Flaw Detection in the Coating Process of Lithium-ion Battery Electrodes with Acoustic Guided Waves PDF Download

Author: Alexander Gitis
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Author: Schmitt, Marcel
Publisher: KIT Scientific Publishing
ISBN: 3731504774
Category : Chemical engineering
Languages : en
Pages : 202

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The Li-ion battery technology could help to accelerate the transition towards renewable energy sources. In the manufacturing chain, the electrode processing by slot die coating is one of the most crucial steps. Increased line speeds and reduced scrap rates could help decrease these costs. The scope of this work is therefore the scientific elaboration of the process limits of single and subdivided, simultaneous coated multilayer films, a minimizing of edge effects and intermittent coatings.

Author: Marcel Schmitt
Publisher:
ISBN: 9781013283482
Category : Technology & Engineering
Languages : en
Pages : 198

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The Li-ion battery technology could help to accelerate the transition towards renewable energy sources. In the manufacturing chain, the electrode processing by slot die coating is one of the most crucial steps. Increased line speeds and reduced scrap rates could help decrease these costs. The scope of this work is therefore the scientific elaboration of the process limits of single and subdivided, simultaneous coated multilayer films, a minimizing of edge effects and intermittent coatings. This work was published by Saint Philip Street Press pursuant to a Creative Commons license permitting commercial use. All rights not granted by the work's license are retained by the author or authors.

Author: Long, Julian
Publisher: Universitätsverlag der TU Berlin
ISBN: 3798332789
Category : Technology & Engineering
Languages : en
Pages : 260

