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Author: Ivan Brovchenko Publisher: Elsevier ISBN: 0080558178 Category : Technology & Engineering Languages : en Pages : 317
Book Description
Water in the proximity of a surface (interfacial water) is abundant on the earth. It is involved in various physical and chemical processes and crucial for biological function. Despite numerous studies of interfacial water, systematic analysis of its properties is missing in scientific literature. This book is a first comprehensive review of experimental and simulation studies of water in various confining environments, such as hydrophilic and hydrophobic surfaces, surfaces of biomolecules, porous media, etc. Systematic analysis of interfacial and confined water is based on the firm physical ground, which accounts for variety of the thermodynamic states of water near the surface, surface phase transitions, surface critical behaviour, effect of confinement on the bulk and surface phase transitions of water, clustering and formation of a spanning hydrogen-bonded water network via percolation transition. This allows distinguishing between universal features, common for all fluids, and some specific water properties, related to intermolecular hydrogen bonds. Special attention is paid to the properties of hydration water, which covers biomolecules and enables their biological activity. This book provides readers with basic information on interfacial and confined water, which will be useful for scientists and engineers working in the fields of bioscienses, nanociences and nanotechnologies. Comprehensive review and analysis of interfacial and confined water Updates and informs practitioners and students on all the latest developments in the field Written by leading scholars and industry experts
Author: Ivan Brovchenko Publisher: Elsevier ISBN: 0080558178 Category : Technology & Engineering Languages : en Pages : 317
Book Description
Water in the proximity of a surface (interfacial water) is abundant on the earth. It is involved in various physical and chemical processes and crucial for biological function. Despite numerous studies of interfacial water, systematic analysis of its properties is missing in scientific literature. This book is a first comprehensive review of experimental and simulation studies of water in various confining environments, such as hydrophilic and hydrophobic surfaces, surfaces of biomolecules, porous media, etc. Systematic analysis of interfacial and confined water is based on the firm physical ground, which accounts for variety of the thermodynamic states of water near the surface, surface phase transitions, surface critical behaviour, effect of confinement on the bulk and surface phase transitions of water, clustering and formation of a spanning hydrogen-bonded water network via percolation transition. This allows distinguishing between universal features, common for all fluids, and some specific water properties, related to intermolecular hydrogen bonds. Special attention is paid to the properties of hydration water, which covers biomolecules and enables their biological activity. This book provides readers with basic information on interfacial and confined water, which will be useful for scientists and engineers working in the fields of bioscienses, nanociences and nanotechnologies. Comprehensive review and analysis of interfacial and confined water Updates and informs practitioners and students on all the latest developments in the field Written by leading scholars and industry experts
Author: Adrian Perez Defante Publisher: ISBN: Category : Adhesion Languages : en Pages : 115
Book Description
The role of water is often overlooked in interfacial phenomena, but its presence influences many interfacial processes relevant to a number of scientific disciplines. Direct force measurements have offered the most insight into underwater surface related phenomena such as adhesion, wetting, and friction, and have provided molecular descriptions to the physical interactions taking place at the contact interface. Although the insight from these experiments maybe true, there lacks direct molecular confirmation of the assertions interpreted from these force measurements. To address this, we have studied the impact of water on adhesion, friction, and wetting by using a suite of complementary surface sensitive techniques. By using non-linear sum frequency generation spectroscopy, we are able to probe surfaces at a molecular level and connect these chemical details to better understand interfacial phenomena. This thesis focuses on three studies to better understand the role of water in interfacial phenomena. For the first study, we focused on the contact of two hydrophobic surfaces in water. Here, we use surface sensitive sum frequency generation spectroscopy to directly probe the contact interface between hydrophobic poly-(dimethylsiloxane) (PDMS) and two hydrophobic surfaces (a self-assembled monolayer, OTS, and a polymer coating, PVNODC). We show that the interfacial structure for OTS and PVNODC are identical in dry contact but that they differ dramatically in wet contact. In water, the PVNODC surface partially rearranges at grain boundaries, trapping water at the contact interface leading to a 50% reduction in adhesion energy compared to OTS-PDMS contact. The Young-Dupr\'e equation, used extensively to calculate the thermodynamic work of adhesion, predicts no differences between the adhesion energy for these two hydrophobic surfaces, indicating a failure of this well-known equation when there is a heterogeneous contact.For the second study, we studied the role of water between two hydrophilic interfaces in sliding friction and adhesion. We achieve this by adsorbing cationic surfactant, cetyl trimethyl ammonium bromide (CTAB), on two hydrophobic surfaces, PDMS and a self assembled monolayer. Using surface sensitive sum frequency generation spectroscopy, we highlight a strongly coordinated ice-like water layer confined between two surfactant covered hydrophobic surfaces under hydration pressures. Such strongly coordinated water structure, that reduces the sliding friction, forms past the surfactant concentration needed for monolayer coverage. In addition, the surprising observance of a highly coordinated ice like layer of water between these two surfaces presents opportunities for developing a theoretical framework to the molecular behavior of confined water.For the third study, we investigate underwater adhesion and friction for a hydrophobic lens in contact with plasma treated surfaces of different wettability. From these measurements, we aimed to guide the interfacial design of underwater adhesives by systematically varying the surface energy of the contact interface. We show underwater adhesion and friction is the highest between a hydrophobic lens and plasma treated surface for a water contact angle of 70 degrees.
