Biomass Recalcitrance PDF Download

Author: Michael Himmel
Publisher: Wiley-Blackwell
ISBN:
Category : Science
Languages : en
Pages : 552

View

Book Description
This book examines the connection between biomass structure, ultrastructure, and composition, to resistance to enzymatic deconstruction, with the aim of discovering new cost-effective technologies for biorefineries. It contains chapters on topics extending from the highest levels of biorefinery design and biomass life-cycle analysis, to detailed aspects of plant cell wall structure, chemical treatments, enzymatic hydrolysis, and product fermentation options."--Pub. desc.

Author: Arthur J. Ragauskas
Publisher: Frontiers Media SA
ISBN: 2889457060
Category :
Languages : en
Pages : 103

View

Book Description
Lignocellulosic biomass has great potentials as an alternative feedstock for fuels and chemicals. For effective utilization of biomass, biomass recalcitrance, which is inherent resistance of plant cell walls to biological deconstruction, needs to be reduced. Among many factors in biomass, lignin is significantly related to biomass recalcitrance. Lignin, a complex aromatic polymer, is the largest non-carbohydrate component (15-40% dry weight) in most terrestrial plants. In nature, it provides a structural integrity, facilitates water and nutrient transport, and protects plants from microbial attack. From a different angle, lignin significantly contributes to biomass recalcitrance, so it is necessary to reduce and/or modify the lignin for effective conversion of biomass. Genetic modifications of the lignin biosynthetic pathway and lignin-targeting pretreatments have been developed to minimize the lignin-induced biomass recalcitrance. High carbon content of lignin also renders it an attractive feedstock for many applications. About 100,000 to 200,000 tons of lignin can be generated per year as a byproduct from cellulosic ethanol production, so valorization of these lignins could be one of keys for achieving economic biorefinery. However, investigations of lignin conversion have not been accomplished as the utilization of carbohydrates in biomass. Depolymerization of lignin is still challenging because of its broad distribution of bond strengths, recondensation of low-molecular species, and poor product selectivity. Diverse biological and thermochemical depolymerization methods have been investigated to overcome these barriers. In this Research Topic, recent advancements in biomass recalcitrance by effective utilization of lignin are introduced.

Author: Charles E. Wyman
Publisher: John Wiley & Sons
ISBN: 0470972025
Category : Science
Languages : en
Pages : 597

View

Book Description
Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.

Author: Abu Yousuf
Publisher: Academic Press
ISBN: 0128162805
Category : Science
Languages : en
Pages : 360

View

Book Description
Lignocellulosic Biomass to Liquid Biofuels explores the existing technologies and most recent developments for the production of second generation liquid biofuels, providing an introduction to lignocellulosic biomass and the processes for its conversion into biofuels. The book demonstrates biorefinery concepts compared with petro refinery, as well as the challenges of second generation biofuels processing. In addition to current pre-treatment techniques and their technical, environmental and economic implications, chapters included also further examine the particularities of conversion processes for bioethanol, biobutanol and biodiesel through chemical, biochemical and combined approaches. Finally, the book looks into concepts and tools for techno-economic and environmental analysis, which include supply chain assessment, by-products, zero-waste techniques and process evaluation and optimization. Lignocellulosic Biomass to Liquid Biofuels is particularly useful for researchers in the field of liquid biofuels seeking alternative chemical and biochemical pathways or those interested advanced methods to calculate maximum yield for each process and methods to simulate the implications and costs of scaling up. Furthermore, with the introduction provided by this volume, researchers and graduate students entering the field will be able to quickly get up to speed and identify knowledge gaps in existing and upcoming technology the book's comprehensive overview. - Examines the state-of-the-art technology for liquid biofuels production from lignocellulosic biomass - Provides a comprehensive overview of the existing chemical and biochemical processes for second generation biofuel conversion - Presents tools for the techno-economic and environmental analysis of technologies, as well as for the scale-up simulation of conversion processes

Author: S.I. Mussatto
Publisher: Elsevier
ISBN: 0128025611
Category : Technology & Engineering
Languages : en
Pages : 676

