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Author: Michael Smialowski Publisher: Elsevier ISBN: 1483213714 Category : Science Languages : en Pages : 469
Book Description
Hydrogen in Steel: Effect of Hydrogen on Iron and Steel During Production, Fabrication, and Use focuses on the effect of hydrogen on iron and steel during production, fabrication, and use. Topics covered range from the solubility of hydrogen in iron and ferrous alloys to the diffusion and permeation of hydrogen through iron and steel. Electrochemical problems related to the ability of iron to absorb hydrogen from aqueous solutions are also considered. Comprised of 19 chapters, this book begins with a detailed treatment of the nature and properties of metal-hydrogen systems, paying particular attention to the behavior of hydrogen in the bulk of the metal phase and the mechanism of reactions between metals and hydrogen or hydrogen-producing compounds. The reader is then introduced to the solubility of hydrogen in iron and ferrous alloys as well as the nature of the final product of the hydrogen-iron interaction. Subsequent chapters deal with dimensional changes and stresses produced in steel by cathodically evolved hydrogen; the effects of hydrogen on the physical, mechanical, and chemical properties of iron and steel; influence of welding on hydrogen; and sulfide corrosion cracking of steel. The effects of pickling on steel are also examined, along with the blistering and embrittlement caused by hydrogen on the base metal during electroplating. This book will be of value to students and practitioners in the field of physical chemistry.
Author: Michael Smialowski Publisher: Elsevier ISBN: 1483213714 Category : Science Languages : en Pages : 469
Book Description
Hydrogen in Steel: Effect of Hydrogen on Iron and Steel During Production, Fabrication, and Use focuses on the effect of hydrogen on iron and steel during production, fabrication, and use. Topics covered range from the solubility of hydrogen in iron and ferrous alloys to the diffusion and permeation of hydrogen through iron and steel. Electrochemical problems related to the ability of iron to absorb hydrogen from aqueous solutions are also considered. Comprised of 19 chapters, this book begins with a detailed treatment of the nature and properties of metal-hydrogen systems, paying particular attention to the behavior of hydrogen in the bulk of the metal phase and the mechanism of reactions between metals and hydrogen or hydrogen-producing compounds. The reader is then introduced to the solubility of hydrogen in iron and ferrous alloys as well as the nature of the final product of the hydrogen-iron interaction. Subsequent chapters deal with dimensional changes and stresses produced in steel by cathodically evolved hydrogen; the effects of hydrogen on the physical, mechanical, and chemical properties of iron and steel; influence of welding on hydrogen; and sulfide corrosion cracking of steel. The effects of pickling on steel are also examined, along with the blistering and embrittlement caused by hydrogen on the base metal during electroplating. This book will be of value to students and practitioners in the field of physical chemistry.
Author: D. J. Fisher Publisher: ISBN: Category : Science Languages : en Pages : 340
Book Description
The present work draws upon Diffusion and Defect Forum's 30-year project of summarizing recent progress in the fields of diffusion and defect research, by collating the relevant data which have been published during that time. The large number of studies of iron alloys reflects the great commercial importance of hydrogen embrittlement; an annoying phenomenon which has long plagued steel fabricators.
Author: Ellis E. Fletcher Publisher: ISBN: Category : Steel Languages : en Pages : 82
Book Description
This report deals with the deleterious effects of hydrogen gas on steel at elevated temperatures and/or pressures. Hydrogen attack on steels is manifest as decarburization, intergranular fissuring, or blistering. These conditions result in lowered tensile strength, ductility, and impact strength. The reaction of hydrogen with iron carbide to form methane is probably the most important chemical reaction involved in the attack on steel by hydrogen. Attack of steel at elevated temperatures and pressures is limited or prevented by the following measures: (1) use of steel alloyed with strong carbide-forming elements, (2) use of liners of resistant alloy steels, and (3) substitution of resistant nonferrous alloys.
Author: A. R. Elsea Publisher: ISBN: Category : Steel Languages : en Pages : 42
Book Description
This memorandum introduces the problem of delayed, brittle failures associated with hydrogen in steel, particularly high-strength steel. It is intended to help the steel user determine if he has such a problem. The effects of hydrogen on the mechanical properties of steel are dealt with, and the behavior of material susceptible to delayed, brittle failure is described. Also, the effects of such factors as strength level, magnitude of applied stress, hydrogen content, steel composition, test temperature, and strain rate on hydrogen embrittlement and the susceptibility to hydrogen-induced, delayed, brittle failure are discussed. Possible sources of hydrogen in steel and the types of tests useful in determining the susceptibility to delayed failure are outlined. (Author).
Author: Ellis E. Fletcher Publisher: ISBN: Category : Steel Languages : en Pages : 96
Book Description
This report discusses the ways in which H2 enters steels, how it moves through steel, and methods whereby it may be removed from steel. The solubility of H2 is important in understanding other aspects of the behavior of H2 in steel and such aspects of solubility as preferred lattice sites, lattice expansion, measurements of solubility, and estimates of equilibrium H2 pressure in steel are discussed. The permeation of H2 through steel consisting of interactions at both the entry and exit surfaces of the metal as well as diffusion through the bulk metal is discussed. The various possibilities of H2 entry by corrosion processes, electrochemical processes, and other means are considered as well as factors which influence the rate of H2 removal from iron and steel. (Author).
Author: Michihiko Nagumo Publisher: Springer Nature ISBN: 9819909929 Category : Technology & Engineering Languages : en Pages : 316
Book Description
This book is the second edition of the one originally published in 2016, as the first comprehensive treatment on the fundamentals of hydrogen embrittlement of metallic materials, mainly steel. The book provides students and researchers engaging in hydrogen problems with a unified view of the subject. Establishing reliable principles for materials design against hydrogen embrittlement and assessing their performance are recent urgent industrial needs in developing high-strength steel for hydrogen energy equipment and weight-reducing vehicles. The interdisciplinary nature of the subject, covering metal physics, materials science, and mechanics of fracture, has disturbed a profound understanding of the problem. In this book, previous studies are critically reviewed, and supplemental descriptions of fundamental ideas are presented when necessary. Emphasis is placed on experimental facts, with particular attention to their implication rather than phenomenological appearance. The adopted experimental conditions are also noted since the operating mechanism of hydrogen might differ by material and environment. For theories, employed assumptions and premises are noted to examine their versatility. Progress in the past decade in experimental and theoretical tools is remarkable and has nearly unveiled characteristic features of hydrogen embrittlement. Proposed models have almost covered feasible aspects of the function of hydrogen. This second edition has enriched the contents with recent crucial findings. Chapters on the manifestation of embrittlement in the deterioration of mechanical properties and microscopic features are reorganized, and the description is revised for the convenience of readers’ systematic understanding. A new chapter is created for delayed fracture in atmospheric environments as a conclusive subject of critical ideas presented in this book.
Author: Mehmet Sankir Publisher: John Wiley & Sons ISBN: 1119283655 Category : Science Languages : en Pages : 653
Book Description
Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.