Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.
Author: Publisher: ISBN: Category : Languages : en Pages : 11
Book Description
A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.
Author: Robert J. Lemire Publisher: Elsevier ISBN: 9780444503794 Category : Medical Languages : en Pages : 876
Book Description
Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.
Author: R. Guillaumont Publisher: ISBN: Category : Science Languages : en Pages : 976
Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency, and updates and expands the thermodynamic data on inorganic compounds and complexes of uranium, neptunium, plutonium, americium and technetium contained in the previous volumes of the series. A review team, composed of seven internationally recognized experts, has critically reviewed during five years all the scientific literature containing chemical thermodynamic information for the above mentioned systems that has appeared since the publication of the earlier volumes. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains new tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.
Author: Paul L. Brown Publisher: John Wiley & Sons ISBN: 3527656200 Category : Science Languages : en Pages : 1449
Book Description
Endlich ein Fachbuch, das die Theorie, Methoden und die verschiedenen Arten von Metall-Ionen-Komplexen in Wasser (Hydrolyse) umfassend behandelt. Geschrieben wurde dieses Referenzwerk von einem Kernchemiker aus dem Hochschulbereich und einem Geochemiker aus der Industrie. Behandelt werden Kationen- und Anionen-Komplexe sowie die Metall-Ionen-Hydrolyse, zu der zunächst Hintergrundinformationen geliefert werden, bevor eine Beschreibung der Dissoziation von Wasser, aller verschiedenen Hydrolysekomplexe und Verbindungen von Metall und Wasser folgt. Ein Muss für Wissenschaftler im universitären Umfeld und in der Industrie, die sich mit diesem interdisziplinären Thema beschäftigen.
Author: L.R. Morss Publisher: Springer Science & Business Media ISBN: 1402035985 Category : Science Languages : en Pages : 4059
Book Description
The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.
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Author: Robert J. Lemire
Author: R. Guillaumont
Author: Paul L. Brown
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Author: L.R. Morss