Cavity Ringdown Spectroscopy in Nitrogen/oxygen Mixtures in the Presence of Alpha Radiation PDF Download

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Cavity Ringdown Spectroscopy in Nitrogen/oxygen Mixtures in the Presence of Alpha Radiation

Cavity Ringdown Spectroscopy in Nitrogen/oxygen Mixtures in the Presence of Alpha Radiation PDF Author: Sidney John Gautrau
Publisher:
ISBN:
Category : Cavity-ringdown spectroscopy
Languages : en
Pages : 115

Book Description
This research was part of an effort to experimentally validate computational models under development for radiation-induced atmospheric effects. Cavity Ringdown Spectroscopy (CRDS) was used to measure the concentration of chemical products generated as a result of radiation interactions in a controlled atmosphere. Experiments were conducted in a vacuum chamber interfaced with a gas introduction system that controlled the initial atmospheric composition. A quadrupole mass spectrometer and tunable dye laser were integrated to confirm initial atmospheric composition, and provide wavelength flexibility for detecting a variety of chemical products generated by radiation interactions. CRDS measurements were made for ozone production resulting from alpha radiation interactions in nitrogen-oxygen mixtures while the Polonium 210 alpha sources were cycled between being shielded and exposed. The beginning of this thesis will provide brief reviews of ionizing radiation and ozone formation, along with explanations of Cavity Enhanced Absorption Spectroscopy and CRDS. This is followed by a description of the existing vacuum and optical system, as well as the modifications required to integrate the mass spectrometer and dye laser. Another chapter details the modifications made to the existing software, as well as new software developed for the mass spectrometer and dye laser. Finally, results are presented showing the rapid production of ozone following exposure of the alpha radiation to the controlled atmosphere. Results also show ozone concentrations rapidly decreasing when the source was re-shielded, but when the source was re-exposed, the ozone concentration started at the previous concentration and continued to increase. This indicates the presence of a possible ozone catalyst. --Page ii.

Cavity Ringdown Spectroscopy in Nitrogen/oxygen Mixtures in the Presence of Alpha Radiation

Cavity Ringdown Spectroscopy in Nitrogen/oxygen Mixtures in the Presence of Alpha Radiation PDF Author: Sidney John Gautrau
Publisher:
ISBN:
Category : Cavity-ringdown spectroscopy
Languages : en
Pages : 115

Book Description
This research was part of an effort to experimentally validate computational models under development for radiation-induced atmospheric effects. Cavity Ringdown Spectroscopy (CRDS) was used to measure the concentration of chemical products generated as a result of radiation interactions in a controlled atmosphere. Experiments were conducted in a vacuum chamber interfaced with a gas introduction system that controlled the initial atmospheric composition. A quadrupole mass spectrometer and tunable dye laser were integrated to confirm initial atmospheric composition, and provide wavelength flexibility for detecting a variety of chemical products generated by radiation interactions. CRDS measurements were made for ozone production resulting from alpha radiation interactions in nitrogen-oxygen mixtures while the Polonium 210 alpha sources were cycled between being shielded and exposed. The beginning of this thesis will provide brief reviews of ionizing radiation and ozone formation, along with explanations of Cavity Enhanced Absorption Spectroscopy and CRDS. This is followed by a description of the existing vacuum and optical system, as well as the modifications required to integrate the mass spectrometer and dye laser. Another chapter details the modifications made to the existing software, as well as new software developed for the mass spectrometer and dye laser. Finally, results are presented showing the rapid production of ozone following exposure of the alpha radiation to the controlled atmosphere. Results also show ozone concentrations rapidly decreasing when the source was re-shielded, but when the source was re-exposed, the ozone concentration started at the previous concentration and continued to increase. This indicates the presence of a possible ozone catalyst. --Page ii.

Quantities, Units and Symbols in Physical Chemistry

Quantities, Units and Symbols in Physical Chemistry PDF Author: International Union of Pure and Applied Chemistry. Physical and Biophysical Chemistry Division
Publisher: Royal Society of Chemistry
ISBN: 0854044337
Category : Reference
Languages : en
Pages : 240

Book Description
Prepared by the IUPAC Physical Chemistry Division this definitive manual, now in its third edition, is designed to improve the exchange of scientific information among the readers in different disciplines and across different nations. This book has been systematically brought up to date and new sections added to reflect the increasing volume of scientific literature and terminology and expressions being used. The Third Edition reflects the experience of the contributors with the previous editions and the comments and feedback have been integrated into this essential resource. This edition has been compiled in machine-readable form and will be available online.

Multiphase Environmental Chemistry in the Atmosphere

Multiphase Environmental Chemistry in the Atmosphere PDF Author: Sherri W. Hunt
Publisher: ACS Symposium
ISBN: 9780841233638
Category : Science
Languages : en
Pages : 0

Book Description
This book highlights new cross-disciplinary advances in aerosol chemistry that involve more than one phase, for example, unique chemical processes occurring on gas-solid and liquid-solid interfaces.

