental sustainability and operating efficiency demands, modern combustion research has to face two main objectives, the optimization of combustion efficiency and the reduction of pollutants. This book reports on the combustion research activities carried out within the Collaborative Research Center (SFB) 568 “Flow and Combustion in Future Gas Turbine Combustion Chambers” funded by the German Research Foundation (DFG). This aimed at designing a completely integrated modeling and numerical simulation of the occurring very complex, coupled and interacting physico-chemical processes, such as turbulent heat and mass transport, single or multi-phase flows phenomena, chemical reactions/combustion and radiation, able to support the development of advanced gas turbine chamber concepts

Author: Guy B. Marin
Publisher: John Wiley & Sons
ISBN: 3527342958
Category : Science
Languages : en
Pages : 462

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Book Description
This second, extended and updated edition presents the current state of kinetics of chemical reactions, combining basic knowledge with results recently obtained at the frontier of science. Special attention is paid to the problem of the chemical reaction complexity with theoretical and methodological concepts illustrated throughout by numerous examples taken from heterogeneous catalysis combustion and enzyme processes. Of great interest to graduate students in both chemistry and chemical engineering.

Author: Monika Heiner
Publisher: Springer
ISBN: 3540885625
Category : Science
Languages : en
Pages : 413

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Book Description
This book constitutes the refereed proceedings of the 6th International Conference on Computational Methods in Systems Biology, CMSB 2008, held in Rostock, Germany, in September 2008. The 21 revised full papers presented together with the summaries of 5 invited papers were carefully reviewed and selected from more than 60 submissions. The papers cover theoretical or applied contributions that are motivated by a biological question focusing on modeling approaches, including process algebra, simulation approaches, analysis methods, in particular model checking and flux analysis, and case studies.

Author: Alexander N. Gorban
Publisher: Springer Science & Business Media
ISBN: 3540358889
Category : Science
Languages : en
Pages : 554

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Book Description
Model reduction and coarse-graining are important in many areas of science and engineering. How does a system with many degrees of freedom become one with fewer? How can a reversible micro-description be adapted to the dissipative macroscopic model? These crucial questions, as well as many other related problems, are discussed in this book. All contributions are by experts whose specialities span a wide range of fields within science and engineering.

Author: Tarek Echekki
Publisher: Springer Science & Business Media
ISBN: 9400704127
Category : Technology & Engineering
Languages : en
Pages : 496

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Book Description
Turbulent combustion sits at the interface of two important nonlinear, multiscale phenomena: chemistry and turbulence. Its study is extremely timely in view of the need to develop new combustion technologies in order to address challenges associated with climate change, energy source uncertainty, and air pollution. Despite the fact that modeling of turbulent combustion is a subject that has been researched for a number of years, its complexity implies that key issues are still eluding, and a theoretical description that is accurate enough to make turbulent combustion models rigorous and quantitative for industrial use is still lacking. In this book, prominent experts review most of the available approaches in modeling turbulent combustion, with particular focus on the exploding increase in computational resources that has allowed the simulation of increasingly detailed phenomena. The relevant algorithms are presented, the theoretical methods are explained, and various application examples are given. The book is intended for a relatively broad audience, including seasoned researchers and graduate students in engineering, applied mathematics and computational science, engine designers and computational fluid dynamics (CFD) practitioners, scientists at funding agencies, and anyone wishing to understand the state-of-the-art and the future directions of this scientifically challenging and practically important field.

Author: Tamás Turányi
Publisher: Springer
ISBN: 366244562X
Category : Science
Languages : en
Pages : 369

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Book Description
Chemical processes in many fields of science and technology, including combustion, atmospheric chemistry, environmental modelling, process engineering, and systems biology, can be described by detailed reaction mechanisms consisting of numerous reaction steps. This book describes methods for the analysis of reaction mechanisms that are applicable in all these fields. Topics addressed include: how sensitivity and uncertainty analyses allow the calculation of the overall uncertainty of simulation results and the identification of the most important input parameters, the ways in which mechanisms can be reduced without losing important kinetic and dynamic detail, and the application of reduced models for more accurate engineering optimizations. This monograph is invaluable for researchers and engineers dealing with detailed reaction mechanisms, but is also useful for graduate students of related courses in chemistry, mechanical engineering, energy and environmental science and biology.

Author: Denis Constales
Publisher: Elsevier
ISBN: 0444594841
Category : Technology & Engineering
Languages : en
Pages : 416

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Book Description
Advanced Data Analysis and Modeling in Chemical Engineering provides the mathematical foundations of different areas of chemical engineering and describes typical applications. The book presents the key areas of chemical engineering, their mathematical foundations, and corresponding modeling techniques. Modern industrial production is based on solid scientific methods, many of which are part of chemical engineering. To produce new substances or materials, engineers must devise special reactors and procedures, while also observing stringent safety requirements and striving to optimize the efficiency jointly in economic and ecological terms. In chemical engineering, mathematical methods are considered to be driving forces of many innovations in material design and process development. - Presents the main mathematical problems and models of chemical engineering and provides the reader with contemporary methods and tools to solve them - Summarizes in a clear and straightforward way, the contemporary trends in the interaction between mathematics and chemical engineering vital to chemical engineers in their daily work - Includes classical analytical methods, computational methods, and methods of symbolic computation - Covers the latest cutting edge computational methods, like symbolic computational methods