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Author: Roman Makitra Publisher: CRC Press ISBN: 9067644064 Category : Science Languages : en Pages : 333
Book Description
The behavior of substances in solutions may not be adequately characterized by the effect of any single physicochemical parameter of solvents, nor are numerous semi-empirical scales of the solvent effect (their ‘polarity’) suitable for their limited selections only. In recent decades, it has been found that the variation of reaction rate constants in solutions or that spectral parameters of dissolved substances are determined by the total effect of different solvation processes. This monograph presents numerous examples of such an approach and characterizes various empirical and semi-empirical scales of solvent properties. It is shown that additional consideration of some structural parameters of solvents, namely, their cohesive energy and the molar volume, may provide for spreading this approach on homolytical and catalytic reaction. It is also shown that for the solvolysis reaction, one of the excessive reagents may represent either a reagent or a solvent, which requires additional consideration of its structural characteristics in the Hammeth equation. The application of the principle of free energy linearity also allowed adequate generalization of data on the effect of solvents on different physicochemical processes, such as dissolution of gases and solids in various solvents, swelling of polymers and solid fossil fuels, coal extraction, adsorption, absorption, diffusion, and chromatography. Special attention is paid to substance distribution between two immiscible phases. Properties of both an extractive phase and an active extractant dissolved in inert diluter are taken into account. The majority of these processes indicate the efficiency of solvent self-association factor that defines the energy consumption for formation of a void for an alien molecule injection.
Author: Roman Makitra Publisher: CRC Press ISBN: 9047413245 Category : Science Languages : en Pages : 333
Book Description
The behavior of substances in solutions may not be adequately characterized by the effect of any single physicochemical parameter of solvents, nor are numerous semi-empirical scales of the solvent effect (their a polaritya ) suitable for their limited selections only. In recent decades, it has been found that the variation of reaction rate consta
Author: N. Chapman Publisher: Springer Science & Business Media ISBN: 1461588316 Category : Science Languages : en Pages : 557
Book Description
This book, Correlation Analysis in Chemistry: Recent Advances, is a sequel to our Advances in Linear Free Energy Relationships. t The change in the title is designed to reflect more accurately the nature of the field and the contents of the volume. The term LFER is still widely used, but it is often applied rather loosely to correlation equations that are not LFER in the restricted sense of a relationship involving logarithms of rate or equili brium constants on each side of the equation. The term "correlation analysis" seems to us more appropriate for the whole subject. The use of this term has compelled us also to introduce "chemistry" into the title; we have preferred not to prefix this with "organic" on the grounds that several areas of interest are not "organic chemistry" as usually understood, al though, of course, traditional applications of the basic relationships asso ciated with the names of Hammett and of Taft continue to be of interest. In the first volume we sought through our authors to provide a series of general articles covering the various aspects of the field as they seemed to us. Since the book was the first international research monograph in its field, each chapter, while giving prominence to recent developments, did not neglect earlier work, so that each article presented a comprehensive account of its own area.
Author: Donald Mackay Publisher: CRC Press ISBN: 9781566700351 Category : Science Languages : en Pages : 1008
Book Description
Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals is a comprehensive series that focuses on environmental fate prediction and quantitative structure activity relationship analysis.
Author: Robert W. Taft Publisher: John Wiley & Sons ISBN: 0470172177 Category : Science Languages : en Pages : 330
Book Description
Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Progress in Physical Organic Chemistry are not only of interest to scientists working in physical organic chemistry, but also scientists working in the many subdisciplines of chemistry in which physical organic chemistry approaches are now applied, such as biochemistry, pharmaceutical chemistry, and materials and polymer science. Among the topics explored in this series are reaction mechanisms; reactive intermediates; combinatorial strategies; novel structures; spectroscopy; chemistry at interfaces; stereochemistry; conformational analysis; quantum chemical studies; structure-reactivity relationships; solvent, isotope and solid-state effects; long-lived charged, sextet or open-shell species; magnetic, non-linear optical and conducting molecules; and molecular recognition.
Author: Joseph R. Lakowicz Publisher: Springer Science & Business Media ISBN: 0306470578 Category : Science Languages : en Pages : 462
Book Description
In this inaugural volume of a new series, experts in the field help biochemists, analytical chemists, spectroscopists, biophysicists, and other specialists keep up with the latest techniques and technologies available in fluorescence spectroscopy.
Author: Donald Mackay Publisher: CRC Press ISBN: 1420044397 Category : Science Languages : en Pages : 4196
Book Description
CHOICE Award WinnerTransport and transformation processes are key for determining how humans and other organisms are exposed to chemicals. These processes are largely controlled by the chemicals' physical-chemical properties. This new edition of the Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals is a comprehen
Author: Christian Reichardt Publisher: John Wiley & Sons ISBN: 3527642137 Category : Science Languages : en Pages : 722
Book Description
Now in its 4th edition, this book remains the ultimate reference for all questions regarding solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no other book which covers the subject in so much depth, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids". An essential part of every organic chemist's library.
Author: David Harvey Publisher: McGraw-Hill Science, Engineering & Mathematics ISBN: 9780072375473 Category : Analytical chemistry Languages : en Pages : 0
Book Description
This introductory text covers both traditional and contemporary topics relevant to analytical chemistry. Its flexible approach allows instructors to choose their favourite topics of discussion from additional coverage of subjects such as sampling, kinetic method, and quality assurance.
Author: Roman Makitra
Author: Roman Makitra
Author: N. Chapman
Author: Australian National University Medical School
Author: Donald Mackay
Author: Robert W. Taft
Author: Joseph R. Lakowicz
Author: Donald Mackay
Author: Water Resources Scientific Information Center
Author: Christian Reichardt
Author: David Harvey