Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel PDF full book. Access full book title Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel by Bruce L. Yoder. Download full books in PDF and EPUB format.
Author: Bruce L. Yoder Publisher: Springer Science & Business Media ISBN: 3642276784 Category : Science Languages : en Pages : 185
Book Description
Bruce Yoder’s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas.
Author: Bruce L. Yoder Publisher: Springer Science & Business Media ISBN: 3642276784 Category : Science Languages : en Pages : 185
Book Description
Bruce Yoder’s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas.
Author: Oleg V. Krylov Publisher: CRC Press ISBN: 1351083473 Category : Science Languages : en Pages : 312
Book Description
Nonequilibrium Processes in Catalysis presents modern ideas and experimental data (e.g., molecular beams, laser technique) on adsorption and catalysis, the mechanism of energy exchange in the processes of particles interaction with a surface, and the lifetimes of excited particles on a surface. Previously unpublished theoretical information regarding the principle of chemoenergetical stimulation accounting for the acceleration of one reaction at the expense of reactant excitation in another is provided, and new ideas about nonequilibrium surface diffusion are explored. Examples of the formation of nonequilibrium dissipative structures in catalysis are presented, including auto-oscillations, auto-waves, multiplicity of kinetic regimes, nonequilibrium phase transition, and decelerated electron exchange between solid and adsorbed species. The book also describes new experimental methods for studying nonequilibrium and quick processes in catalysis. Nonequilibrium Processes in Catalysis will benefit physicists involved with surface science, chemists involved with adsorption and catalysis, engineers, vacuum scientists, physical chemists, materials chemists, students, and others interested in these processes.
Author: K. P. Lawley Publisher: John Wiley & Sons ISBN: 0470141867 Category : Science Languages : en Pages : 398
Book Description
This text is the first of a two-volume work on molecule surface interactions addressing topics in chemical physics, surface science, physical chemistry, materials science, and electronics and semiconductor manufacture. As with the other titles in the Advances in Chemical Physics series, the chapters are written by an international group of contributors and cover a wide range of important issues in the field.
Author: K.G. Standing Publisher: Springer Science & Business Media ISBN: 1468479261 Category : Science Languages : en Pages : 319
Book Description
A NATO Advanced Research Workshop on Methods and Mechanisms for Producing Ions from Large Molecules was held at Minaki Lodge, Minaki, Ontario, Canada, from 24 to 28 June 1990. The workshop was hosted by the time-of-flight group of the Department of Physics at the University of Manitoba, and was attended by 64 invited participants from around the world. Twenty-nine invited talks were given and 19 papers were presented as posters. Of the 48 contributions, 38 are included in these proceedings. The conference was organized to study the rapidly changing field of mass spectrometry of biomolecules. Particle-induced desorption (especially with MeV particles) has been the most effective method of producing molecular ions from biomolecules. An important part of the workshop was devoted to recent developments in this field, particularly to progress in understanding the fundamentals of the desorption process. In this respect, the meeting was similar to previous conferences in Marburg, FRG (1978); Paris, F (1980); Uppsala, S (1981); College Station, USA (1983,1984); Wangerooge, FRG (1986); Orsay, F (1988); Spiekeroog, FRG (1989); and to the IFOS series of meetings at Munster, FRG (1981,1983,1985,1987) and L6vAnger, S (1989). As in the most recent of these meetings, there was some emphasis on new developments, particularly cluster bombardment. A departure from the concentration on particle bombardment processes at this conference was inspired by the dramatic results obtained with two new methods for producing molecular ions from large molecules: matrix-assisted laser desorption and electrospray.
Author: Zinetula Insepov Publisher: CRC Press ISBN: 143987543X Category : Science Languages : en Pages : 266
Book Description
Cluster Ion-Solid Interactions: Theory, Simulation, and Experiment provides an overview of various concepts in cluster physics and related topics in physics, including the fundamentals and tools underlying novel cluster ion beam technology. The material is based on the author's highly regarded courses at Kyoto University, Purdue University, the Mos
Author: Daniel J. Ehrlich Publisher: Elsevier ISBN: 0080918026 Category : Technology & Engineering Languages : en Pages : 602
Book Description
This book reviews the solid core of fundamental scientific knowledge on laser-stimulated surface chemistry that has accumulated over the past few years. It provides a useful overview for the student and interested non-expert as well as essential reference data (photodissociation cross sections, thermochemical constants, etc.) for the active researcher.
Author: F.J. Currell Publisher: Springer Science & Business Media ISBN: 9401705445 Category : Science Languages : en Pages : 422
Book Description
Highly charged ions are the most chemically reactive species known to mankind. This reactivity is due to the extremely large potential energy they posses. This textbook deals with the wide range of interactions which occur when such ions interact with other forms of matter, especially solid surfaces and gasses. Particular emphasis is placed on situations where the kinetic energy associated with the interactions is small so that the effects of the high potential energy are most apparent. Experimental and theoretical techniques of investigation are covered in addition to the findings they produce. The treatment aims to be instructive to the beginner while leading on to a level where the newest findings are reviewed. As such the text is suitable for final year undergraduates, postgraduates or experienced researchers.
Author: Bruce L. Yoder
Author: Bruce L. Yoder
Author: Oleg V. Krylov
Author: K. P. Lawley
Author: 
Author: 
Author: K.G. Standing
Author: Zinetula Insepov
Author: Daniel J. Ehrlich
Author: 
Author: F.J. Currell