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Development of Single and Array Electro-chemical Sensors for Real-time Trace Metal Analysis in Aqueous Environmental Media

Development of Single and Array Electro-chemical Sensors for Real-time Trace Metal Analysis in Aqueous Environmental Media PDF Author: Yuanyuan Yang
Publisher:
ISBN:
Category : Chemistry, Analytic
Languages : en
Pages : 139

Book Description
Detection of trace metals has great importance in environmental and biological applications. While traditional electrochemical techniques have played critical roles in this field, their usefulness is limited by temporal resolution, Hg toxicity and stability concerns. Recently, we developed a method using fast-scan cyclic voltammetry (FSCV) at carbon-fiber microelectrodes (CFMs) to achieve rapid measurement of metal ions with high sensitivity, selectivity, and stability. Through optimizations this method showed strengths in real-time trace metal analysis. Analytical selectivity was improved via covalent functionalization on CFMs. We employed diazonium electrochemical reduction followed by click chemistry to create robust covalent attachments. We showcased its application through grafting Cu(II) ionophores onto CFMs. The selectivity was further reinforced via inhibition of other species' adsorption at surface oxygen groups. This stepwise functionalization approach served as a universal platform for elevating CFMs' selectivity, while retaining sensitivity, response, stability, and lifetime. In parallel work, pyrolyzed photoresist film (PPF) microelectrode arrays (MEAs) were fabricated to extend the borderlines of FSCV towards simultaneous multi-analyte analysis. The PPF MEAs maintained CFM's carbon-fiber structures but provided more sensing channels. We employed a two-step pyrolysis process and a dual oxygen plasma treatment to improve fabrication repeatability, surface reactivity, and spatial geometry. Our technique has evident potential to achieve real-time simultaneous detection of various electroactive molecules and be employed for numerous applications in complex biological and environmental systems.

Development of Single and Array Electro-chemical Sensors for Real-time Trace Metal Analysis in Aqueous Environmental Media

Development of Single and Array Electro-chemical Sensors for Real-time Trace Metal Analysis in Aqueous Environmental Media PDF Author: Yuanyuan Yang
Publisher:
ISBN:
Category : Chemistry, Analytic
Languages : en
Pages : 139

Book Description
Detection of trace metals has great importance in environmental and biological applications. While traditional electrochemical techniques have played critical roles in this field, their usefulness is limited by temporal resolution, Hg toxicity and stability concerns. Recently, we developed a method using fast-scan cyclic voltammetry (FSCV) at carbon-fiber microelectrodes (CFMs) to achieve rapid measurement of metal ions with high sensitivity, selectivity, and stability. Through optimizations this method showed strengths in real-time trace metal analysis. Analytical selectivity was improved via covalent functionalization on CFMs. We employed diazonium electrochemical reduction followed by click chemistry to create robust covalent attachments. We showcased its application through grafting Cu(II) ionophores onto CFMs. The selectivity was further reinforced via inhibition of other species' adsorption at surface oxygen groups. This stepwise functionalization approach served as a universal platform for elevating CFMs' selectivity, while retaining sensitivity, response, stability, and lifetime. In parallel work, pyrolyzed photoresist film (PPF) microelectrode arrays (MEAs) were fabricated to extend the borderlines of FSCV towards simultaneous multi-analyte analysis. The PPF MEAs maintained CFM's carbon-fiber structures but provided more sensing channels. We employed a two-step pyrolysis process and a dual oxygen plasma treatment to improve fabrication repeatability, surface reactivity, and spatial geometry. Our technique has evident potential to achieve real-time simultaneous detection of various electroactive molecules and be employed for numerous applications in complex biological and environmental systems.

Environmental Analysis by Electrochemical Sensors and Biosensors

Environmental Analysis by Electrochemical Sensors and Biosensors PDF Author: Ligia Maria Moretto
Publisher: Springer
ISBN: 1493913018
Category : Science
Languages : en
Pages : 455

Book Description
This book discusses in detail the analysis and monitoring of the most important analytes in the environmental field. It also reviews the implementation, realization and application of sensor designs mentioned in the first volume of this set, dividing the coverage into global parameters, sensors of organics and sensors of inorganics.

