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Aerogels for Energy Storage Applications: from Shape Memory Materials to Thermites and Explosives

Aerogels for Energy Storage Applications: from Shape Memory Materials to Thermites and Explosives PDF Author: Suraj Donthula
Publisher:
ISBN:
Category :
Languages : en
Pages : 247

Book Description
"Aerogels are three dimensional highly porous solid objects that provide density reduction compared to dense objects. Those materials can have applications in different classes of energy storage and the two types that are focused in this dissertation are mechanical energy and thermal energy storage. Shape memory materials can store and recover elastic deformation energy when triggered by an external stimulus such as temperature. To incorporate those properties, shape memory polymeric aerogels (SMPA) were synthesized from a rigid isocyanurate containing triisocyanate (N3300 A) and four short oligomeric derivatives of ethylene glycol: H(OCH2CH2)[sub n]OH (1 d"n d"4). The shape memory effect (SME) of those aerogels were evaluated via four figures of merit namely strain fixity, strain recovery, strain recovery rate and fill factor. The morphologies of skeletal frameworks of those aerogels varied from micrometer sized particles with thick necks to bicontinuous structures, that are typical of spinodal decomposition. A Marcus-type thermodynamic-kinetic relationship was identified between that shape recovery rate, R[sub t](N), and the elastic modulus, E. Other part of the dissertation deals with the synthesis of nanoporous metallic iron (Fe(0)) aerogels via carbothermal reduction of interpenetrating networks of polybenzoxazine and iron oxide nanoparticles. Excess carbon was removed oxidatively at 600 °C under flowing air and the oxides of Fe(0) thus produced in the oxidative step were reduced back to Fe(0) with H2 at different temperatures ranging from 300 - 1300 °C. Those final monoliths were loaded with perchlorates and ignited with a flame in open air. Based on the temperature of the reduction step, monoliths either fizzled out (d"00 °C), exploded violently (500-900 °C), or behaved as thermites (e"50 °C)"--Abstract, page v.

Aerogels for Energy Storage Applications: from Shape Memory Materials to Thermites and Explosives

Aerogels for Energy Storage Applications: from Shape Memory Materials to Thermites and Explosives PDF Author: Suraj Donthula
Publisher:
ISBN:
Category :
Languages : en
Pages : 247

Book Description
"Aerogels are three dimensional highly porous solid objects that provide density reduction compared to dense objects. Those materials can have applications in different classes of energy storage and the two types that are focused in this dissertation are mechanical energy and thermal energy storage. Shape memory materials can store and recover elastic deformation energy when triggered by an external stimulus such as temperature. To incorporate those properties, shape memory polymeric aerogels (SMPA) were synthesized from a rigid isocyanurate containing triisocyanate (N3300 A) and four short oligomeric derivatives of ethylene glycol: H(OCH2CH2)[sub n]OH (1 d"n d"4). The shape memory effect (SME) of those aerogels were evaluated via four figures of merit namely strain fixity, strain recovery, strain recovery rate and fill factor. The morphologies of skeletal frameworks of those aerogels varied from micrometer sized particles with thick necks to bicontinuous structures, that are typical of spinodal decomposition. A Marcus-type thermodynamic-kinetic relationship was identified between that shape recovery rate, R[sub t](N), and the elastic modulus, E. Other part of the dissertation deals with the synthesis of nanoporous metallic iron (Fe(0)) aerogels via carbothermal reduction of interpenetrating networks of polybenzoxazine and iron oxide nanoparticles. Excess carbon was removed oxidatively at 600 °C under flowing air and the oxides of Fe(0) thus produced in the oxidative step were reduced back to Fe(0) with H2 at different temperatures ranging from 300 - 1300 °C. Those final monoliths were loaded with perchlorates and ignited with a flame in open air. Based on the temperature of the reduction step, monoliths either fizzled out (d"00 °C), exploded violently (500-900 °C), or behaved as thermites (e"50 °C)"--Abstract, page v.

