Inclusion Chemistry with Zeolites: Nanoscale Materials by Design PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Inclusion Chemistry with Zeolites: Nanoscale Materials by Design PDF full book. Access full book title Inclusion Chemistry with Zeolites: Nanoscale Materials by Design by N. Herron. Download full books in PDF and EPUB format.
Author: N. Herron Publisher: Springer Science & Business Media ISBN: 9401101191 Category : Science Languages : en Pages : 353
Book Description
Zeolites, with their crystalline microporous structures, are cordial hosts to a wide variety of guests. However, it was the abrupt and unexpected departure of one of these guests (water) from a host (stilbite) on heating which led Cronstedt, in 1756, to coin the term "zeolite" (from the Greek meaning "boiling stone") to describe this material. Since that time, approximately 40 different naturally-occurring zeolites have been discovered on earth. Recent studies of meteorite compositions have shown that these guest-host materials (e. g. , sodalite) occur in other parts of the universe as well. However, it wasn't until the twentieth century that synthetic routes to zeolites and other non-aluminosilicate molecular sieves were discovered. In addition, with the development of X-ray diffraction and the various spectroscopies, better understanding of the nature of the cavities, cages, and channels of these materials has led to the industrial exploitation of their guest-host properties. The world of zeolites has now expanded into a greater than 2 billion pound per year business, with major applications in detergent formulations, catalysis, and as adsorbents and desiccants. Their economic impact is difficult to determine; however, the improvement in gasoline yields alone (from catalytic cracking) must account for hundreds ofbillions ofdollars in increased GDP. In this volume, we have brought together a sampling of recent developments in various areas of guest-host or inclusion chemistry in zeolites.
Author: N. Herron Publisher: Springer Science & Business Media ISBN: 9401101191 Category : Science Languages : en Pages : 353
Book Description
Zeolites, with their crystalline microporous structures, are cordial hosts to a wide variety of guests. However, it was the abrupt and unexpected departure of one of these guests (water) from a host (stilbite) on heating which led Cronstedt, in 1756, to coin the term "zeolite" (from the Greek meaning "boiling stone") to describe this material. Since that time, approximately 40 different naturally-occurring zeolites have been discovered on earth. Recent studies of meteorite compositions have shown that these guest-host materials (e. g. , sodalite) occur in other parts of the universe as well. However, it wasn't until the twentieth century that synthetic routes to zeolites and other non-aluminosilicate molecular sieves were discovered. In addition, with the development of X-ray diffraction and the various spectroscopies, better understanding of the nature of the cavities, cages, and channels of these materials has led to the industrial exploitation of their guest-host properties. The world of zeolites has now expanded into a greater than 2 billion pound per year business, with major applications in detergent formulations, catalysis, and as adsorbents and desiccants. Their economic impact is difficult to determine; however, the improvement in gasoline yields alone (from catalytic cracking) must account for hundreds ofbillions ofdollars in increased GDP. In this volume, we have brought together a sampling of recent developments in various areas of guest-host or inclusion chemistry in zeolites.
Author: Kenneth D. Karlin Publisher: John Wiley & Sons ISBN: 0470167068 Category : Science Languages : en Pages : 616
Book Description
Straight from the frontier of scientific investigation . . . Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." —Journal of the American Chemical Society "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." —Chemistry in Britain CONTENTS OF VOLUME 48: Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials (David B. Mitzi, IBM T. J. Watson Research Center, Yorktown Heights, New York). Transition Metals in Polymeric 1 - Conjugated Organic Frameworks (Richard P. Kingsborough and Timothy M. Swager, Massachusetts Institute of Technology, Cambridge, Massachusetts). The Transition Metal Coordination Chemistry of Hemilabile Ligands (Caroline S. Slone, Dana A. Weinberger, and Chad A. Mirkin, Northwestern University, Evanston, Illinois). Organometallic Fluorides of the Main Group Metals Containing the C-M-F Fragment (Balaji R. Jagirdar, Eamonn F. Murphy, and Herbert W. Roesky, Universität Göttingen, Germany). Coordination Complex Impregnated Molecular Sieves-Synthesis, Characterization, Reactivity, and Catalysis (Partha P. Paul, Southwest Research Institute, San Antonio, Texas). Advances in Metal Boryl and Metal-Mediated B-X Activation Chemistry (Milton R. Smith III, Michigan State University, East Lansing, Michigan).