Strategy and Methodology for Radioactive Waste Characterization

Strategy and Methodology for Radioactive Waste Characterization PDF Author: International Atomic Energy Agency
Publisher: IAEA
ISBN:
Category : Business & Economics
Languages : en
Pages : 188

Book Description
Over the past decade significant progress has been achieved in the development of waste characterization and control procedures and equipment as a direct response to ever-increasing requirements for quality and reliability of information on waste characteristics. Failure in control procedures at any step can have important, adverse consequences and may result in producing waste packages which are not compliant with the waste acceptance criteria for disposal, thereby adversely impacting the repository. The information and guidance included in this publication corresponds to recent achievements and reflects the optimum approaches, thereby reducing the potential for error and enhancing the quality of the end product. -- Publisher's description.

Atmospheric Pressure Plasma

Atmospheric Pressure Plasma PDF Author: Anton Nikiforov
Publisher: BoD – Books on Demand
ISBN: 1838802495
Category : Science
Languages : en
Pages : 146

Book Description
Plasma as the fourth state of matter is an ionized gas consisting of both negative and positive ions, electrons, neutral atoms, radicals, and photons. In the last few decades, atmospheric-pressure plasmas have started to attract increasing attention from both scientists and industry due to a variety of potential applications. Because of increasing interest in the topic, the focus of this book is on providing engineers and scientists with a fundamental understanding of the physical and chemical properties of different atmospheric-pressure plasmas via plasma diagnostic techniques and their applications. The book has been organized into two parts. Part I focuses on the latest achievements in advanced diagnostics of different atmospheric-pressure plasmas. Part II deals with applications of different atmospheric-pressure plasmas.

International Aerospace Abstracts

International Aerospace Abstracts PDF Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 528

Book Description


A Brief Practical Guide to Eddy Covariance Flux Measurements

A Brief Practical Guide to Eddy Covariance Flux Measurements PDF Author: George Burba
Publisher: LI-COR Biosciences
ISBN: 0615430139
Category : Science
Languages : en
Pages : 214

Book Description
This book was written to familiarize beginners with general theoretical principles, requirements, applications, and processing steps of the Eddy Covariance method. It is intended to assist in further understanding the method, and provides references such as textbooks, network guidelines and journal papers. It is also intended to help students and researchers in field deployment of instruments used with the Eddy Covariance method, and to promote its use beyond micrometeorology.

Isotopes in the Water Cycle

Isotopes in the Water Cycle PDF Author: Pradeep K. Aggarwal
Publisher: Springer Science & Business Media
ISBN: 1402030231
Category : Technology & Engineering
Languages : en
Pages : 377

Book Description
Environmental isotope and nuclear techniques provide unmatched insights into the processes governing the water cycle and its variability. This monograph presents state of the art applications and new developments of isotopes in hydrology, environmental disciplines and climate change studies. Coverage ranges from the assessment of groundwater resources in terms of recharge and flow regime to studies of the past and present global environmental and climate changes.

Mars Science Laboratory

Mars Science Laboratory PDF Author: John Grotzinger
Publisher: Springer
ISBN: 9781461463382
Category : Science
Languages : en
Pages : 0

Book Description
The Mars Science Laboratory is the latest and most advanced NASA roving vehicle to explore the surface of Mars. The Curiosity rover has landed in Gale crater and will explore this region assessing conditions on the surface that might be hospitable to life and paving the way for later even more sophisticated exploration of the surface. This book describes the mission, its exploration and scientific objectives, studies leading to the design of the mission and the instruments that accomplish the objectives of the mission. This book is aimed at all those engaged in Martian studies as well as those interested in the origin of life in other environments. It will be a valuable reference for anyone who uses data from the Mars Science Laboratory. Previously published in Space Science Reviews journal, Vol. 170/1-4, 2012.

Air Quality in the Mexico Megacity

Air Quality in the Mexico Megacity PDF Author: L. Molina
Publisher: Springer Science & Business Media
ISBN: 9401004544
Category : Science
Languages : en
Pages : 401

Book Description
In this book, experts in atmospheric sciences, human health, economics, social and political sciences contribute to an integrated assessment of the complex elements needed to structure air quality policy in the 21st century. The analysis is developed through a case study of the Mexico City Metropolitan Area - one of the world's largest megacities in which air pollution grew unchecked for decades. The international research team is led by Luisa T. and Mario J. Molina, Nobel Laureate in Chemistry. Improvements in Mexico City's air quality in the last decade testifies to the power of determined and enlightened policy making, and throws into relief the tough problems that remain to be solved. The volume's first six chapters, including the contributions of over 50 distinguished scholars from Mexico and the US, outline the fundamental areas of knowledge policy makers must accommodate. The message is that only good science and well-chosen technologies can direct the way to corrective regulatory measures; but without strong commitment from government, no amount of science or technology can help.