Assessing the Sustainability of Electrodialysis for Rare Earth Element Recovery from Phosphogypsum PDF Download

Author: Alexandra Brajovic
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
Electrodialysis (ED) has been sought as a method of rare earth element (REE) separation from phosphogypsum as a means to promote sustainable waste recovery and implement a circular economy. In order to handle large amounts of waste generated from mining activities, ED must be scaled up to industrial levels and evaluated as a continuous process of REE recovery, rather than as a batch or pilot-scale process, and evaluated for its environmental and financial impacts. A Life Cycle Analysis (LCA) was performed on ED using openLCA software, and the results were compared to an LCA performed on precipitation from oxalic acid. For financial impacts, a model was developed in Microsoft Excel with adjustable parameters to determine the capital and annual operating costs of an ED system that meets set production goals. Compared to precipitation from oxalic acid, ED has slightly higher global warming potential and fossil fuel consumption impacts but also displays significantly lower impacts for human and terrestrial toxicity. Financially, an ED system is economically viable; although multiple units running in parallel are required to meet production needs, the overall cost is dominated by capital costs, which scale with membrane size, which is driven by current applied to the unit. The initial investment will be made back after three years, and thus the ED system will be profitable over time.

Author: Arda Isildar
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
The well-being of the society depends on a number of metals, including base metals, precious metals and increasingly rare earth elements (REE). The usage of these metals increased in numerous applications, including electrical and electronic equipment (EEE), and their interrupted supply is at stake. There is an increasing interest in the secondary sources of these metals, particularly waste electrical and electronic equipment (WEEE) in order to compensate their potential supply deficit. This PhD thesis demonstrates the advantages and bottlenecks of biological and chemical approaches, as well as the advances and perspectives in the development of sustainable processes for metal recovery from WEEE. Furthermore, a novel process for the recovery of metals from WEEE is described, and a techno-economic assessment is given. Discarded printed circuit boards (PCB) from personal computers (PC), laptops, mobile phones and telecom servers were studied. Following an extensive literature review, a novel characterization and total metal assay method is introduced and applied to waste board materials. Discarded PCB contained metals in the range of (%, by weight): copper (Cu) 17.6 - 39.0, iron (Fe) 0.7 - 7.5, aluminum (Al) 1.0 - 5.5, nickel (Ni) 0.2 - 1.1, zinc (Zn) 0.3 - 1.2, as well as gold (Au) (in ppm) 21 - 320. In addition, multi-criteria analysis (MCA) using the analytical hierarchical process (AHP) methodology is applied for selection of the best-suited technology. A proof-of-concept for a two-step bioleaching extraction was given, in which 98.4% and 44.0% of the Cu and Au, respectively, were extracted. The two-step extraction concept was applied to the chemical leaching of metals from PCB. Cu leaching was carried in an acidic oxidative mixture of H2SO4 and H2O2, whereas Au leaching for carried out by S_2 O_3^(2-) in a NH_4^+ medium, catalyzed by CuSO4. Under the optimized parameters, 99.2% and 96.6% of Cu and Au, respectively, were extracted from the board material. Selective recovery of Cu from the bioleaching leachate using sulfidic precipitation and electrowinning was studied. Cu was selectively recovered on the cathode electrode at a 50 mA current density in 50 minutes, with a 97.8% efficiency and 65.0% purity. The techno-economic analysis and environmental sustainability assessment of the new technology at an early stage of development was investigated.

Author: Luigi Gurreri
Publisher: MDPI
ISBN: 3036515305
Category : Technology & Engineering
Languages : en
Pages : 236

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Book Description
Electromembrane processes offer a multitude of applications, allowing for the recovery of water, other products, and energy. This book is a collection of contributions on recent advancements in electromembrane processes attained via experiments and/or models. The first paper is a comprehensive review article on the applications of electrodialysis for wastewater treatment, highlighting current status, technical challenges, and key points for future perspectives. The second paper focuses on ZSM-5 zeolite/PVA mixed matrix CEMs with high monovalent permselectivity for recovering either acid or Li+. The third paper regards direct numerical simulations of electroconvection in an electrodialysis dilute channel with forced flow under potentiodynamic and galvanodynamic regimes. The fourth paper investigates the reasons for the formation and properties of soliton-like charge waves in overlimiting conditions. The fifth paper focuses on the characterization of AEMs functionalized by surface modification via poly(acrylic) acid yielding monovalent permselectivity for reverse electrodialysis. In the sixth paper, CFD simulations of reverse electrodialysis systems are performed. The seventh paper proposes an integrated membrane process, including electrochemical intercalation–deintercalation, for the preparation of Li2CO3 from brine with a high Mg2+/Li+ mass ratio. Finally, the eighth paper is a perspective article devoted to the acid–base flow battery with monopolar and bipolar membranes.

