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Author: David Morales-Morales Publisher: Elsevier ISBN: 0128129328 Category : Science Languages : en Pages : 756
Book Description
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. - Describes the chemistry and applications of this important class of organometallic and coordination compounds - Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes - Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry
Author: David Morales-Morales Publisher: Elsevier ISBN: 0128129328 Category : Science Languages : en Pages : 756
Book Description
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. - Describes the chemistry and applications of this important class of organometallic and coordination compounds - Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes - Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry
Author: Joseph Shinar Publisher: Springer Science & Business Media ISBN: 9780387953434 Category : Science Languages : en Pages : 334
Book Description
Although it has long been possible to make organic materials emit light, it has only recently become possible to do so at the level and with the efficiency and control necessary to make the materials a useful basis for illumination or displays. The early electroluminescent devices provided reasonably bright light, but required high operating voltages, produced only a narrow range of colors, and had severely limited lifetimes. Recent developments, however, make it possible to manufacture organic light-emitting devices that are thin, bright, efficient, and stable and that produce a broad range of colors. This book surveys the current status of the field. It begins with an overview of the physics and chemistry of organic light emitting devices by J. Shinar and V. Savvateev. Subsequenbt chapters discuss the design of molecular materials for high performance devices (C. Adachi and T. Tsutsui) and chemical degradation and physical aging (K. Higginson, D. L. Thomsen, B. Yang, and F. Papadimitrakopoulos). A. Dodabalapur describes microcavity OLEDs, and Y. Shi, J. Liu, and Y. Yang discuss polymer morphology and device performance. Various aspects of devices based on polyparaphenylene vinylenes are discussed in chapters by N.C. Greenham and R.H. Friend and by H. Chayet, V. Savvateeyv, D. Davidov and R. Neumann. Chapters by S. Tasch, W. Graupner, and G. Leising and by Y. Z. Wang, D. Gebler, and A. J. Epstein describe OLEDs based on poly(paraphenylene) and poly(pyridine), respectively. The book concludes with a chapter on polyfluorene-based devices, which show great promise for producing light in all colors from blue to red.
Author: S. Huzinaga Publisher: Elsevier ISBN: 044459647X Category : Science Languages : en Pages : 435
Book Description
Physical Sciences Data, Volume 16: Gaussian Basis Sets for Molecular Calculations provides information pertinent to the Gaussian basis sets, with emphasis on lithium, radon, and important ions. This book discusses the polarization functions prepared for lithium through radon for further improvement of the basis sets. Organized into three chapters, this volume begins with an overview of the basis set for the most stable negative and positive ions. This text then explores the total atomic energies given by the basis sets. Other chapters consider the distinction between diffuse functions and polarization function. This book presents as well the exponents of polarization function. The final chapter deals with the Gaussian basis sets. This book is a valuable resource for chemists, scientists, and research workers.
Author: D. Max Roundhill Publisher: Springer Science & Business Media ISBN: 1475761015 Category : Science Languages : en Pages : 422
Book Description
This book is intended to offer the reader a snapshot of the field of optoelectronic materials from the viewpoint of inorganic chemists. The field of inorganic chemistry is transforming from one focused on the synthesis of compounds having interesting coordination numbers, structures, and stereochemistries, to one focused on preparing compounds that have potentially useful practical applica tions. Two such applications are in the area of optics and electronics. These are fields where the use of inorganic materials has a long history. As the field of microelectronics develops the demands on the performance of such materials increases, and it becomes necessary to discover compounds that will meet these demands. The field of optoelectronics represents a merging of the two disciplines. Its emergence is a natural one because many of the applications involve both of these properties, and also because the electronic structure of a metal compound that confers novel optical properties is often one that also influences its electron transfer and conductivity characteristics. Two of the more important growth areas that have led to these developments are communications and medicine. Within the communications field there is the microelectronics that is involved in information storage and transmittal, some of which will be transferred into the optical regime. Within the medical field there are chemical probes that transmit analytical information from an in vivo environment. This information needs to be readily accessible from an external site, and then quickly converted into images or data that yield accurate and inexpensive diagnoses.
Author: Gerard van Koten Publisher: Springer ISBN: 3642310818 Category : Science Languages : en Pages : 363
Book Description
Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.
Author: Iwao Omae Publisher: Springer Science & Business Media ISBN: 4431546049 Category : Science Languages : en Pages : 214
Book Description
This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
Author: Kenneth Kam-Wing Lo Publisher: ISBN: 9783662467190 Category : Languages : en Pages :
Book Description
The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.
Author: Jose Luis Serrano Publisher: John Wiley & Sons ISBN: 3527615083 Category : Technology & Engineering Languages : en Pages : 517
Book Description
Research on metal-containing liquid crystals is a rapidly expanding, multidisciplinary field with new materials continually being synthesized and novel applications being developed. 'Metallomesogens' is the first comprehensive survey of the field, introducing the reader to: * materials design * synthesis * physical properties * emerging applications Carefully selected references round off this well-organized compendium. It is an indispensable guide to experienced researchers in coordination and organometallic chemistry as well as in liquid-crystal and materials science. Newcomers and graduate students will also benefit from this didactically sound introduction to the field.
Author: Donald T. Sawyer Publisher: Wiley-Interscience ISBN: 9780471594680 Category : Science Languages : en Pages : 528
Book Description
A complete and practical guide to the basic principles of electrochemistry for the nonspecialist Emphasizing practical applications and real-world experimentation, Electrochemistry for Chemists gives chemists, biologists, and material scientists a solid understanding of the basic principles and modern methodology of electrochemistry. Incorporating the many new applications of recent years, this thoroughly updated Second Edition gives the nonelectrochemist access to a powerful tool for the study and measurement of chemical systems. And, like the popular first edition, the Second Edition is also a useful text for senior undergraduate and graduate students, especially in organic, inorganic, and biological chemistry. * Offers a practical guide to the use of electrochemical methods in research and laboratory work * Provides examples of molecular characterization by electrochemical methods in all subdivisions of chemistry, including dioxygen species, base metals, and nonmetals * Includes numerous tables of electrochemical data, as well as physical parameters for solvents, electrolytes, cells, and electrodes * Incorporates the latest information on instrumentation, solvents, and reagents * Lists extensive references for further study of theoretical issues
Author: David Morales-Morales
Author: David Morales-Morales
Author: Hartmut Yersin
Author: Joseph Shinar
Author: S. Huzinaga
Author: D. Max Roundhill
Author: Gerard van Koten
Author: Iwao Omae
Author: Kenneth Kam-Wing Lo
Author: Jose Luis Serrano
Author: Donald T. Sawyer