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Author: Florence Bart Publisher: Springer Science & Business Media ISBN: 1461434459 Category : Technology & Engineering Languages : en Pages : 266
Book Description
As the re-emergence of nuclear power as an acceptable energy source on an international basis continues, the need for safe and reliable ways to dispose of radioactive waste becomes ever more critical. The ultimate goal for designing a predisposal waste-management system depends on producing waste containers suitable for storage, transportation and permanent disposal. Cement-Based Materials for Nuclear-Waste Storage provides a roadmap for the use of cementation as an applied technique for the treatment of low- and intermediate-level radioactive wastes. Coverage includes, but is not limited to, a comparison of cementation with other solidification techniques, advantages of calcium-silicate cements over other materials and a discussion of the long-term suitability and safety of waste packages as well as cement barriers.
Author: Florence Bart Publisher: Springer Science & Business Media ISBN: 1461434459 Category : Technology & Engineering Languages : en Pages : 266
Book Description
As the re-emergence of nuclear power as an acceptable energy source on an international basis continues, the need for safe and reliable ways to dispose of radioactive waste becomes ever more critical. The ultimate goal for designing a predisposal waste-management system depends on producing waste containers suitable for storage, transportation and permanent disposal. Cement-Based Materials for Nuclear-Waste Storage provides a roadmap for the use of cementation as an applied technique for the treatment of low- and intermediate-level radioactive wastes. Coverage includes, but is not limited to, a comparison of cementation with other solidification techniques, advantages of calcium-silicate cements over other materials and a discussion of the long-term suitability and safety of waste packages as well as cement barriers.
Author: Rehab O. Abdel Rahman Publisher: John Wiley & Sons ISBN: 1118512006 Category : Science Languages : en Pages : 245
Book Description
Cementitious materials are an essential part in any radioactive waste disposal facility. Conditioning processes such as cementation are used to convert waste into a stable solid form that is insoluble and will prevent dispersion to the surrounding environment. It is incredibly important to understand the long-term behavior of these materials. This book summarises approaches and current practices in use of cementitious materials for nuclear waste immobilisation. It gives a unique description of the most important aspects of cements as nuclear waste forms: starting with a description of wastes, analyzing the cementitious systems used for immobilization and describing the technologies used, and ending with analysis of cementitious waste forms and their long term behavior in an envisaged disposal environment. Extensive research has been devoted to study the feasibility of using cement or cement based materials in immobilizing and solidifying different radioactive wastes. However, these research results are scattered. This work provides the reader with both the science and technology of the immobilization process, and the cementitious materials used to immobilize nuclear waste. It summarizes current knowledge in the field, and highlights important areas that need more investigation. The chapters include: Introduction, Portland cement, Alternative cements, Cement characterization and testing, Radioactive waste cementation, Waste cementation technology, Cementitious wasteform durability and performance assessment.
Author: Publisher: ISBN: Category : Languages : en Pages : 66
Book Description
This report contains the findings of a literature review on the use of cement-based materials in the disposal of low- and medium-level radioactive waste. The desirable performance characteristics of these materials are outlined. The effect of various mix components on the mechanical, hydraulic, chemical, thermal and emplacement properties is discussed. Information on cement-based materials both from within Ontario Hydro and from external sources has been reviewed. A small number of basic mix components are recommended for study in the development of a grout for low- medium-level radioactive waste storage.
Author: K.L. Scrivener Publisher: CRC Press ISBN: 1482294958 Category : Architecture Languages : en Pages : 470
Book Description
Deterioration of cement-based materials is a continuing problem, as it results in the substantial shortening of the lives of conventional concrete structures. The main costs result from poor performance and the need for early repair. With more advanced applications, where very long service lives are essential, such as the storage of nuclear waste,
Author: Valérie L'Hostis Publisher: Springer ISBN: 9402409041 Category : Technology & Engineering Languages : en Pages : 95
Book Description
The main outcomes of RILEM TC-226-CNM are summarized in this book. Key input was provided by researchers from countries that are main contributors in the R&D, design, construction, operation, and regulation of waste nuclear reinforced concrete facilities. Nuclear power plants and many of the facilities and structures used for the management of radioactive waste materials generated by the fuel cycle use concrete in their construction. RILEM TC 226 CNM covered several areas including functional and performance requirements for concrete structures; degradation processes; phenomenological modelling, field experiences, tests approaches, instrumentation and monitoring methods dedicated to performance assessments; service-life models; aging Management of Nuclear Power Plants, repair techniques; codes and standards specific to radioactive waste facilities.