Environmental Analysis by Electrochemical Sensors and Biosensors

Environmental Analysis by Electrochemical Sensors and Biosensors PDF Author: Ligia Maria Moretto
Publisher: Springer
ISBN: 1493906763
Category : Science
Languages : en
Pages : 714

Book Description
This book presents an exhaustive overview of electrochemical sensors and biosensors for the analysis and monitoring of the most important analytes in the environmental field, in industry, in treatment plants and in environmental research. The chapters give the reader a comprehensive, state-of-the-art picture of the field of electrochemical sensors suitable to environmental analytes, from the theoretical principles of their design to their implementation, realization and application. The first three chapters discuss fundamentals, and the last three chapters cover the main groups of analytes of environmental interest.

Smart Sensors for Environmental and Medical Applications

Smart Sensors for Environmental and Medical Applications PDF Author: Hamida Hallil
Publisher: John Wiley & Sons
ISBN: 1119587344
Category : Technology & Engineering
Languages : en
Pages : 240

Book Description
Provides an introduction to the topic of smart chemical sensors, along with an overview of the state of the art based on potential applications This book presents a comprehensive overview of chemical sensors, ranging from the choice of material to sensor validation, modeling, simulation, and manufacturing. It discusses the process of data collection by intelligent techniques such as deep learning, multivariate analysis, and others. It also incorporates different types of smart chemical sensors and discusses each under a common set of sub-sections so that readers can fully understand the advantages and disadvantages of the relevant transducers—depending on the design, transduction mode, and final applications. Smart Sensors for Environmental and Medical Applications covers all major aspects of the field of smart chemical sensors, including working principle and related theory, sensor materials, classification of respective transducer type, relevant fabrication processes, methods for data analysis, and suitable applications. Chapters address field effect transistors technologies for biological and chemical sensors, mammalian cell–based electrochemical sensors for label-free monitoring of analytes, electronic tongues, chemical sensors based on metal oxides, metal oxide (MOX) gas sensor electronic interfaces, and more. Addressing the limitations and challenges in obtaining state-of-the-art smart biochemical sensors, this book: Balances the fundamentals of sensor design, fabrication, characterization, and analysis with advanced methods Categorizes sensors into sub-types and describes their working, focusing on prominent applications Describes instrumentation and IoT networking methods of chemical transducers that can be used for inexpensive, accurate detection in commercialized smart chemical sensors Covers monitoring of food spoilage using polydiacetylene- and liposome-based sensors; smart and intelligent E-nose for sensitive and selective chemical sensing applications; odor sensing system; and microwave chemical sensors Smart Sensors for Environmental and Medical Applications is an important book for senior-level undergraduate and graduate students learning about this high-performance technology and its many applications. It will also inform practitioners and researchers involved in the creation and use of smart sensors.

Electrochemical Sensor Analysis

Electrochemical Sensor Analysis PDF Author: Salvador Alegret
Publisher: Elsevier
ISBN: 0080560695
Category : Science
Languages : en
Pages : 1416

Book Description
Electrochemical Sensor Analysis (ECSA) presents the recent advances in electrochemical (bio)sensors and their practical applications in real clinical, environment, food and industry related samples, as well as in the safety and security arena. In a single source, it covers the entire field of electrochemical (bio)sensor designs and characterizations. The 38 chapters are grouped in seven sections: 1) Potentiometric sensors, 2) Voltammetric sensors, 3) Electrochemical gas sensors 4) Enzyme-based sensors 5) Affinity biosensors 6) Thick and thin film biosensors and 7) Novel trends. Written by experts working in the diverse technological and scientific fields related to electrochemical sensors, each section provides an overview of a specific class of electrochemical sensors and their applications. This interdisciplinary text will be useful for researchers and professionals alike. Covers applications and problem solving (sensitivity, interferences) in real sample analysis Details procedures to construct and characterize electrochemical (bio)sensors

Environmental, Chemical and Medical Sensors

Environmental, Chemical and Medical Sensors PDF Author: Shantanu Bhattacharya
Publisher: Springer
ISBN: 9811077517
Category : Technology & Engineering
Languages : en
Pages : 414

Book Description
This book covers the fundamentals of sensor technologies as well as the recent research for the development of environmental, chemical and medical sensor technologies. Chapters include current research on microflow cytometry, microfluidic devices, colorimetric sensors, and the development of low-cost optical densitometric sensors and paper based analytical devices for environmental and biomedical applications. Special focus has been given to nanotechnology and nanostructures- their fabrication, uses and utility in different fields of research such as for the design of tools for medical diagnostics, therapeutics, as well as for detection and estimation of pollutant levels in water and air quality monitoring. This book is intended as a resource for researchers working in the field of sensor development across the world.