View

Book Description
Biomass Fractionation Technologies for a Lignocellulosic Feedstock-based Biorefinery reviews the extensive research and tremendous scientific and technological developments that have occurred in the area of biorefinering, including industrial processes and product development using 'green technologies', often referred as white biotechnology. As there is a huge need for new design concepts for modern biorefineries as an alternative and amendment to industrial crude oil and gas refineries, this book presents the most important topics related to biomass fractionation, including advances, challenges, and perspectives, all with references to current literature for further study. Presented in 26 chapters by international field specialists, each chapter consists of review text that comprises the most recent advances, challenges, and perspectives for each fractionation technique. The book is an indispensable reference for all professionals, students, and workers involved in biomass biorefinery, assisting them in establishing efficient and economically viable process technologies for biomass fractionation. - Provides information on the most advanced and innovative pretreatment processes and technologies for biomass - Reviews numerous valuable products from lignocellulose - Discusses integration of processes for complete biomass conversion with minimum waste generation - Identifies the research gaps in scale-up - Presents an indispensable reference for all professionals, students, and workers involved in biomass biorefinery, assisting them in establishing efficient and economically viable process technologies for biomass fractionation

Author: Ashok Pandey
Publisher: Academic Press
ISBN: 0128003960
Category : Technology & Engineering
Languages : en
Pages : 273

View

Book Description
Pretreatment of Biomass provides general information, basic data, and knowledge on one of the most promising renewable energy sources—biomass for their pretreatment—which is one of the most essential and critical aspects of biomass-based processes development. The quest to make the environment greener, less polluted, and less hazardous has led to the concept of biorefineries for developing bio-based processes and products using biomass as a feedstock. Each kind of biomass requires some kind of pretreatment to make it suitable for bioprocess. This book provides state-of-art information on the methods currently available for this. This book provides data-based scientific information on the most advanced and innovative pretreatment of lignocellulosic and algal biomass for further processing. Pretreatment of biomass is considered one of the most expensive steps in the overall processing in a biomass-to-biofuel program. With the strong advancement in developing lignocellulose biomass- and algal biomass-based biorefineries, global focus has been on developing pretreatment methods and technologies that are technically and economically feasible. This book provides a comprehensive overview of the latest developments in methods used for the pretreatment of biomass. An entire section is devoted to the methods and technologies of algal biomass due to the increasing global attention of its use. - Provides information on the most advanced and innovative pretreatament processes and technologies for biomass - Covers information on lignocellulosic and algal biomass to work on the principles of biorefinery - Useful for researchers intending to study scale-up - Provides information on integration of processes and technologies for the pretreatment of biomass

Author: Marcos S. Buckeridge
Publisher: Springer
ISBN: 3319498266
Category : Science
Languages : en
Pages : 217

View

Book Description
This book focuses on the basic science recently produced in Brazil for the improvement of sugarcane as a bioenergy crop and as a raw material for 2nd generation bioethanol production. It reports achievements that have been advancing the science of cell walls, enzymes, genetics, and sustainability related to sugarcane technologies and give continuity to the research reported in the “Routes to Cellulosic Ethanol”, from Springer. The Introduction (Chapter I) explains how the National Institute of Science and Technology of Bioethanol, founded in 2008 in Brazil, became part of the main international initiatives that started to search for forms to use biomass for bioethanol production in Brazil, US and Europe. Part I reports the advances in plant cell wall composition, structure and architecture, and physical characteristics of sugarcane biomass. These discoveries are opening the way to increased efficiency of pretreatments and hydrolysis, being therefore important information for 2nd generation processes as well as for biorefinery initiatives. Part II focuses on the discovery and characterization of hydrolases from microorganisms that could be used in industrial processes. Recent advances in the search for hydrolases using metagenomics is reported. A great number of genes and enzymes from microorganisms have been discovered, affording improvement of enzyme cocktails better adapted to sugarcane biomass. Part III reports two key issues in the process of 2G ethanol, pentose fermentation and sugarcane genetics. These are the discoveries of new yeast species capable of producing ethanol more efficiently from xylose and the advances made on the sugarcane genetics, a key issue to design varieties adapted to 2G ethanol production. Part IV approaches sustainability through two chapters, one discussing the sustainability of the sugarcane agricultural and environmental system and another discussing how national and mainly international policies of Brazil regarding 2G ethanol production affected the country’s strategies to establish itself as an international player in renewable energy area.

Author: Ackmez Mudhoo
Publisher: John Wiley & Sons
ISBN: 1118404076
Category : Technology & Engineering
Languages : en
Pages : 352

View

Book Description
Biogas Production covers the most cutting-edge pretreatment processes being used and studied today for the production of biogas. As an increasingly important piece of the "energy pie," biogas and other biofuels are being used more and more around the world in every conceivable area of industry and could be a partial answer to the energy problem and the elimination of global warming. This book will highlight the recent advances in the pretreatment and value addition of lignocellulosic wastes (LCW) with the main focus on domestic and agro-industrial residues. Mechanical, physical, and biological treatment systems are brought into perspective. The main value-added products from lignocellulosic wastes are summarized in a manner that pinpoints the most recent trends and the future directions. Physico-chemical and biological treatment systems seem to be the most favored options while biofuels, biodegradable composites, and biosorbents production paint a bright picture of the current and future bio-based products. Engineered microbes seem to tackle the problem of bioconversion of substrates that are otherwise nonconvertible by conventional wild strains. Although the main challenge facing LCW utilization is the high costs involved in treatment and production processes, some recent affordable processes with promising results have been proposed. Future trends are being directed to nanobiotechnology and genetic engineering for improved processes and products.