Author: Rehab O. Abdel Rahman Publisher: Woodhead Publishing ISBN: 0128183292 Category : Technology & Engineering Languages : en Pages : 676
Book Description
Sustainability of Life Cycle Management for Nuclear Cementation-Based Technologies, edited by Dr. Rahman and Dr. Ojovan, presents the latest knowledge and research on the management of cementitious systems within nuclear power plants. The book covers aging, development and updates on regulatory frameworks on a global scale, the development of cementitious systems for the immobilization of problematic wastes, and the decommissioning and decontamination of complex cementitious systems. The book's editors and their team of experts combine their practical knowledge to provide the reader with a thorough understanding on the sustainability of lifecycle management of cementitious systems within the nuclear industry. Sections provide a comparative tool that presents national regulations concerning cementitious systems within nuclear power plants, check international and national evaluation results of the sustainability of different systems, help in the development of performance test procedures, and provide a guide on aging nuclear power plants and the long-term behavior of these systems in active and passive safety environments. Presents the latest information on the behavior of different cementitious systems used in the nuclear industry in one comprehensive resource Includes scientific justifications of system behavior during the design, operation, maintenance and decommissioning phases Aids the reader in the development of evaluation tests for problematic wastes
Author: Michael I. Ojovan Publisher: Elsevier ISBN: 0080455719 Category : Technology & Engineering Languages : en Pages : 334
Book Description
Safety and environmental impact is of uppermost concern when dealing with the movement and storage of nuclear waste. The 20 chapters in 'An Introduction to Nuclear Waste Immobilisation' cover all important aspects of immobilisation, from nuclear decay, to regulations, to new technologies and methods. Significant focus is given to the analysis of the various matrices used in transport: cement, bitumen and glass, with the greatest attention being given to glass. The last chapter concentrates on the performance assessment of each matrix, and on new developments of ceramics and glass composite materials, thermochemical methods and in-situ metal matrix immobilisation. The book thoroughly covers all issues surrounding nuclear waste: from where to locate nuclear waste in the environment, through nuclear waste generation and sources, treatment schemes and technologies, immobilisation technologies and waste forms, disposal and long term behaviour. Particular attention is paid to internationally approved and worldwide-applied approaches and technologies. * Each chapter focuses on a different matrix used in nuclear waste immobilisation: Cement, bitumen, glass and new materials. * Keeps the most important issues surrounding nuclear waste – such as treatment schemes and technologies, and disposal - at the forefront.
Author: Michael Ochs Publisher: Springer ISBN: 3319236512 Category : Technology & Engineering Languages : en Pages : 322
Book Description
Cementitious materials are being widely used as solidification/stabilisation and barrier materials for a variety of chemical and radioactive wastes, primarily due to their favourable retention properties for metals, radionuclides and other contaminants. The retention properties result from various mineral phases in hydrated cement that possess a high density and diversity of reactive sites for the fixation of contaminants through a variety of sorption and incorporation reactions. This book presents a state of the art review and critical evaluation of the type and magnitude of the various sorption and incorporation processes in hydrated cement systems for twenty-five elements relevant for a broad range of radioactive and industrial wastes. Effects of cement evolution or ageing on sorption/incorporation processes are explicitly evaluated and quantified. While the immobilisation of contaminants by mixing-in during hydration is not explicitly addressed, the underlying chemical processes are similar. A quantitative database on the solid/liquid distribution behaviour of radionuclides and other elements in hydrated cement systems is established on the basis of a consistent review and re-evaluation of literature data. In addition to recommended values, all underlying original experimental data and key experimental info rmation are provided, which allows users to trace the given recommendations or to develop their own set of key values. This database is closely tied to the safety analysis of near surface disposal of radioactive waste in Belgium. It focuses on radioelements, toxic stable elements and heavy metals, which makes it relevant for investigations involving the interaction of radioactive and conventional contaminants with cement-based barriers.
Author: Michael I Ojovan Publisher: Elsevier ISBN: 9780080993928 Category : Technology & Engineering Languages : en Pages : 0
Book Description
Drawing on the authors' extensive experience in the processing and disposal of waste, An Introduction to Nuclear Waste Immobilisation, Second Edition examines the gamut of nuclear waste issues from the natural level of radionuclides in the environment to geological disposal of waste-forms and their long-term behavior. It covers all-important aspects of processing and immobilization, including nuclear decay, regulations, new technologies and methods. Significant focus is given to the analysis of the various matrices used, especially cement and glass, with further discussion of other matrices such as bitumen. The final chapter concentrates on the performance assessment of immobilizing materials and safety of disposal, providing a full range of the resources needed to understand and correctly immobilize nuclear waste.
Author: J. Sun Publisher: ISBN: Category : Languages : en Pages :
Book Description
The use of cement based materials could be widespread in the long term management of radioactive materials in the United Kingdom. In the Geological Disposal Concepts proposed by the Radioactive Waste Management Directorate of the Nuclear Decommissioning Authority (NDA), several cement based materials are used in the long-term management of intermediate-level wastes. Much of the waste will be immobilised within stainless steel containers using cement grouts based on ordinary Portland cement (OPC) blended with blast furnace slag (BFS) or pulverised fuel ash (PFA). The resulting waste packages will be placed underground in a Geological Disposal Facility (or Repository) after a period of storage at the waste producers' sites. The repository will then be filled with cement based backfill. The encapsulation grouts and the backfill materials will perform as both a physical barrier and chemical barrier for confining the radioactive wastes. During storage and disposal, some wastes may generate carbon dioxide from the degradation of organic materials and this will react with the cement based materials. Therefore, carbonation of the cementitious encapsulation grouts and backfill materials is of interest because of the resulting changes to their physical and chemical properties and also because of its ability to remove carbon-14 labelled carbon dioxide from the gas phase. It is also important to understand the reaction kinetics under a range of conditions, due to the long-term nature of storage and disposal. In this work, the carbonation progress of one backfill material and of two encapsulation grouts used in the UK has been studied in batch reactors. These materials are known as Nirex Reference Vault Backfill (NRVB), 3:1 PFA/OPC and 3:1 BFS/OPC. Based on the single dimensional carbonation experiments, fundamental parameters affecting the rate of carbonation were investigated and the carbon dioxide uptake capacity of each material was determined. For these three materials, an increase in relative humidity (75% to 100%) decreases the carbonation rate. A higher reaction pressure can facilitate the carbonation, but its effect was less obvious than the effect of relative humidity. The progression of the carbonation fronts have also been observed by various techniques and the shape of carbonation front was proved to be influenced by the relative humidity. Special attention was given to the modelling of the kinetics and mechanism of the carbonation reaction of these materials. This work provides fundamental understanding of the carbonation reaction of NRVB, 3:1 PFA/OPC and 3:1 BFS/OPC of relevance to the future optimization of a geological disposal facility in the UK and to assessments of the performance of such a facility.