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Lithium plating is not only the most severe ageing mechanism in lithium-ion batteries (LIBs) but also becoming more and more important due the increasing presence of electric vehicles (EVs). In EVs the extreme conditions causing lithium plating, like very high charging currents and low environment temperatures, are much more prevalent than in consumer electronics. Due to the high number of factors that influence the plating process, ranging from the cell geometry to the chemical composition of the electrolyte, a deeper understanding of the plating process is still lacking. Without this knowledge it is hard to design cells in a plating resistant way, or to operate cells under the ideal conditions to minimize plating. This thesis aims at showing different methods to investigate the plating process on three different levels. The first method is on the cell level, investigating the behaviour of the whole cell during plating. It contains the analysis of the voltage and current profiles that show an atypical behaviour during plating. The focus of the analysis is on the current profile of the constant voltage (CV) phase during charging under low temperature conditions leading to plating. This current profile can be fitted with the Johnson-Mehl-Avrami-Kolmogorov (JMAK) function that describes the electrochemical deposition process of a metallic species on a surface. The resulting fitting parameters can be utilized to characterize the plating behaviour of the cell as well as better estimate the amount of plated lithium than commonly used methods. It can also potentially predict the future safety risk due to dendrite formation. In the second part the chemical composition of the surface electrolyte interface (SEI) is investigated using X-ray photoelectron spectroscopy (XPS). The composition as well as the mechanical properties of the SEI are strongly influencing the plating process and preliminary work has shown that plating is also changing the morphology of the SEI and increasing its thickness drastically. Cells under different conditions (plated, charged and discharged) as well as cells of different manufacturers have been probed using XPS. During the measurements an unwanted side effect of the experimental setup was discovered that lead to a migration of lithium to the surface of the sample and was distorting the measurement results. Regardless of the effect, it was possible to see that the SEI can have a very different composition in cells of different manufacturers and that plating not only changes the morphology but also the composition of the SEI. The unwanted side effect could furthermore be utilized to identify samples that were plated recently and could be used in further more controlled experiments to localize lithium depositions on plated samples. In the last part the particle structure of the anode surface of cells of different manufacturers was investigated using a watershed particle detection algorithm on laser scanning microscopy (LSM) images of the anode surfaces. The distributions of the particle sizes have then been compared to the capacity loss in plated cells. It was shown that the capacity loss correlates with parameters extracted from the particle size distributions. It is however necessary to create more data to verify this correlation. In summary this thesis utilized new methods to detect or characterize plating on different levels of magnification, from the cell level to the chemical composition. New approaches were found to predict a cells future plating behaviour, spatially localize plated areas on the anode and design cells in a plating resistant way. Lithium Plating ist nicht nur der Alterungsmechanismus in Lithium-Ionen-Batterien mit dem größten Kapazitätsverlust, sondern wird auch im Zuge der voranschreitenden Elektrifizierung des Personenverkehrs immer wichtiger. In Elektrofahrzeugen finden sich die extremen Zustände, wie niedrige Ladetemperaturen und hohe Ladestrome, unter denen Plating auftritt, deutlich häufiger als in Unterhaltungstechnik. Durch die Vielzahl von Parametern, von der Zellgeometrie bis hin zur Elektrolyzusammensetzung, die Plating beeinflussen, fehlt immer noch ein tieferes Verständnis des Plating-Prozesses. Ohne dieses Wissen ist es schwer, Zellen zu designen, die resistent gegen Plating sind oder Zellen unter optimalen Bedingungen zu betreiben um Plating zu minimieren. Das Ziel dieser Arbeit ist es, verschiedene Methoden aufzuzeigen, die die Untersuchung von Plating auf drei verschiedenen Ebenen ermöglichen. Die erste Methode untersucht das Gesamtverhalten der Zelle auf Zellebene. Hierbei wird das atypische Verhalten der Strom- und Spannunsprofile wahrend des Plating-Vorgangs analysiert. Der Fokus liegt dabei auf der Untersuchung der Konstantstrom-Phase bei niedrigen Temperaturen während der Ladung. Das Stromprofil dieser Phase kann mit der JMAK-Funktion gefittet werden, welche die elektrochemische Abscheidung eines Metalls auf einer Oberfläche beschreibt. Die resultierenden Fitting-Parameter können genutzt werden, um das Plating-Verhalten vorherzusagen und sind gleichzeitig eine bessere Abschätzung fur die Menge an geplatetem Lithium im Vergleich zu gängigen Methoden. Die Ergebnisse konnten außerdem helfen das Sicherheitsrisiko der Zelle bei Dendritenbildung vorherzusagen. Im zweiten Teil wird die chemische Zusammensetzung der SEI mittels XPS untersucht. Die Zusammensetzung, wie auch die mechanischen Eigenschaften der SEI, beeinflussen den Plating-Prozess stark und es wurde in vorhergehenden Arbeiten gezeigt, dass Plating auch die Morphologie und Dicke der SEI drastisch verändern kann. Zellen in verschiedenen Zuständen (geplatet, geladen, entladen), sowie Zellen verschiedener Hersteller wurden mit XPS untersucht. Während der Messungen wurde ein ungewollter Nebeneffekt des Messaufbaus entdeckt, der zu einer Migration von Lithium an die Oberflache der Proben geführt und die Messergebnisse verfälscht hat. Unabhängig von diesem Effekt war es dennoch möglich, zu zeigen, dass die SEI in Zellen verschiedener Hersteller stark unterschiedliche Zusammensetzungen haben kann und dass Plating nicht nur die Morphologie der SEI beeinflusst, sondern auch die chemische Zusammensetzung. Weiterhin konnte der ungewollte Nebeneffekt verwendet werden, um Proben zu identifizieren, die vor kurzem geplatet wurden und konnte in zukünftigen Arbeiten verwendet werden, um lokalisiert Lithium-Ablagerungen auf geplateten Proben zu identifizieren. Im letzten Teil wurde die Partikelstruktur der Anoden von Zellen verschiedener Zellhersteller mit Hilfe einer watershed-Partikeldetektion an LSM-Bildern untersucht. Die Verteilung der Partikelgrößen wurde mit dem Kapazitätsverlust gleicher Zelle durch Plating verglichen. Es wurde gezeigt, dass der Kapazitätsverlust mit Parametern, die aus den Partikelverteilungen extrahiert wurden, korreliert. Ein größerer Datensatz ist jedoch notwendig, um diese Ergebnisse zu validieren. Zusammenfassend hat diese Arbeit verschiedene neue Methoden aufgezeigt, um Plating auf verschiedenen Vergrößerungsebenen zu detektieren und zu charakterisieren. Neue Ansätze wurden gefunden, um das Platingverhalten von Zellen vorherzusagen, lokalisiertes Lithium auf der Oberfläche zu detektieren und Zellen platingresistenter designen zu können.

Author: J. David N. Cheeke
Publisher: CRC Press
ISBN: 1351833197
Category : Science
Languages : en
Pages : 507

