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Cross Sections and Rate Constants for Ion-molecule Reactions

Cross Sections and Rate Constants for Ion-molecule Reactions PDF Author: George Gioumousis
Publisher:
ISBN:
Category : Cross sections (Nuclear physics)
Languages : en
Pages : 198

Book Description
The importance of ion-neutral reactions is well recognized, especially in the study of the chemistry of upper atmosphere. The first section of the report is concerned with refining the calculation of the cross section from the long-range interactions, assuming an arbitrary classical potential. The cross section so found is not regarded as an approximation to the reaction cross section, but rather the cross section for any sort of significant interaction, that is, the sum of the cross sections for elastic scattering, inelastic scattering, and the various reactions that can occur. The next section is a rigorous analysis of the experiments, based on the kinetic theory of gases, from the point of view of expressing whatever macroscopic parameters the experiment yields in terms of the reaction cross section, which is assumed known as a function of energy. An approximate method is developed which inverts the relationship and yields the reaction cross section as a function of energy if the experimental data are adequate. The final section applied the above-mentioned method to various reactions. This is believed to be the only way to find the cross section as such for ion-neutral reactions in the energy range somewhat above thermal. Some new and unexpected results were found by this method, especially for the H2, Ne reaction. (Author).

Cross Sections and Rate Constants for Ion-molecule Reactions

Cross Sections and Rate Constants for Ion-molecule Reactions PDF Author: George Gioumousis
Publisher:
ISBN:
Category : Cross sections (Nuclear physics)
Languages : en
Pages : 198

Book Description
The importance of ion-neutral reactions is well recognized, especially in the study of the chemistry of upper atmosphere. The first section of the report is concerned with refining the calculation of the cross section from the long-range interactions, assuming an arbitrary classical potential. The cross section so found is not regarded as an approximation to the reaction cross section, but rather the cross section for any sort of significant interaction, that is, the sum of the cross sections for elastic scattering, inelastic scattering, and the various reactions that can occur. The next section is a rigorous analysis of the experiments, based on the kinetic theory of gases, from the point of view of expressing whatever macroscopic parameters the experiment yields in terms of the reaction cross section, which is assumed known as a function of energy. An approximate method is developed which inverts the relationship and yields the reaction cross section as a function of energy if the experimental data are adequate. The final section applied the above-mentioned method to various reactions. This is believed to be the only way to find the cross section as such for ion-neutral reactions in the energy range somewhat above thermal. Some new and unexpected results were found by this method, especially for the H2, Ne reaction. (Author).

Ion-molecule Reactions

Ion-molecule Reactions PDF Author: Henry M. Rosenstock
Publisher:
ISBN:
Category : Ion-molecule collisions
Languages : en
Pages : 206

Book Description


Ion-Molecule Reactions

Ion-Molecule Reactions PDF Author: J. Franklin
Publisher: Springer Science & Business Media
ISBN: 1475700881
Category : Science
Languages : en
Pages : 394

Book Description
After a few faint stirrings of interest in ion-molecule reactions during the early days of mass spectrometry, the subject was almost completely neglected for many years. There was a renascence of interest in the subject following pioneering experiments by Tal'roze in Russia and independently by Steven son and Schissler and Field, Franklin, and Lampe in this country. Since that time, interest in the subject has continued to grow and the number of papers published to expand almost exponentially during the past 15 years. The result is a body of literature that is now almost beyond any single individual's capacity for encompassing in his reading and research activities. Thus, it seemed timely to prepare a book giving in some detail a comprehen sive review of the field. Ideally, such a book would be written by one or possibly two authors. Unfortunately, the sheer bulk and variety of the studies of ion-molecule reactions has made it impractical for a single person to prepare a book on the subject in a time that would permit it to be issued before the material covered was obsolete. Consequently, the only practical, although surely not the ideal, solution is to issue a multiauthor volume. The present book represents our best efforts to accomplish this goal. We have secured from 18 authors material representing the most advanced work in the field and the resulting compilation is presented herein.

Publications

Publications PDF Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 362

Book Description


Publications of the National Bureau of Standards, 1973 Catalog

Publications of the National Bureau of Standards, 1973 Catalog PDF Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 360

Book Description


Gas Phase Ion Chemistry

Gas Phase Ion Chemistry PDF Author: Michael T. Bowers
Publisher: Academic Press
ISBN: 1483216489
Category : Science
Languages : en
Pages : 369

Book Description
Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well as the rapidity of ion-molecule reactions are also encompassed. Chemists, physicists, and people working in aeronomy laboratory and involved in space research will find the book invaluable.

Catalog of National Bureau of Standards Publications, 1966-1976

Catalog of National Bureau of Standards Publications, 1966-1976 PDF Author: United States. National Bureau of Standards. Technical Information and Publications Division
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 854

Book Description


Catalog of National Bureau of Standards Publications, 1966-1976: pt. 1-2. Key word index

Catalog of National Bureau of Standards Publications, 1966-1976: pt. 1-2. Key word index PDF Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 844

Book Description


Catalog of National Bureau of Standards Publications, 1966-1976

Catalog of National Bureau of Standards Publications, 1966-1976 PDF Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 844

Book Description


AFOSR Chemical & Atmospheric Sciences Program Review

AFOSR Chemical & Atmospheric Sciences Program Review PDF Author: United States. Air Force. Directorate of Chemical and Atmospheric Sciences
Publisher:
ISBN:
Category : Atmospheric chemistry
Languages : en
Pages : 136

Book Description