Author: Robert Henry
Publisher: Frontiers Media SA
ISBN: 2889198677
Category : Biotechnology
Languages : en
Pages : 158

View

Book Description
The conversion of lignocellulosic biomass into renewable fuels and other commodities has provided an appealing alternative towards supplanting global dependence on fossil fuels. The suitability of multitudes of plants for deconstruction to useful precursor molecules and products is currently being evaluated. These studies have probed a variety of phenotypic traits, including cellulose, non-cellulosic polysaccharide, lignin, and lignin monomer composition, glucose and xylose production following enzymatic hydrolysis, and an assessment of lignin-carbohydrate and lignin-lignin linkages, to name a few. These quintessential traits can provide an assessment of biomass recalcitrance, enabling researchers to devise appropriate deconstruction strategies. Plants with high polysaccharide and lower lignin contents have been shown to breakdown to monomeric sugars more readily. Not all plants contain ideal proportions of the various cell wall constituents, however. The capabilities of biotechnology can alleviate this conundrum by tailoring the chemical composition of plants to be more favorable for conversion to sugars, fuels, etc. Increases in the total biomass yield, cellulose content, or conversion efficiency through, for example, a reduction in lignin content, are pathways being evaluated to genetically improve plants for use in manufacturing biofuels and bio-based chemicals. Although plants have been previously domesticated for food and fiber production, the collection of phenotypic traits prerequisite for biofuel production may necessitate new genetic breeding schemes. Given the plethora of potential plants available for exploration, rapid analytical methods are needed to more efficiently screen through the bulk of samples to hone in on which feedstocks contain the desired chemistry for subsequent conversion to valuable, renewable commodities. The standard methods for analyzing biomass and related intermediates and finished products are laborious, potentially toxic, and/or destructive. They may also necessitate a complex data analysis, significantly increasing the experimental time and add unwanted delays in process monitoring, where delays can incur in significant costs. Advances in thermochemical and spectroscopic techniques have enabled the screening of thousands of plants for different phenotypes, such as cell-wall cellulose, non-cellulosic polysaccharide, and lignin composition, lignin monomer composition, or monomeric sugar release. Some instrumental methods have been coupled with multivariate analysis, providing elegant chemometric predictive models enabling the accelerated identification of potential feedstocks. In addition to the use of high-throughput analytical methods for the characterization of feedstocks based on phenotypic metrics, rapid instrumental techniques have been developed for the real-time monitoring of diverse processes, such as the efficacy of a specific pretreatment strategy, or the formation of end products, such as biofuels and biomaterials. Real-time process monitoring techniques are needed for all stages of the feedstocks-to-biofuels conversion process in order to maximize efficiency and lower costs by monitoring and optimizing performance. These approaches allow researchers to adjust experimental conditions during, rather than at the conclusion, of a process, thereby decreasing overhead expenses. This Frontiers Research Topic explores options for the modification of biomass composition and the conversion of these feedstocks into to biofuels or biomaterials and the related innovations in methods for the analysis of the composition of plant biomass, and advances in assessing up- and downstream processes in real-time. Finally, a review of the computational models available for techno-economic modeling and lifecycle analysis will be presented.

Author: Michael E. Himmel
Publisher: Humana Press
ISBN: 9781617799556
Category : Science
Languages : en
Pages : 0

View

Book Description
Biomass conversion research is a combination of basic science, applied science, and engineering testing and analysis. Conversion science includes the initial treatment (called pre-treatment) of the feedstock to render it more amenable to enzyme action, enzymatic saccharification, and finally product formation by microbiological or chemical processes. In Biomass Conversion: Methods and Protocols, expert researchers in the field detail methods which are now commonly used to study biomass conversion. These methods include Biomass Feedstocks and Cellulose, Plant Cell Wall Degrading Enzymes and Microorganisms, and Lignins and Hemicelluloses. Written in the highly successful Methods in Molecular BiologyTM series format, the chapters include the kind of detailed description and implementation advice that is crucial for getting informed, reproducible results in the laboratory.