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Author: Samuel Cruz-Manzo Publisher: Elsevier ISBN: 0323914322 Category : Technology & Engineering Languages : en Pages : 388
Book Description
Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells: Fundamentals, Modelling, and Applications establishes how the electrochemical and diffusion mechanisms of a polymer electrolyte membrane fuel cell (PEMFC) are related to electrochemical impedance spectroscopy (EIS) measurements using physics-based impedance models derived from fundamental electrode and diffusion theories. The contribution of the different phenomena occurring at the different layers comprising the cathode on the impedance response of the PEMFC is revealed through EIS-modelling analysis. The relation between EIS measurements and polarisation curves representing the performance of PEMFCs is established. Insight is gained into how the EIS response of the PEMFC changes at different operating conditions e.g. relative humidity, load demand, gas reactant stoichiometry and temperature using physics-based impedance models. The application of impedance models with EIS measurements carried out in the individual cells comprising a PEMFC stack is demonstrated, while recent modelling approaches and other impedance models reported in the literature to represent the EIS response of the PEMFC are also considered and discussed. - Provides further understanding of ambiguities during the interpretation of the electrochemical impedance spectrum of the PEMFC - Includes impedance models written in MATLAB® for replication or application to other PEMFC-EIS measurements - Includes impedance spectra of the PEMFC at different operating conditions, electro/diffusion pathways for derivation of the impedance models and flowcharts for application of the impedance models with real-world measured EIS data
Author: Samuel Cruz-Manzo Publisher: Elsevier ISBN: 0323914322 Category : Technology & Engineering Languages : en Pages : 388
Book Description
Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells: Fundamentals, Modelling, and Applications establishes how the electrochemical and diffusion mechanisms of a polymer electrolyte membrane fuel cell (PEMFC) are related to electrochemical impedance spectroscopy (EIS) measurements using physics-based impedance models derived from fundamental electrode and diffusion theories. The contribution of the different phenomena occurring at the different layers comprising the cathode on the impedance response of the PEMFC is revealed through EIS-modelling analysis. The relation between EIS measurements and polarisation curves representing the performance of PEMFCs is established. Insight is gained into how the EIS response of the PEMFC changes at different operating conditions e.g. relative humidity, load demand, gas reactant stoichiometry and temperature using physics-based impedance models. The application of impedance models with EIS measurements carried out in the individual cells comprising a PEMFC stack is demonstrated, while recent modelling approaches and other impedance models reported in the literature to represent the EIS response of the PEMFC are also considered and discussed. - Provides further understanding of ambiguities during the interpretation of the electrochemical impedance spectrum of the PEMFC - Includes impedance models written in MATLAB® for replication or application to other PEMFC-EIS measurements - Includes impedance spectra of the PEMFC at different operating conditions, electro/diffusion pathways for derivation of the impedance models and flowcharts for application of the impedance models with real-world measured EIS data
Author: Xiao-Zi (Riny) Yuan Publisher: Springer Science & Business Media ISBN: 1848828462 Category : Science Languages : en Pages : 428
Book Description
"Electrochemical Impedance Spectroscopy in PEM Fuel Cells" discusses one of the most powerful and useful diagnostic tools for various aspects of the study of fuel cells: electrochemical impedance spectroscopy (EIS). This comprehensive reference on EIS fundamentals and applications in fuel cells contains information about basic principles, measurements, and fuel cell applications of the EIS technique. Many illustrated examples are provided to ensure maximum clarity and observability of the spectra. "Electrochemical Impedance Spectroscopy in PEM Fuel Cells" will enable readers to explore the frontiers of EIS technology in PEM fuel cell research and other electrochemical systems. As well as being a useful text for electrochemists, it can also help researchers who are unfamiliar with EIS to learn the technique quickly and to use it correctly in their fuel cell research. Managers or entrepreneurs may also find this book a useful guide to accessing the challenges and opportunities in fuel cell technology.
Author: Qingfeng Li Publisher: Springer ISBN: 3319170821 Category : Technology & Engineering Languages : en Pages : 561
Book Description
This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept of and motivated extensive research activity in the field. The last 11 chapters summarize the state-of-the-art of technological development of high temperature-PEMFCs based on acid doped PBI membranes including catalysts, electrodes, MEAs, bipolar plates, modelling, stacking, diagnostics and applications.
Author: Matthew M. Mench Publisher: Academic Press ISBN: 0123869366 Category : Technology & Engineering Languages : en Pages : 474
Book Description
For full market implementation of PEM fuel cells to become a reality, two main limiting technical issues must be overcome- cost and durability. This cutting-edge volume directly addresses the state-of-the-art advances in durability within every fuel cell stack component. [...] chapters on durability in the individual fuel cell components -- membranes, electrodes, diffusion media, and bipolar plates -- highlight specific degradation modes and mitigation strategies. The book also includes chapters which synthesize the component-related failure modes to examine experimental diagnostics, computational modeling, and laboratory protocol"--Back cover.
