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Author: Max Wolfsberg Publisher: Springer ISBN: 9789400790933 Category : Science Languages : en Pages : 0
Book Description
As the title suggests, Isotope Effects in the Chemical, Geological and Bio Sciences deals with differences in the properties of isotopically substituted molecules, such as differences in the chemical and physical properties of water and the heavy waters. Since the various fields in which isotope effects are applied do not only share fundamental principles but also experimental techniques, this book includes a discussion of experimental apparatus and experimental techniques. Isotope Effects in the Chemical, Geological and Bio Sciences is an educational monograph addressed to graduate students and others undertaking isotope effect research. The fundamental principles needed to understand isotope effects are presented in appropriate detail. While it is true that these principles are more familiar to students of physical chemistry and some background in physical chemistry is recommended, the text provides enough detail to make the book an asset to students in organic and biochemistry, and geochemistry.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
The difference in rates of reaction of isotopic molecules may be utilized to produce appreciable isotope enrichments. When a competitive irreversible isotopic reaction is carried out to a high extent of completion, the residual unconverted substrate becomes exponentlally enriched in the heavier isotope. In deuterium systems, a substantial function of the D inventory is retained in the enriched residual substrate, so that conversion of the depleted product is unnecessary. For isotopes of heavier elements such as C/sup 13/, N/ sup 15/, and O/sup 18/ the retention is low, so that product conversion and recycling is desirable unless the starting material is of negligible value. Experiments are described in which enrichments of C/sup 13/ have been obtained using the reaction rate principle in dehydration of formic acid and hydrolysis of urea. Procedures are given for the preparation of decimolar barium carbonate at the level of 1.6% C/sup 13/, and molar barium carbonate at the 1.4% level starting with commercial materials. (J.R.D.).
Author: Max Wolfsberg Publisher: Springer Science & Business Media ISBN: 9048122651 Category : Science Languages : en Pages : 477
Book Description
As the title suggests, Isotope Effects in the Chemical, Geological and Bio Sciences deals with differences in the properties of isotopically substituted molecules, such as differences in the chemical and physical properties of water and the heavy waters. Since the various fields in which isotope effects are applied do not only share fundamental principles but also experimental techniques, this book includes a discussion of experimental apparatus and experimental techniques. Isotope Effects in the Chemical, Geological and Bio Sciences is an educational monograph addressed to graduate students and others undertaking isotope effect research. The fundamental principles needed to understand isotope effects are presented in appropriate detail. While it is true that these principles are more familiar to students of physical chemistry and some background in physical chemistry is recommended, the text provides enough detail to make the book an asset to students in organic and biochemistry, and geochemistry.
Author: Karl Cohen Publisher: ISBN: 9784871877060 Category : Science Languages : en Pages : 184
Book Description
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is various. The largest variety is used in research (e.g. in chemistry where atoms of "marker" nuclide are used to figure out reaction mechanisms). By tonnage, separating natural uranium into enriched uranium and depleted uranium is the largest application. In the following text, mainly the uranium enrichment is considered. This process is a crucial one in the manufacture of uranium fuel for nuclear power stations, and is also required for the creation of uranium based nuclear weapons. Plutonium-based weapons use plutonium produced in a nuclear reactor, which must be operated in such a way as to produce plutonium already of suitable isotopic mix or grade. While different chemical elements can be purified through chemical processes, isotopes of the same element have nearly identical chemical properties, which makes this type of separation impractical, except for separation of deuterium. There are three types of isotope separation techniques: Those based directly on the atomic weight of the isotope. Those based on the small differences in chemical reaction rates produced by different atomic weights. Those based on properties not directly connected to atomic weight, such as nuclear resonances. The third type of separation is still experimental; practical separation techniques all depend in some way on the atomic mass. It is therefore generally easier to separate isotopes with a larger relative mass difference. For example deuterium has twice the mass of ordinary (light) hydrogen and it is generally easier to purify it than to separate uranium-235 from the more common uranium-238. On the other extreme, separation of fissile plutonium-239 from the common impurity plutonium-240, while desirable in that it would allow the creation of gun-type nuclear weapons from plutonium, is generally agreed to be impractical.
Author: Amnon Kohen Publisher: CRC Press ISBN: 1420028022 Category : Medical Languages : en Pages : 1092
Book Description
The field of isotope effects has expanded exponentially in the last decade, and researchers are finding isotopes increasingly useful in their studies. Bringing literature on the subject up to date, Isotope Effects in Chemistry and Biology covers current principles, methods, and a broad range of applications of isotope effects in the physical, biolo
Author: Boris Mikhailovich Andreev Publisher: Elsevier ISBN: 0080468098 Category : Science Languages : en Pages : 317
Book Description
Separation of Isotopes of Biogenic Elements provides a detailed overview of this area of research covering all aspects from the value of isotope effects to their practical use (equilibrium single-stage isotope effect - kinetics and mass transfer – multiplication of the single-stage isotope separation factor - technological peculiarity of processes) with the purpose of extraction from the natural mixture of the enriched and highly concentrated isotopes. In contrast to traditional books on the theory of isotope separation, the theoretical part of the book describes separation in two-phase processes in counter-flow columns. The experimental part of the book presents systematic analysis of specialists in the field of isotope separation in counter-flow columns. This book will be of interest to scientists, engineers and technical workers engaged in isotope separation processes and isotope application in nuclear physics, medicine, agro-chemistry, biology and other areas. This book may also be used in teaching theory and practical aspects in courses on physical chemistry and Isotope separation of light elements by physicochemical methods. * summarises current state of isotope research, especially biogenic elements* covering all aspects from the value of isotope effects to their practical use* of interest to scientists, engineers and technical workers engaged in isotope separation processes and isotope application
Author: Attila Vértes Publisher: Springer Science & Business Media ISBN: 144190719X Category : Science Languages : en Pages : 3693
Book Description
This revised and extended 6 volume handbook set is the most comprehensive and voluminous reference work of its kind in the field of nuclear chemistry. The Handbook set covers all of the chemical aspects of nuclear science starting from the physical basics and including such diverse areas as the chemistry of transactinides and exotic atoms as well as radioactive waste management and radiopharmaceutical chemistry relevant to nuclear medicine. The nuclear methods of the investigation of chemical structure also receive ample space and attention. The international team of authors consists of scores of world-renowned experts - nuclear chemists, radiopharmaceutical chemists and physicists - from Europe, USA, and Asia. The Handbook set is an invaluable reference for nuclear scientists, biologists, chemists, physicists, physicians practicing nuclear medicine, graduate students and teachers - virtually all who are involved in the chemical and radiopharmaceutical aspects of nuclear science. The Handbook set also provides further reading via the rich selection of references.
Author: Max Wolfsberg
Author: 
Author: Max Wolfsberg
Author: Karl Cohen
Author: Amnon Kohen
Author: Lars C. S. Melander
Author: Boris Mikhailovich Andreev
Author: Lars C. S. Melander
Author: William Spindel
Author: G. M. Begun
Author: Attila Vértes