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Chemical Relaxation with Preferential Dissociation from Excited Vibrational Levels

Chemical Relaxation with Preferential Dissociation from Excited Vibrational Levels PDF Author: Paul V. Marrone
Publisher:
ISBN:
Category : Chemical reactions
Languages : en
Pages : 60

Book Description


Chemical Relaxation with Preferential Dissociation from Excited Vibrational Levels

Chemical Relaxation with Preferential Dissociation from Excited Vibrational Levels PDF Author: Paul V. Marrone
Publisher:
ISBN:
Category : Chemical reactions
Languages : en
Pages : 60

Book Description


Advances in Hypersonics

Advances in Hypersonics PDF Author: Bertin
Publisher: Springer Science & Business Media
ISBN: 1461203716
Category : Science
Languages : en
Pages : 280

Book Description
These three volumes entitled Advances in Hypersonics contain the Proceedings of the Second and Third Joint US/Europe Short Course in Hypersonics which took place in Colorado Springs and Aachen. The Second Course was organized at the US Air Force Academy, USA in January 1989 and the Third Course at Aachen, Germany in October 1990. The main idea of these Courses was to present to chemists, com puter scientists, engineers, experimentalists, mathematicians, and physicists state of the art lectures in scientific and technical dis ciplines including mathematical modeling, computational methods, and experimental measurements necessary to define the aerothermo dynamic environments for space vehicles such as the US Orbiter or the European Hermes flying at hypersonic speeds. The subjects can be grouped into the following areas: Phys ical environments, configuration requirements, propulsion systems (including airbreathing systems), experimental methods for external and internal flow, theoretical and numerical methods. Since hyper sonic flight requires highly integrated systems, the Short Courses not only aimed to give in-depth analysis of hypersonic research and technology but also tried to broaden the view of attendees to give them the ability to understand the complex problem of hypersonic flight. Most of the participants in the Short Courses prepared a docu ment based on their presentation for reproduction in the three vol umes. Some authors spent considerable time and energy going well beyond their oral presentation to provide a quality assessment of the state of the art in their area of expertise as of 1989 and 1991.

The Effect of Dissociation on the Rate of Vibrational Relaxation

The Effect of Dissociation on the Rate of Vibrational Relaxation PDF Author: Charles E. Treanor
Publisher:
ISBN:
Category : Dissociation
Languages : en
Pages : 46

Book Description


NASA Technical Note

NASA Technical Note PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 470

Book Description


Two Different Interpretations of Measured Dissociation-rate Constants and Their Effects on Coupled Vibrational-dissociational Flows of Oxygen Over a Wedge

Two Different Interpretations of Measured Dissociation-rate Constants and Their Effects on Coupled Vibrational-dissociational Flows of Oxygen Over a Wedge PDF Author: Fred R. DeJarnette
Publisher:
ISBN:
Category : Coupling constants
Languages : en
Pages : 34

Book Description


Effects of Two Vibration-dissociation Coupling Models on Nonequilibrium Hypersonic Flow of Nitrogen Over a Wedge

Effects of Two Vibration-dissociation Coupling Models on Nonequilibrium Hypersonic Flow of Nitrogen Over a Wedge PDF Author: Fred R. DeJarnette
Publisher:
ISBN:
Category : Nonequilibrium thermodynamics
Languages : en
Pages : 36

Book Description


Chemical Kinetics

Chemical Kinetics PDF Author: Vivek Patel
Publisher: BoD – Books on Demand
ISBN: 9535101323
Category : Science
Languages : en
Pages : 358

Book Description
Chemical Kinetics relates to the rates of chemical reactions and factors such as concentration and temperature, which affects the rates of chemical reactions. Such studies are important in providing essential evidence as to the mechanisms of chemical processes. The book is designed to help the reader, particularly students and researchers of physical science, understand the chemical kinetics mechanics and chemical reactions. The selection of topics addressed and the examples, tables and graphs used to illustrate them are governed, to a large extent, by the fact that this book is aimed primarily at physical science (mainly chemistry) technologists. Undoubtedly, this book contains "must read" materials for students, engineers, and researchers working in the chemistry and chemical kinetics area. This book provides valuable insight into the mechanisms and chemical reactions. It is written in concise, self-explanatory and informative manner by a world class scientists in the field.

