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Chemical Thermodynamics of Neptunium and Plutonium

Chemical Thermodynamics of Neptunium and Plutonium PDF Author: Robert J. Lemire
Publisher: Elsevier
ISBN: 9780444503794
Category : Medical
Languages : en
Pages : 876

Book Description
Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.

Chemical Thermodynamics of Neptunium and Plutonium

Chemical Thermodynamics of Neptunium and Plutonium PDF Author: Robert J. Lemire
Publisher: Elsevier
ISBN: 9780444503794
Category : Medical
Languages : en
Pages : 876

Book Description
Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.

Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium

Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium PDF Author: R. Guillaumont
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 976

Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency, and updates and expands the thermodynamic data on inorganic compounds and complexes of uranium, neptunium, plutonium, americium and technetium contained in the previous volumes of the series. A review team, composed of seven internationally recognized experts, has critically reviewed during five years all the scientific literature containing chemical thermodynamic information for the above mentioned systems that has appeared since the publication of the earlier volumes. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains new tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.

Chemical Thermodynamics of Technetium

Chemical Thermodynamics of Technetium PDF Author: J.A. Rard
Publisher: North Holland
ISBN:
Category : Science
Languages : en
Pages : 578

Book Description
This volume in the series Chemical Thermodynamics provides a comprehensive review and critical evaluation of experimental data available for the chemical thermodynamics of inorganic compounds and aqueous species and complexes of technetium. The objective of the reviews in the series Chemical Thermodynamics is to provide a set of reliable thermodynamic data that can be used to describe the behaviour of the elements reviewed under conditions relevant for radioactive waste disposal systems and various geochemical environments. Data and their uncertainty limits are recommended for the formation energies, enthalpies and entropies of selected aqueous complexes, solids and gaseous compounds containing technetium. The data are internally consistent and compatible with the CODATA Key Values, as well as with the data in the earlier volumes in the series Chemical Thermodynamics. The book contains a detailed discussion of the selection procedures used

Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands

Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands PDF Author:
Publisher: Elsevier
ISBN: 0080457525
Category : Science
Languages : en
Pages : 1133

Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for compounds of complexes of oxalate, citrate, EDTA and iso-saccharinate with uranium, neptunium, plutonium, americium, technetium, selenium, nickel and zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.Contributed by: Wolfgang Hummel (Chairman), Paul Scherrer Institute, Switzerland, Giorgio Anderegg, Swiss Federal Institute of Technology (ETH), Switzerland, Linfeng Rao, Lawrence Berkeley National Laboratory, U.S.A., Ignasi Puigdomènech, Swedish Nuclear Fuel and Waste Management Co. (SKB), Sweden, and Osamu Tochiyama, Tohoku University, Japan.* Critical review of all literature on chemical thermodynamics for compounds and complexes of oxalate, citrate, EDTA and iso-saccharinate with U, Np, Pu, Am, Tc and Se, Ni and Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.

Chemical Thermodynamics of Uranium

Chemical Thermodynamics of Uranium PDF Author: Ingmar Grenthe
Publisher: Elsevier Science & Technology
ISBN:
Category : Science
Languages : en
Pages : 744

Book Description
This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.

Chemical Thermodynamics of Selenium

Chemical Thermodynamics of Selenium PDF Author:
Publisher: Elsevier
ISBN: 0080457517
Category : Technology & Engineering
Languages : en
Pages : 896

Book Description
In order to quantitatively predict the chemical reactions that hazardous materials may undergo in the environment, it is necessary to know the relative stabilities of the compounds and complexes that may be found under certain conditions. This type of calculations may be done using consistent chemical thermodynamic data, such as those contained in this book for inorganic compounds and complexes of selenium.* Fully detailed authoritative critical review of literature.* Integrated into a comprehensive and consistent database for waste management applications.* CD ROM version.

Chemical Thermodynamics of Americium

Chemical Thermodynamics of Americium PDF Author: R.J. Silva
Publisher: Newnes
ISBN: 0444599355
Category : Science
Languages : en
Pages : 393

Book Description
This is the second volume in a series of critical reviews of the chemical thermodynamic data of those elements of particular importance in the safety assessment modeling of high-level radioactive waste storage and disposal facilities. The objective of these reviews is to provide a set of reliable thermodynamic data that can be used to describe the behaviour of these elements under conditions relevant for radioactive waste disposal systems and the geochemical environments. The present volume is a review of experimental data reported in the literature for americium. On a few occasions, where no data existed, comparisons and estimates were made based on experimental data on analog lanthanide elements. The basic philosophy was to develop a minimum set of solid phases and solution species of americium that would fit all experimental data being reviewed.

Chemical Thermodynamics of Nickel

Chemical Thermodynamics of Nickel PDF Author:
Publisher: Elsevier
ISBN: 0080457541
Category : Science
Languages : en
Pages : 648

Book Description
In order to quantitatively predict the chemical reactions that hazardous materials may undergo in the environment, it is necessary to know the relative stabilities of the compounds and complexes that may be found under certain conditions. This type of calculations may be done using consistent chemical thermodynamic data, such as those contained in this book for inorganic compounds and complexes of nickel.* Fully detailed authoritative critical review of literature.* Integrated into a comprehensive and consistent database for waste management applications.* CD ROM version.

Chemical Thermodynamics of Zirconium

Chemical Thermodynamics of Zirconium PDF Author:
Publisher: Elsevier
ISBN: 0080457533
Category : Science
Languages : en
Pages : 545

Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.* Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.

The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)

The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) PDF Author: L.R. Morss
Publisher: Springer Science & Business Media
ISBN: 1402035985
Category : Science
Languages : en
Pages : 4059

Book Description
The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.