Gas-Phase Combustion Chemistry PDF Download

Author: W.C., Jr. Gardiner
Publisher: Springer
ISBN: 9781461270881
Category : Science
Languages : en
Pages : 0

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Book Description
Superseding Gardiner's "Combustion Chemistry", this is an updated, comprehensive coverage of those aspects of combustion chemistry relevant to gas-phase combustion of hydrocarbons. The book includes an extended discussion of air pollutant chemistry and aspects of combustion, and reviews elementary reactions of nitrogen, sulfur and chlorine compounds that are relevant to combustion. Methods of combustion modeling and rate coefficient estimation are presented, as well as access to databases for combustion thermochemistry and modeling.

Author: W.C., Jr. Gardiner
Publisher: Springer Science & Business Media
ISBN: 146121310X
Category : Science
Languages : en
Pages : 553

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Book Description
Superseding Gardiner's "Combustion Chemistry", this is an updated, comprehensive coverage of those aspects of combustion chemistry relevant to gas-phase combustion of hydrocarbons. The book includes an extended discussion of air pollutant chemistry and aspects of combustion, and reviews elementary reactions of nitrogen, sulfur and chlorine compounds that are relevant to combustion. Methods of combustion modeling and rate coefficient estimation are presented, as well as access to databases for combustion thermochemistry and modeling.

Author:
Publisher: Elsevier
ISBN: 0128195797
Category : Technology & Engineering
Languages : en
Pages : 1034

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Book Description
Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications.

Author: Michael A. Liberman
Publisher: Springer Science & Business Media
ISBN: 3540787593
Category : Science
Languages : en
Pages : 368

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Book Description
Most of the material covered in this book deals with the fundamentals of chemistry and physics of key processes and fundamental mechanisms for various combustion and combustion related phenomena in gaseous combustible mixture. It provides the reader with basic knowledge of burning processes and mechanisms of reaction wave propagation. The combustion of a gas mixture (flame, explosion, detonation) is necessarily accompanied by motion of the gas. The process of combustion is therefore not only a chemical phenomenon but also one of gas dynamics. The material selection focuses on the gas phase and with premixed gas combustion. Premixed gas combustion is of practical importance in engines, modern gas turbine and explosions, where the fuel and air are essentially premixed, and combustion occurs by the propagation of a front separating unburned mixture from fully burned mixture. Since premixed combustion is the most fundamental and potential for practical applications, the emphasis in the present work is be placed on regimes of premixed combustion. This text is intended for graduate students of different specialties, including physics, chemistry, mechanical engineering, computer science, mathematics and astrophysics.

Author: V.N. Kondratiev
Publisher: Springer Science & Business Media
ISBN: 3642676081
Category : Science
Languages : en
Pages : 254

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Book Description
The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.

Author: Irvin Glassman
Publisher: Academic Press
ISBN: 0124115551
Category : Technology & Engineering
Languages : en
Pages : 775

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Book Description
Throughout its previous four editions, Combustion has made a very complex subject both enjoyable and understandable to its student readers and a pleasure for instructors to teach. With its clearly articulated physical and chemical processes of flame combustion and smooth, logical transitions to engineering applications, this new edition continues that tradition. Greatly expanded end-of-chapter problem sets and new areas of combustion engineering applications make it even easier for students to grasp the significance of combustion to a wide range of engineering practice, from transportation to energy generation to environmental impacts. Combustion engineering is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications—including power generation in internal combustion automobile engines and gas turbine engines. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions, make this a crucial area of engineering. - New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion—all interrelated and discussed by considering scaling issues (e.g., length and time scales) - New information on sensitivity analysis of reaction mechanisms and generation and application of reduced mechanisms - Expanded coverage of turbulent reactive flows to better illustrate real-world applications - Important new sections on stabilization of diffusion flames—for the first time, the concept of triple flames will be introduced and discussed in the context of diffusion flame stabilization

Author: W. C. Jr. Gardiner
Publisher: Springer Science & Business Media
ISBN: 1468401866
Category : Science
Languages : en
Pages : 515

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Book Description
Detailed study of the rates and mechanisms of combustion reactions has not been in the mainstream of combustion research until the recent recognition that further progress in optimizing burner performance and reducing pollutant emission can only be done with fundamental understanding of combustion chemistry. This has become apparent at a time when our understanding of the chemistry, at least of small-molecule combustion, and our ability to model combustion processes on large computers have developed to the point that real confidence can be placed in the results. This book is an introduction for outsiders or beginners as well as a reference work for people already active in the field. Because the spectrum of combustion scientists ranges from chemists with little computing experience to engineers who have had only one college chemistry course, everything needed to bring all kinds of beginners up to the level of current practice in detailed combustion modeling is included. It was a temptation to include critical discussions of modeling results and computer programs that would enable outsiders to start quickly into problem solving. We elected not to do either, because we feel that the former are better put into the primary research literature and that people who are going to do combustion modeling should either write their own programs or collaborate with experts. The only exception to this is in the thermochemical area, where programs have been included to do routine fitting operations. For reference purposes there are tables of thermochemical, transport-property, and rate coefficient data.

Author: Faure Lique
Publisher:
ISBN: 9780750314268
Category : Science
Languages : en
Pages : 400

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Book Description
Astrochemistry, the study of chemistry in space, is a rapidly growing field in astrophysics. Molecules are found everywhere; from our solar system to high-redshift galaxies. Gas-Phase Chemistry in Space: From elementary particles to complex organic molecules addresses the physics and chemistry of astrophysical molecules with a focus on gas-phase processes. Edited by François Lique and Alexandre Faure, alongside a collection of experts in the field, this book introduces essential concepts that govern the formation, excitation and destruction of molecules at postgraduate and research levels. A broad range of topics are covered, including early universe chemistry and stellar nucleosynthesis, and the study of bimolecular reaction kinetics. Detailed descriptions of the gas-phase process are provided and recent examples of the interplay between observational and laboratory astrophysics are examined. Coinciding with the timely arrival of powerful new telescopes, this work examines numerous advances in astrochemistry and paves the way for these advances to be implemented in the future. More than 100 figures are used, alongside examples, providing both theoretical and experimental perspectives. Book jacket.

Author: A. Fontijn
Publisher: Elsevier
ISBN: 1483291219
Category : Science
Languages : en
Pages : 711

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Book Description
The book brings together, for the first time, all aspects of reactions of metallic species in the gas phase and gives an up-to-date overview of the field. Reactions covered include those of atomic, other free radical and transient neutral species, as well as ions. Experimental and theoretical work is reviewed and the efforts to establish a closer link between these approaches are discussed. The field is mainly approached from a fundamental point-of-view, but the applied problems which have helped stimulate the interest are pointed out and form the major subject of the final chapters. These emphasize the competition between purely gas-phase and gas-surface reactions.

Author: Francis Westley
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 148

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Book Description
Work supported by the Office of Standard Reference Data, National Bureau of Standards, Naval Sea Systems Command, Department of the Navy, and Division of Conservation, Research and Technology, Energy Research and Development Administration.