Aerogels for Energy Saving and Storage

Aerogels for Energy Saving and Storage PDF Author: Meldin Mathew
Publisher: John Wiley & Sons
ISBN: 1119717639
Category : Technology & Engineering
Languages : en
Pages : 548

Book Description
Explore the energy storage applications of a wide variety of aerogels made from different materials In Aerogels for Energy Saving and Storage, an expert team of researchers delivers a one-stop resource covering the state-of-the-art in aerogels for energy applications. The book covers their morphology, properties, and processability and serves as a valuable resource for researchers and professionals working in materials science and environmentally friendly energy and power technology. The authors offer a comprehensive review of highly efficient energy applications of aerogels that bridges the gap between engineering, science, and chemistry and advances the field of materials development. They provide a Life Cycle Assessment of aerogels in energy systems, as well as discussions of their impact on the environment. Aerogel synthesis, characterization, fabrication, morphology, properties, energy-related applications, and simulations are all explored, and likely future research directions are provided. Readers will also find: A thorough introduction to aerogels in energy, including state-of-the-art advancements and challenges newly encountered Comprehensive explorations of chitin-based and cellulose-derived aerogels, as well as lignin-, clay-, and carbon nanotube-based aerogels Practical discussions of organic, natural, and inorganic aerogels, with further analyses of the lifecycle of aerogels In-depth examinations of the theory, modeling, and simulation of aerogels Perfect for chemical and environmental engineers, Aerogels for Energy Saving and Storage will also earn a place in the libraries of chemistry and materials science researchers in academia and industry.

Aerogels for Energy Saving and Storage

Aerogels for Energy Saving and Storage PDF Author: Meldin Mathew
Publisher: John Wiley & Sons
ISBN: 1119717655
Category : Technology & Engineering
Languages : en
Pages : 548

Book Description
Explore the energy storage applications of a wide variety of aerogels made from different materials In Aerogels for Energy Saving and Storage, an expert team of researchers delivers a one-stop resource covering the state-of-the-art in aerogels for energy applications. The book covers their morphology, properties, and processability and serves as a valuable resource for researchers and professionals working in materials science and environmentally friendly energy and power technology. The authors offer a comprehensive review of highly efficient energy applications of aerogels that bridges the gap between engineering, science, and chemistry and advances the field of materials development. They provide a Life Cycle Assessment of aerogels in energy systems, as well as discussions of their impact on the environment. Aerogel synthesis, characterization, fabrication, morphology, properties, energy-related applications, and simulations are all explored, and likely future research directions are provided. Readers will also find: A thorough introduction to aerogels in energy, including state-of-the-art advancements and challenges newly encountered Comprehensive explorations of chitin-based and cellulose-derived aerogels, as well as lignin-, clay-, and carbon nanotube-based aerogels Practical discussions of organic, natural, and inorganic aerogels, with further analyses of the lifecycle of aerogels In-depth examinations of the theory, modeling, and simulation of aerogels Perfect for chemical and environmental engineers, Aerogels for Energy Saving and Storage will also earn a place in the libraries of chemistry and materials science researchers in academia and industry.

Aerogels II

Aerogels II PDF Author: Inamuddin
Publisher: Materials Research Forum LLC
ISBN: 1644901293
Category : Technology & Engineering
Languages : en
Pages : 192

Book Description
The book focuses on aerogels for biomedical applications, thermal insulation, energy storage, fuel cells, batteries and environmental remediation. Keywords: Aerogels, Biomedical Applications, Implantable Devices, Tissue Engineering, Bone Regeneration, Biosensing, Pharmacological Applications, Catalysts, Water Purification, Pesticides, Thermal Insulation, Energy Storage, Fuel Cells, Batteries, Environmental Remediation, Polymer Aerogels, Bioaerogels, Carbon-based Aerogels.

Aerogels I

Aerogels I PDF Author: Inamuddin
Publisher: Materials Research Forum LLC
ISBN: 1644900998
Category : Technology & Engineering
Languages : en
Pages : 282

Book Description
This book focuses on aerogels and their applications in such areas as energy storage, thermal storage, catalysis, water splitting and environmental remediation. The materials covered include nanocellulose-, porous-, silica-, hybrid silica-, carbon-, graphene- and magnetic aerogels. Ways of modulating the pore structure of aerogels are presented, as well as surface modifications and the application of coatings. Future perspectives focus on functional foods, thickeners, stabilizers, and scaffolding in tissue repair. Keywords: Aerogels, Nanocellulose Aerogels, Non-Silicate Aerogels, Organic Aerogels, Composite Hybrid Aerogels, Carbon-based and Graphene-based Aerogels, Biogels, Hybrid Silica-based Aerogels, Energy Storage, Thermal Storage, Catalysis, Water Splitting, Environmental Remediation, Absorbents, Gas Filters, Packaging Materials, Electrical Devices, Thermal Insulations, Fire Retardants, Pharmaceutical and Biomedical Applications, Functional Foods, Thickeners, Stabilizers, Scaffolding in Tissue Repair.