Author: Tatenda Dalu
Publisher: Elsevier
ISBN: 0323903150
Category : Science
Languages : en
Pages : 410

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Book Description
Emerging Freshwater Pollutants: Analysis, Fate and Regulations comprises of 20 chapters, all written by leading experts. This book is written in the most practical terms and is easy to understand, with numerous helpful examples and case studies and can be used as a practical guide and important educational tool on issues concerning freshwater emerging pollutants. The organisation of the book exposes the reader in logical succession to the full range of complex scientific and management aspects of emerging freshwater pollutants in the developing world. The book recognises that water chemistry, emerging freshwater pollutants and management are inter-dependent disciplines. The book covers (i) the different monitoring techniques, current analytical approaches and instrumental analyses, (ii) fate and occurrence of emerging pollutants in aquatic systems and (iii) management policies and legislations on emerging pollutants. Thus, subsequent chapters elucidate chemicals with pollution potential, multi-detection approaches to analysis of organic pollutants in water, microplastics effects and photochemical transformation of emerging pollutants in freshwater systems. Whereas, other chapters address oxidation of organic compounds in aquatic systems, biomonitoring systems for detection of toxic levels of water pollutants, and health aspects of water recycling practices. This book melds several different perspectives on the subject of freshwater emerging pollutants and shows the interrelationships between the various professions that deal with water quality issues. Further, within the presentation of each separate chapter is discussion of how the various scientific and management aspects of the subject interrelate. Includes case studies and practical examples in each chapter Presents a much-needed interdisciplinary approach, representing the overlap between water chemistry and emerging freshwater pollutants Provides a thorough introduction to emerging tropical and freshwater pollutants that typically occur in these systems

Author: Lawrence Smith
Publisher: DIANE Publishing
ISBN: 9780788116179
Category : Nature
Languages : en
Pages : 100

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Book Description
Provides assistance in identifying recycling technologies for a wide variety of contaminants and matrices, including: energy recovery; decanting; thermal desorption; solvent extraction; pumping and recovery; freeze-crystallization; thermolysis; ion exchange; reverse osmosis; diffusion dialysis; evaporation; amalgamation; cementation; electrowinning; vitrification; physical separation; mercury distillation, etc. Contents: description of recycling technologies; product quality specifications; 8 case studies. Extensive references. 50 charts and tables.

Author: Mostafa Benzaazoua
Publisher: MDPI
ISBN: 3039281720
Category : Science
Languages : en
Pages : 172

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Book Description
The extraction of apatite minerals is becoming more and more crucial with the depletion of high-grade ores. At the same time, many streams of waste are continuously being produced by the phosphate industry, including calcareous and siliceous waste rocks, clayey sludge and phosphogypsum. These waste products are produced in huge volumes reaching a ratio of between 5 to 10 tons of waste per each ton of concentrated phosphate. The management of these waste products is becoming a real issue in terms of growing public awareness and environmental and financial aspects. In addition, phosphate ores are known to contain other critical raw materials (CRM) such as rare earth elements and uranium. The recovery of these vital elements from phosphate waste may help to develop the needs of the green energy of the future and contribute to the achievement of the sustainable development goals. In this Special Issue, insights related to the following aspects were studied: phosphate extraction and beneficiation, novel phosphate ores, the fine characterization of phosphate ores and waste, phosphoric acid production, critical raw material (CRM) recovery from phosphate ores and waste, reprocessing of phosphate wastes and finally the valorization and reuse of phosphate waste and phosphogypsum.