Author: Frano Barbir Publisher: Academic Press ISBN: 0123877105 Category : Science Languages : en Pages : 537
Book Description
Demand for fuel cell technology is growing rapidly. Fuel cells are being commercialized to provide power to buildings like hospitals and schools, to replace batteries in portable electronic devices, and as replacements for internal combustion engines in vehicles. PEM (Proton Exchange Membrane) fuel cells are lighter, smaller, and more efficient than other types of fuel cell. As a result, over 80% of fuel cells being produced today are PEM cells. This new edition of Dr. Barbir's groundbreaking book still lays the groundwork for engineers, technicians and students better than any other resource, covering fundamentals of design, electrochemistry, heat and mass transport, as well as providing the context of system design and applications. Yet it now also provides invaluable information on the latest advances in modeling, diagnostics, materials, and components, along with an updated chapter on the evolving applications areas wherein PEM cells are being deployed. Comprehensive guide covers all aspects of PEM fuel cells, from theory and fundamentals to practical applications Provides solutions to heat and water management problems engineers must face when designing and implementing PEM fuel cells in systems Hundreds of original illustrations, real-life engineering examples, and end-of-chapter problems help clarify, contextualize, and aid understanding
Author: Mark E. Orazem Publisher: John Wiley & Sons ISBN: 111820994X Category : Science Languages : en Pages : 510
Book Description
Using electrochemical impedance spectroscopy in a broad range of applications This book provides the background and training suitable for application of impedance spectroscopy to varied applications, such as corrosion, biomedical devices, semiconductors and solid-state devices, sensors, batteries, fuel cells, electrochemical capacitors, dielectric measurements, coatings, electrochromic materials, analytical chemistry, and imaging. The emphasis is on generally applicable fundamentals rather than on detailed treatment of applications. With numerous illustrative examples showing how these principles are applied to common impedance problems, Electrochemical Impedance Spectroscopy is ideal either for course study or for independent self-study, covering: Essential background, including complex variables, differential equations, statistics, electrical circuits, electrochemistry, and instrumentation Experimental techniques, including methods used to measure impedance and other transfer functions Process models, demonstrating how deterministic models of impedance response can be developed from physical and kinetic descriptions Interpretation strategies, describing methods of interpretating of impedance data, ranging from graphical methods to complex nonlinear regression Error structure, providing a conceptual understanding of stochastic, bias, and fitting errors in frequency-domain measurements An overview that provides a philosophy for electrochemical impedance spectroscopy that integrates experimental observation, model development, and error analysis This is an excellent textbook for graduate students in electrochemistry, materials science, and chemical engineering. It's also a great self-study guide and reference for scientists and engineers who work with electrochemistry, corrosion, and electrochemical technology, including those in the biomedical field, and for users and vendors of impedance-measuring instrumentation.
Author: Vadim F. Lvovich Publisher: John Wiley & Sons ISBN: 0470627786 Category : Science Languages : en Pages : 368
Book Description
This book presents a balance of theoretical considerations and practical problem solving of electrochemical impedance spectroscopy. This book incorporates the results of the last two decades of research on the theories and applications of impedance spectroscopy, including more detailed reviews of the impedance methods applications in industrial colloids, biomedical sensors and devices, and supercapacitive polymeric films. The book covers all of the topics needed to help readers quickly grasp how to apply their knowledge of impedance spectroscopy methods to their own research problems. It also helps the reader identify whether impedance spectroscopy may be an appropriate method for their particular research problem. This includes understanding how to correctly make impedance measurements, interpret the results, compare results with expected previously published results form similar chemical systems, and use correct mathematical formulas to verify the accuracy of the data. Unique features of the book include theoretical considerations for dealing with modeling, equivalent circuits, and equations in the complex domain, review of impedance instrumentation, best measurement methods for particular systems and alerts to potential sources of errors, equations and circuit diagrams for the most widely used impedance models and applications, figures depicting impedance spectra of typical materials and devices, extensive references to the scientific literature for more information on particular topics and current research, and a review of related techniques and impedance spectroscopy modifications.
Author: Andrzej Lasia Publisher: Springer ISBN: 1461489334 Category : Science Languages : en Pages : 376
Book Description
This book presents a complete overview of the powerful but often misused technique of Electrochemical Impedance Spectroscopy (EIS). The book presents a systematic and complete overview of EIS. The book carefully describes EIS and its application in studies of electrocatalytic reactions and other electrochemical processes of practical interest. This book is directed towards graduate students and researchers in Electrochemistry. Concepts are illustrated through detailed graphics and numerous examples. The book also includes practice problems. Additional materials and solutions are available online.
Author: Michael Eikerling Publisher: CRC Press ISBN: 1439854068 Category : Science Languages : en Pages : 567
Book Description
The book provides a systematic and profound account of scientific challenges in fuel cell research. The introductory chapters bring readers up to date on the urgency and implications of the global energy challenge, the prospects of electrochemical energy conversion technologies, and the thermodynamic and electrochemical principles underlying the op
Author: Cornelia Breitkopf Publisher: Springer ISBN: 3662466570 Category : Technology & Engineering Languages : en Pages : 1019
Book Description
This comprehensive handbook covers all fundamentals of electrochemistry for contemporary applications. It provides a rich presentation of related topics of electrochemistry with a clear focus on energy technologies. It covers all aspects of electrochemistry starting with theoretical concepts and basic laws of thermodynamics, non-equilibrium thermodynamics and multiscale modeling. It further gathers the basic experimental methods such as potentiometry, reference electrodes, ion-sensitive electrodes, voltammetry and amperometry. The contents cover subjects related to mass transport, the electric double layer, ohmic losses and experimentation affecting electrochemical reactions. These aspects of electrochemistry are especially examined in view of specific energy technologies including batteries, polymer electrolyte and biological fuel cells, electrochemical capacitors, electrochemical hydrogen production and photoelectrochemistry. Organized in six parts, the overall complexity of electrochemistry is presented and makes this handbook an authoritative reference and definitive source for advanced students, professionals and scientists particularly interested in industrial and energy applications.
Author: Samuel Cruz-Manzo
Author: Samuel Cruz-Manzo
Author: Xiao-Zi (Riny) Yuan
Author: Qingfeng Li
Author: Matthew M. Mench
Author: Frano Barbir
Author: Mark E. Orazem
Author: Vadim F. Lvovich
Author: Andrzej Lasia
Author: Michael Eikerling
Author: Cornelia Breitkopf