Author: Forrest E. MichaelPublisher:
ISBN:
Category : Chirality
Languages : en
Pages : 666
Book Description
Chiral Mixed Phosphorus/sulfur Ligands in Late Transition Metal-catalyzed Reactions
Author: Forrest E. MichaelPublisher:
ISBN:
Category : Chirality
Languages : en
Pages : 666
Book Description
Development of Chiral Mixed Phosphorus/sulfur Ligands for Late Transition Metal-catalyzed Reactions
Author: Kevin Richard CamposPublisher:
ISBN:
Category : Ligands
Languages : en
Pages : 604
Book Description
I. Chiral Mixed Phosphorus/sulfur Ligands
Author: Jason Scot TedrowPublisher:
ISBN:
Category : Chirality
Languages : en
Pages : 776
Book Description
Chiral Sulfur Ligands
Author: Hélène PellissierPublisher: Royal Society of Chemistry
ISBN: 1847559247
Category : Science
Languages : en
Pages : 403
Book Description
The goal of this book is to show the high potential of chiral sulfur-containing ligands to promote numerous asymmetric catalytic transformations. These ligands can now be recognised as real competitors to the more usual phosphorus- or nitrogen-containing ligands.
Synthesis of Chiral Tridentate Ligands Containing Nitrogen, Phosphorus, and Sulfur Donors
Author: Anthony Robert AmaroPublisher:
ISBN:
Category :
Languages : en
Pages : 424
Book Description
Phosphorus(III)Ligands in Homogeneous Catalysis
Author: Paul C. J. KamerPublisher: John Wiley & Sons
ISBN: 1118299701
Category : Technology & Engineering
Languages : en
Pages : 673
Book Description
Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry.
The Chiral Carbon Pool and Chiral Sulfur, Nitrogen, Phosphorus, and Silicon Centers
Author: James D. MorrisonPublisher:
ISBN:
Category : Science
Languages : en
Pages : 400
Book Description
Asymmetric Synthesis, Volume 4: The Chiral Carbon Pool and Chiral Sulfur, Nitrogen, Phosphorus, and Silicon Centers describes the practical methods of obtaining chiral fragments. Divided into five chapters, this book specifically examines initial chiral transmission and extension. The opening chapter describes the so-called chiral carbon pool, the readily available chiral carbon fragments used as building blocks in synthesis. This chapter also provides a list of 375 chiral building blocks, along with their commercial sources, approximate prices, and methods of synthesis. Schemes involving almo ...
Construction of Phosphorus and Sulfur Stereogenic Centers by Chiral Cyclopentadienyl Rhodium(III) Catalysis
Author: Yang SunPublisher:
ISBN:
Category :
Languages : en
Pages : 555
Book Description
Mots-clés de l'auteur: asymmetric synthesis ; C-H activation ; P- and S-chirality ; chiral cyclopentadienyl ligands ; rhodium.
Fundamentals of Asymmetric Catalysis
Author: Patrick J. WalshPublisher: University Science Books
ISBN: 9781891389542
Category : Science
Languages : en
Pages : 692
Book Description
This work describes the essential aspects of enantioselective catalysis, with chapters organised by concept rather than by reaction type. Each concept is supported by examples to give the reader broad exposure to a wide range of catalysts, reactions and reaction mechanisms.
Phosphorus Ligands in Asymmetric Catalysis
Author: Armin BörnerPublisher:
ISBN:
Category : Asymmetric synthesis
Languages : en
Pages : 512
Book Description