Author: Antony van der Ent
Publisher: Springer Nature
ISBN: 3030589048
Category : Technology & Engineering
Languages : en
Pages : 482

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Book Description
This second and expanded edition of the first book on agromining (phytomining) presents a comprehensive overview of the metal farming & recovery of the agromining production chain. Agromining is an emerging technology that aims to transform the extraction of sources of target elements not accessible by traditional mining and processing techniques. Agromining, which is based on sustainable development, uses hyperaccumulator plants as 'metal crops' farmed on sub-economic soils or minerals wastes to obtain valuable target elements. This volume is edited and authored by the pioneers in the rapidly expanding field of agromining and presents the latest insights and developments in the field. This book provides in-depth information on the global distribution and ecology of hyperaccumulator plants, their biogeochemical pathways, the influence of rhizosphere microbes, the physiology and molecular biology of hyperaccumulation, as well as aspects of propagation and conservation of these unusual plants. It describes the agronomy of metal crops and opportunities for incorporating agromining into rehabilitation and mine closure, including test cases for agromining of nickel, cobalt, manganese, arsenic, selenium, cadmium, zinc, thallium, rare earth elements and platinum group elements. Since the first edition was published, there have successful nickel agromining field trials in the tropics (in Malaysia and Guatemala), and these are presented in a dedicated case study chapter. Other new chapters focus on the processing of bio-ore for elements other than nickel, such as rare earth elements and cadmium, and on agromining from industrial wastes such as tailings, and industrial by-products and sites. Furthermore, the book features two new chapters that provide a comprehensive assessment of accumulation a very wide range elements from the Periodic Table in various plant species around the globe, and a chapter on practical methods for discovery of hyperaccumulator plant species in the field and in the herbarium. This book is of interest to environmental professionals in the minerals industry, government regulators, and academics.

Author: Marc Humphries
Publisher: DIANE Publishing
ISBN: 1437937985
Category : Science
Languages : en
Pages : 18

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Book Description
Contents: (1) Intro.; (2) What are Rare Earth Elements (REE)?; (3) Major End Uses and Applications: Demand for REE; The Application of REE in National Defense; (4) Rare Earth Resources and Production Potential; Supply Chain Issues; Role of China; (5) Rare Earth Legislation in the 111th Congress: H.R. 4866, and S. 3521, the Rare Earths Supply-Chain Technology and Resources Transformation Act of 2010; H.R. 5136, the FY 2011 Nat. Defense Authorization Act; P.L. 111-84, the FY 2010 Nat. Defense Authorization Act; (6) Possible Policy Options: Authorize and Appropriate Funding for a USGS Assessment; Support and Encourage Greater Exploration for REE; Challenge China on Its Export Policy; Establish a Stockpile. Illustrations.

Author: Wim Salomons
Publisher: Springer Science & Business Media
ISBN: 3642793169
Category : Nature
Languages : en
Pages : 409

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Book Description
"Heavy Metals: Problems and Solutions" is divided into three sections dealing with basic geochemical processes, remediation and case studies. The basic geochemical processes are discussed with respect to mobility in the environment and impact as well as methods to derive guidelines for heavy metals. Remediation focuses on currently available methods to treat contaminated sediments and soils. In addition, it considers the concept of geochemical engineering for remediation of large areas contaminated by metals. A number of case studies of polluted sediments and soils and their environmental impact highlight the principles discussed in the first two sections.

Author: Gisele Azimi
Publisher: Springer Nature
ISBN: 3030367584
Category : Technology & Engineering
Languages : en
Pages : 379

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Book Description
This collection presents papers from a symposium on extraction of rare metals as well as rare extraction processing techniques used in metal production. Rare metals include strategic metals that are in increasing demand and subject to supply risks. Metals represented include neodymium, dysprosium, scandium and others; platinum group metals including platinum, palladium, iridium, and others; battery related metals including lithium, cobalt, nickel, and aluminum; electronics-related materials including copper and gold; and refectory metals including titanium, niobium, zirconium, and hafnium. Other critical materials such as gallium, germanium, indium and silicon are also included. Papers cover various processing techniques, including but not limited to hydrometallurgy (solvent extraction, ion exchange, precipitation, and crystallization), electrometallurgy (electrorefining and electrowinning), pyrometallurgy, and aeriometallurgy (supercritical fluid extraction). Contributions are focused on primary production as well as secondary production through urban mining and recycling to enable a circular economy. ​A useful resource for all involved in commodity metal production, irrespective of the major metal Provides knowledge of cross-application among industries Extraction and processing of rare metals that are the main building block of many emerging critical technologies have been receiving significant attention in recent years. The technologies that rely on critical metals are prominent worldwide, and finding a way to extract and supply them effectively is highly desirable and beneficial.