Author: Hellmut G. Karge Publisher: Springer Science & Business Media ISBN: 9783540643357 Category : Science Languages : en Pages : 636
Book Description
Molecular Sieves - Science and Technology covers, in a comprehensive manner, the science and technology of zeolites and all related microporous and mesoporous materials. Authored by renowned experts, the contributions are grouped together topically in such a way that each volume of the book series deals with a specific sub-field. Volume 4 covers the characterization of molecular sieves with the help of the most important spectroscopic techniques (Characterization I), i.e. IR, Raman, NMR, EPR, UV-VIS Spectroscopy, X-ray absorption, photoelectron and Mössbauer Spectroscopy. Theory, experiment and application in selected examples are discussed.
Author: John Andraos Publisher: CRC Press ISBN: 100054236X Category : Science Languages : en Pages : 1406
Book Description
Interest in green chemistry and clean processes has grown so much in recent years that topics such as fluorous biphasic catalysis, metal organic frameworks, and process intensification, which were barely mentioned in the First Edition, have become major areas of research. In addition, government funding has ramped up the development of fuel cells and biofuels. This reflects the evolving focus from pollution remediation to pollution prevention. Copiously illustrated with more than 800 figures, the Third Edition provides an update from the frontiers of the field. It features supplementary exercises at the end of each chapter relevant to the chemical examples introduced in each chapter. Particular attention is paid to a new concluding chapter on the use of green metrics as an objective tool to demonstrate proof of synthesis plan efficiency and to identify where further improvements can be made through fully worked examples relevant to the chemical industry. NEW AND EXPANDED RESEARCH TOPICS Metal-organic frameworks Metrics Solid acids for alkylation of isobutene by butanes Carbon molecular sieves Mixed micro- and mesoporous solids Organocatalysis Process intensification and gas phase enzymatic reactions Hydrogen storage for fuel cells Reactive distillation Catalysts in action on an atomic scale UPDATED AND EXPANDED CURRENT EVENTS TOPICS Industry resistance to inherently safer chemistry Nuclear power Removal of mercury from vaccines Removal of mercury and lead from primary explosives Biofuels Uses for surplus glycerol New hard materials to reduce wear Electronic waste Smart growth The book covers traditional green chemistry topics, including catalysis, benign solvents, and alternative feedstocks. It also discusses relevant but less frequently covered topics with chapters such as "Chemistry of Long Wear" and "Population and the Environment." This coverage highlights the importance of chemistry to everyday life and demonstrates the benefits the expanded exploitation of green chemistry can have for society.
Author: L. Bonneviot Publisher: Elsevier ISBN: 008054469X Category : Technology & Engineering Languages : en Pages : 585
Book Description
Formerly, the catalytic use of zeolites was exclusive to the field of acid catalysis. Nowadays, zeolites also find applications as catalysts in a wide array of chemical reactions such as; base catalyzed reactions, Redox reactions and catalytic reactions on transition metals and their complexes in confined environments. The concepts of Brønsted or Lewis acid-base pairs are adequately illustrated in the literature and well-understood in terms of structural and electronic properties of zeolites. By contrast, properties of chemically modified silicates, aluminosilicates and aluminophosphates have not yet been fully explored. The list of oxydo-reduction reactions performed in the presence of these new materials is growing as demonstrated by the selective catalytic reduction of nitrogen oxides or the numerous oxidations employing hydrogen peroxide. Much effort is currently being made to get a better insight into the nature of the sites involved. The zeolite lattice may also be used as a host for encapsulated complexes or metallic clusters allowing the control of nuclearity of these active species and the steric constraints imposed on the reactants. Molecular sieve and shape selectivity effects have also constituted fascinating aspects of zeolite properties. Recent developments leading to increasingly large pore sizes with VPI-5, cloverite and more recently mesoporous molecular sieves have broadened the spectrum of these applications. Indeed, larger and larger reactant and product molecules can be accommodated in these lattices. These new adsorbant/adsorbate systems create additional needs for experimental data and theoretical descriptions of transport properties, in particular of mono- and multi-components diffusion coefficients in the zeolite pore lattice.All these themes, representing the forefront and current trends in zeolite research, were discussed in the submitted papers to the symposium and are widely represented in the selected papers contained in this volume. A feature common to most of these contributions is the combined use of a variety of analytical techniques. Some of these techniques are at the frontier of the latest analytical developments such as multiple scattering EXAFS and bidimensional MAS-NMR.