A Thin-shock-layer Solution for Nonequilibrium, Inviscid Hypersonic Flows in Earth, Martian, and Venusian Atmospheres

A Thin-shock-layer Solution for Nonequilibrium, Inviscid Hypersonic Flows in Earth, Martian, and Venusian Atmospheres PDF Author: William L. Gose
Publisher:
ISBN:
Category : Inviscid flow
Languages : en
Pages : 164

Book Description
An approximate inverse solution is presented for the nonequilibrium flow in the inviscid shock layer about a vehicle in hypersonic flight. The method is based upon a thin-shock-layer approximation and has the advantage of being applicable to both subsonic and supersonic regions of the shock layer. The relative simplicity of the method makes it ideally suited for programming on a digital computer with a significant reduction in storage capacity and computing time required by other more exact methods. Comparison of nonequilibrium solutions for an air mixture obtained by the present method is made with solutions obtained by two other methods. Additional cases are presented for entry of spherical nose cones into representative Venusian and Martian atmospheres. A digital computer program written in FORTRAN language is presented that permits an arbitrary gas mixture to be employed in the solution. The effects of vibration, dissociation, recombination, electronic excitation, and ionization are included in the program.

A Simplified Molecular Model for Studying Vibration-dissociation Coupling in Fluid Flows

A Simplified Molecular Model for Studying Vibration-dissociation Coupling in Fluid Flows PDF Author: Walter Albert Reinhardt
Publisher:
ISBN:
Category : Dissociation
Languages : en
Pages : 340

Book Description
A simplified mathematical model is derived that is useful for studying the effects of vibration-dissociation coupling in fluid flows. The derivation is based on energy-moment procedure for simplifying the master equations. To obtain the model equations it is assumed that the vibrational energy can be approximated by the introduction of two vibrational temperatures. The effects of molecular anharmonicity are also accounted for in an approximate manner. The parameters contained within the equations are evaluated by making comparisons with experimental data. It is shown that the model contains the minimum required structure allowing favorable agreement with existing experimental data. Numerical solutions are given for the quasi-steady zone behind a normal shock wave, for the complete structure of a shock wave, and for nozzle flow. The results provide the appropriate pre-exponential temperature dependence of the effective dissociation rate, yield and induction time before dissociation is observed, and, in the case of expanding flow, yield one-fourth less effective relaxation time than the Landau-Teller theory. The thermodynamic quantities for the vibrational mode (partition function, internal energy, and specific heat) agree accurately with like quantities evaluated from spectroscopic data. By the introduction of appropriate assumptions it is shown that the equations reduce to a form identical to the Marrone-Treanor model except for a "truncation factor". When the vibrational temperatures are not large, the model is identical to that of Landau and Teller. The numerical procedure used to integrate the system of rate and flow equations is also described.

New Results in Numerical and Experimental Fluid Mechanics XIV

New Results in Numerical and Experimental Fluid Mechanics XIV PDF Author: Andreas Dillmann
Publisher: Springer Nature
ISBN: 3031404823
Category : Technology & Engineering
Languages : en
Pages : 700

Book Description
This book offers timely insights into research on numerical and experimental fluid mechanics and aerodynamics, mainly for (but not limited to) aerospace applications. It reports on findings by members of the Deutsche Strömungsmechanische Arbeitsgemeinschaft, STAB (German Aerodynamics/Fluid Mechanics Association) and the Deutsche Gesellschaft für Luft- und Raumfahrt - Lilienthal Oberth e.V., DGLR (German Society for Aeronautics and Astronautics) and covers both nationally and EC-funded projects. Continuing on the tradition of the previous volumes, the book highlights innovative solutions, promoting translation from fundamental research to industrial applications. It addresses academics and professionals in the field of aeronautics, astronautics, ground transportation, and energy alike.