Springer Handbook of Aerogels

Springer Handbook of Aerogels PDF Author: Michel A. Aegerter
Publisher: Springer Nature
ISBN: 3030273229
Category : Technology & Engineering
Languages : en
Pages : 1778

Book Description
This indispensable handbook provides comprehensive coverage of the current state-of-the-art in inorganic, organic, and composite aerogels – from synthesis and characterization to cutting-edge applications and their potential market impact. Built upon Springer’s successful Aerogels Handbook published in 2011, this handbook features extensive revisions and timely updates, reflecting the changes in this fast-growing field. Aerogels are the lightest solids known to man. Up to 1000 times lighter than glass and with a density only four times that of air, they possess extraordinarily high thermal, electrical, and acoustic insulation properties, and boast numerous entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to incorporate non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal, and ceramic materials. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation, and household uses are being developed. Readers of this fully updated and expanded edition will find an exhaustive source for all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and the most recent advances towards applications and commercial use. This key reference is essential reading for a combined audience of graduate students, academic researchers, and industry professionals.

Hybrid Aerogels

Hybrid Aerogels PDF Author: Krunal M. Gangawane
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3111252000
Category : Science
Languages : en
Pages : 302

Book Description
Aerogels are ultralight porous materials showing great promise in environmental remediation and energy storage. Aerogels successfully remove pollutants and can improve the properties of batteries, supercapacitors and even flexible electronics. The book covers the fundamentals of hybrid aerogels synthesis and their applications. It includes computational approaches such as Molecular Dynamics, lattice Boltzmann method and Navier-Stokes solver.

Aerogels

Aerogels PDF Author: Alina Iuliana Pruna
Publisher:
ISBN: 9781685078959
Category : Technology & Engineering
Languages : en
Pages : 0

Book Description
"This book, entitled Aerogels: Properties and Applications, aims to provide an insight into the synthesis and applications of varying materials in their aerogel form. The book covers the recent advances and reviews the state of the art of aerogels prepared from varying nanomaterials including carbon nanomaterials, silica, bioaerogels and hybrid aerogels in applications such as energy storage, electronics, or environmental remediation, in terms of water and air. The book serves as a fundamental information source on the techniques and methodologies applied to obtain the aerogel form of different nanomaterials, their characterization, and their post-synthesis modification or hybridization. The information enclosed in this book will be invaluable for experts to consolidate their knowledge and provide insight for newcomers to the field. Moreover, the book also includes the evolution of student satisfaction regarding a novel teaching approach based on the use of a teaching mobility event (International Week) as a platform to introduce engineering students to nanotechnology and specifically to graphene aerogels which could serve to improve teaching abilities and outcomes"--

Bio-Inspired Innovation and National Security

Bio-Inspired Innovation and National Security PDF Author: National Defense University
Publisher: NDU Press
ISBN: 1780390408
Category : History
Languages : en
Pages : 356

Book Description
Despite the vital importance of the emerging area of biotechnology and its role in defense planning and policymaking, no definitive book has been written on the topic for the defense policymaker, the military student, and the private-sector bioscientist interested in the "emerging opportunities market" of national security. This edited volume is intended to help close this gap and provide the necessary backdrop for thinking strategically about biology in defense planning and policymaking. This volume is about applications of the biological sciences, here called "biologically inspired innovations," to the military. Rather than treating biology as a series of threats to be dealt with, such innovations generally approach the biological sciences as a set of opportunities for the military to gain strategic advantage over adversaries. These opportunities range from looking at everything from genes to brains, from enhancing human performance to creating renewable energy, from sensing the environment around us to harnessing its power.

Textbook of Nanoscience and Nanotechnology

Textbook of Nanoscience and Nanotechnology PDF Author: B.S. Murty
Publisher: Springer Science & Business Media
ISBN: 3642280307
Category : Technology & Engineering
Languages : en
Pages : 256

Book Description
This book is meant to serve as a textbook for beginners in the field of nanoscience and nanotechnology. It can also be used as additional reading in this multifaceted area. It covers the entire spectrum of nanoscience and technology: introduction, terminology, historical perspectives of this domain of science, unique and widely differing properties, advances in the various synthesis, consolidation and characterization techniques, applications of nanoscience and technology and emerging materials and technologies.