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Written at an intermediate level in a way that is easy to understand, Fundamentals and Applications of Ultrasonic Waves, Second Edition provides an up-to-date exposition of ultrasonics and some of its main applications. Designed specifically for newcomers to the field, this fully updated second edition emphasizes underlying physical concepts over mathematics. The first half covers the fundamentals of ultrasonic waves for isotropic media. Starting with bulk liquid and solid media, discussion extends to surface and plate effects, at which point the author introduces new modes such as Rayleigh and Lamb waves. This focus on only isotropic media simplifies the usually complex mathematics involved, enabling a clearer understanding of the underlying physics to avoid the complicated tensorial description characteristic of crystalline media. The second part of the book addresses a broad spectrum of industrial and research applications, including quartz crystal resonators, surface acoustic wave devices, MEMS and microacoustics, and acoustic sensors. It also provides a broad discussion on the use of ultrasonics for non-destructive evaluation. The author concentrates on the developing area of microacoustics, including exciting new work on the use of probe microscopy techniques in nanotechnology. Focusing on the physics of acoustic waves, as well as their propagation, technology, and applications, this book addresses viscoelasticity, as well as new concepts in acoustic microscopy. It updates coverage of ultrasonics in nature and developments in sonoluminescence, and it also compares new technologies, including use of atomic force acoustic microscopy and lasers. Highlighting both direct and indirect applications for readers working in neighboring disciplines, the author presents particularly important sections on the use of microacoustics and acoustic nanoprobes in next-generation devices and instruments.

Author: Danick Briand
Publisher: John Wiley & Sons
ISBN: 3527319026
Category : Technology & Engineering
Languages : en
Pages : 492

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With its inclusion of the fundamentals, systems and applications, this reference provides readers with the basics of micro energy conversion along with expert knowledge on system electronics and real-life microdevices. The authors address different aspects of energy harvesting at the micro scale with a focus on miniaturized and microfabricated devices. Along the way they provide an overview of the field by compiling knowledge on the design, materials development, device realization and aspects of system integration, covering emerging technologies, as well as applications in power management, energy storage, medicine and low-power system electronics. In addition, they survey the energy harvesting principles based on chemical, thermal, mechanical, as well as hybrid and nanotechnology approaches. In unparalleled detail this volume presents the complete picture -- and a peek into the future -- of micro-powered microsystems.

Author: Otwin Breitenstein
Publisher: Springer Science & Business Media
ISBN: 3642024173
Category : Science
Languages : en
Pages : 260

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This is the first book on lock-in thermography, an analytical method applied to the diagnosis of microelectronic devices. This useful introduction and guide reviews various experimental approaches to lock-in thermography, with special emphasis on the lock-in IR thermography developed by the authors themselves.

Author: Birke Peter Kai
Publisher: World Scientific
ISBN: 9813272171
Category : Technology & Engineering
Languages : en
Pages : 304

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This richly illustrated book written by Professor Kai Peter Birke and several co-authors addresses both scientific and engineering aspects of modern batteries in a unique way. Emphasizing the engineering part of batteries, the book acts as a compass towards next generation batteries for automotive and stationary applications. The book provides distinguished answers to still open questions on how future batteries look like.Modern Battery Engineering explains why and how batteries have to be designed for successful commercialization in e-mobility and stationary applications. The book will help readers understand the principle issues of battery designs, paving the way for engineers to avoid wrong paths and settle on appropriate cell technologies for next generation batteries. This book is ideal for training courses for readers interested in the field of modern batteries.

Author: International Atomic Energy Agency
Publisher:
ISBN:
Category : Eddy current testing
Languages : en
Pages :

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Author: Raman Singh
Publisher: John Wiley & Sons
ISBN: 1118350057
Category : Technology & Engineering
Languages : en
Pages : 448

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A comprehensive text to the non-destructive evaluation of degradation of materials due to environment that takes an interdisciplinary approach Non-Destructive Evaluation of Corrosion and Corrosion-assisted Cracking is an important resource that covers the critical interdisciplinary topic of non-destructive evaluation of degradation of materials due to environment. The authors—noted experts in the field—offer an overview of the wide-variety of approaches to non-destructive evaluation and various types of corrosion. The text is filled with instructive case studies from a range of industries including aerospace, energy, defense, and processing. The authors review the most common non-destructive evaluation techniques that are applied in both research and industry in order to evaluate the properties and more importantly degradation of materials components or systems without causing damage. Ultrasonic, radiographic, thermographic, electromagnetic, and optical are some of the methods explored in the book. This important text: Offers a groundbreaking interdisciplinary approach to of non-destructive evaluation of corrosion and corrosion-assisted cracking Discusses techniques for non-destructive evaluation and various types of corrosion Includes information on the application of a variety of techniques as well as specific case studies Contains information targeting industries such as aerospace, energy, processing Presents information from leading researchers and technologists in both non-destructive evaluation and corrosion Written for life assessment and maintenance personnel involved in quality control, failure analysis, and R&D, Non-Destructive Evaluation of Corrosion and Corrosion-assisted Cracking is an essential interdisciplinary guide to the topic.