Sensor Systems for Environmental Monitoring

Sensor Systems for Environmental Monitoring PDF Author: M. Campbell
Publisher: Springer Science & Business Media
ISBN: 9400915713
Category : Science
Languages : en
Pages : 325

Book Description


Multielement Electrochemical Sensors for Trace Metal Analysis in Aqueous Solutions

Multielement Electrochemical Sensors for Trace Metal Analysis in Aqueous Solutions PDF Author: Stevan Bauer Saban
Publisher:
ISBN:
Category : Electrochemical sensors
Languages : en
Pages : 336

Book Description


Surfactant Based Electrochemical Sensors and Biosensors

Surfactant Based Electrochemical Sensors and Biosensors PDF Author: Jamballi G. Manjunatha
Publisher: Elsevier
ISBN: 0443154945
Category : Technology & Engineering
Languages : en
Pages : 538

Book Description
Surfactant Based Electrochemical Sensors and Biosensors discusses the applications of surfactants for Electrochemical Sensors. Surfactant based electrochemical sensors exhibits elevated sensitivity, selectivity, stability and accuracy as compared to other analytical techniques. The fabricated sensors can be applied for routine analysis in clinical and industrial samples with acceptable recovery. This book covers the emerging research trends and exploitation of surfactants for electrochemical sensor preparation for its applications in various fields such as academia, medicine, industry and monitoring of environmental species. The key focus of this book is to expand scientific research in the field of electrochemistry on surfactant based electrochemical sensors in order to construct highly sensitive devices. Part one presents the characteristics of surfactants and discusses their application for the fabrication of electrochemical sensors and bio sensors. Part two addresses the analysis of toxic chemicals and their quantitative determination and offers surfactant based sensing platforms for environmental modelling. Part three discusses the significance of the analysis of molecules and ions in biological and pharmaceutical sampling. Part four presents new methodologies for the determination of food additives and biological molecules present in food samples. Part 5 explores the Sustainability, Safety and Toxicity Aspects of Surfactant Modified Electrochemical Sensors and Biosensors. Presents emerging research trends and discusses the exploitation of surfactants for electrochemical sensor preparation and its applications for multi-disciplinary fields Addresses the development process for a sensitive, robust, and responsive sensor with the use of surfactants Presents the utilization of surfactant based sensors in real-time analysis

Electrochemical Sensors Technology

Electrochemical Sensors Technology PDF Author: Mohammed Rahman
Publisher: BoD – Books on Demand
ISBN: 9535131931
Category : Technology & Engineering
Languages : en
Pages : 172

Book Description
This book Electrochemical Sensors Technology mostly reviews the modem methods and significant electrochemical and electroanalytical applications of chemical sensors and biosensors. Chapters of this book are invited and contributed from the experts throughout the world from prominent researchers and scientists in the field of sensors and in the field of electro- and biochemistry. Each chapter provides technical and methodological details beyond the level found in typical journal articles or reviews and explores the application of chemical sensors, environmental sensors, and biosensors to a significant problem in biomedical and environmental science, also providing a prospectus for the future. This book compiles with the expert knowledge of many specialists in the construction and use of chemical sensors and biosensors including chemical sensors, biological sensors, DNA sensors, immunosensors, gaseous sensors, ionic sensors, bioassay sensors, lab-on-chips, devices, portable sensors, microchips, nanosensors, implantable microsensors, and so on in the field of fundamental and applied electrochemistry. Highlights and importance are laid on real or practical problems, ranging from chemical application to biomedical monitoring, from in vitro to in vivo, and from single cell to animal to human measurement. This offers a unique opportunity of exchanging and combining the scientist or researcher in electrochemical sensors in largely chemistry, biological engineering, electronic engineering, and biomedical and physiological fields.