Author: Albert Matlack Publisher: CRC Press ISBN: 1439882118 Category : Science Languages : en Pages : 602
Book Description
The book covers traditional green chemistry topics, including catalysis, benign solvents, and alternative feedstocks. It also discusses relevant but less frequently covered topics with chapters such as Chemistry of Longer Wear and Population and the Environment. This coverage highlights the importance of chemistry to everyday life and demonstrates the benefits the expanded exploitation of green chemistry can have for society. Copiously illustrated with over 800 figures, this second edition provides an update from the frontiers of the field.
Author: Claudia Belviso Publisher: BoD – Books on Demand ISBN: 9535125761 Category : Science Languages : en Pages : 228
Book Description
This book collects recent results about research activities on zeolites, from synthesis to application. It is composed of two sections. The first is devoted to articles and brief review articles on the synthesis of zeolite from fly ash and final application of these newly formed minerals to solve environmental problems. The second part of the book provides useful information on different applications both of natural and synthetic zeolites ranging from environmental pollution to industrial and commercial applications. The performance of zeolite molecular sieves, hollow titanium zeolites and luminescent zeolites is interesting considering the new frontiers reached by the research on zeolites. This book is a useful instrument for researchers, teachers and students who are interested in investigating innovative aspects of the studies on zeolite.
Author: Jean-Marie Basset Publisher: John Wiley & Sons ISBN: 3527627103 Category : Science Languages : en Pages : 725
Book Description
Covering everything from the basics to recent applications, this monograph represents an advanced overview of the field. Edited by internationally acclaimed experts respected throughout the community, the book is clearly divided into sections on fundamental and applied surface organometallic chemistry. Backed by numerous examples from the recent literature, this is a key reference for all chemists.
Author: Scott M. Auerbach Publisher: CRC Press ISBN: 0824756126 Category : Technology & Engineering Languages : en Pages : 1526
Book Description
The Handbook of Zeolite Science and Technology offers effective analyses ofsalient cases selected expressly for their relevance to current and prospective research. Presenting the principal theoretical and experimental underpinnings of zeolites, this international effort is at once complete and forward-looking, combining fundamental concepts with the most sophisticated data for each scientific subtopic and budding technology. Supplying over 750 figures, and 350 display equations, this impressive achievement in zeolite science observes synthesis through the lens of MFI (ZSM-5 and silicalite). Chapters progress from conceptual building blocks to complex research presentations.
Author: Reinhold Haberlandt Publisher: Springer Science & Business Media ISBN: 9783540205395 Category : Technology & Engineering Languages : en Pages : 546
Book Description
The study of the interaction of molecules with surfaces and interfaces is of great importance for the understanding of adsorption and catalysis on solid surfaces, the complex properties of molecules on fluid interfaces and the relationship between structure and functionality in macromolecular biological systens. It is the aim of this volume to present and analyse in a comprehensive and accesible way the methodical achievements and the recent proress in this field. The broadness of both scope and selection of the topics should help in particular non-expert readers to become familiar with this exciting field of research.
Author: N. Herron
Author: N. Herron
Author: Kenneth D. Karlin
Author: Hellmut G. Karge
Author: John Andraos
Author: L. Bonneviot
Author: Albert Matlack
Author: Claudia Belviso
Author: Jean-Marie Basset
Author: Scott M. Auerbach
Author: Reinhold Haberlandt