Author: Publisher: ISBN: Category : Languages : en Pages : 25
Book Description
The interfacial structure of the two-phase flows is of great importance in view of theoretical modeling and practical applications. In the present study, the focus is made on obtaining detailed local two-phase parameters in the air-water bubbly flow in a rectangular vertical duct using the double-sensor conductivity probe. The characteristic wall-peak is observed in the profiles of the interracial area concentration and the void fraction. The development of the interfacial area concentration along the axial direction of the flow is studied in view of the interfacial area transport and bubble interactions. The experimental data is compared with the drift flux model with C0 = 1.35.
Author: Nikola Kallay Publisher: CRC Press ISBN: 1482289792 Category : Science Languages : en Pages : 760
Book Description
An examination of the theoretical foundations of the kinetics and thermodynamics of solid-liquid interfaces, as well as state-of-the-art industrial applications, this book presents information on surface and colloidal chemical processes and evaluates vital analytical tools such as atomic force microscopy, surface force apparatus measurements, and p
Author: Yuehao Luo Publisher: World Scientific ISBN: 9814704504 Category : Technology & Engineering Languages : en Pages : 599
Book Description
Through millions of years' natural selection, sharkskin has developed into a kind of drag-reducing surface. This book shows how to investigate, model, fabricate and apply sharkskin's unique surface properties, creating a flexible platform for surface and materials engineers and scientists to readily adopt or adapt for their own bio-inspired materials.Rather than inundate the reader with too many examples of materials inspired by nature, sharkskin has been chosen as the center-piece to illustrate accurate 3D digital modeling of surfaces, complete numerical simulation of micro flow field, different fabrication methods, and application to natural gas pipelining. This is a must-read for any researcher or engineer involved in bio-inspired surfaces and materials studies.
Author: VICTORIA GARCIA SAKAI Publisher: Springer Science & Business Media ISBN: 1461407265 Category : Technology & Engineering Languages : en Pages : 455
Book Description
Dynamics of Soft Matter: Neutron Applications provides an overview of neutron scattering techniques that measure temporal and spatial correlations simultaneously, at the microscopic and/or mesoscopic scale. These techniques offer answers to new questions arising at the interface of physics, chemistry, and biology. Knowledge of the dynamics at these levels is crucial to understanding the soft matter field, which includes colloids, polymers, membranes, biological macromolecules, foams, emulsions towards biological & biomimetic systems, and phenomena involving wetting, friction, adhesion, or microfluidics. Emphasizing the complementarities of scattering techniques with other spectroscopic ones, this volume also highlights the potential gain in combining techniques such as rheology, NMR, light scattering, dielectric spectroscopy, as well as synchrotron radiation experiments. Key areas covered include polymer science, biological materials, complex fluids and surface science.
Book Description
This thesis presents a highly innovative study of the ultrafast structural and vibrational dynamics of hydrated phospholipids, the basic constituents of cell membranes. As a novel approach to the water-phospholipid interface, the author studies phosphate vibrations using the most advanced methods of nonlinear vibrational spectroscopy, including femtosecond two-dimensional infrared spectroscopy. He shows for the first time that the structure of interfacial water undergoes very limited fluctuations on a 300 fs time scale and that the lifetimes of hydrogen bonds with the phospholipid are typically longer than 10 ps. Such properties originate from the steric hindrance of water fluctuations at the interface and the orienting action of strong electric fields from the phospholipid head group dipoles. In an extensive series of additional experiments, the vibrational lifetimes of the different vibrations and the processes of energy dissipation are elucidated in detail.
Author: Ivan Brovchenko
Author: Ivan Brovchenko
Author: 
Author: Adrian Perez Defante
Author: 
Author: Biman Bagchi
Author: Nikola Kallay
Author: Yuehao Luo
Author: VICTORIA GARCIA SAKAI
Author: René Costard
Author: