Author: Prof. Dr. Shigeyoshi Inoue Publisher: MDPI ISBN: 3038976385 Category : Science Languages : en Pages : 228
Book Description
The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
Author: Michael J. Owen Publisher: Springer Science & Business Media ISBN: 9400738765 Category : Technology & Engineering Languages : en Pages : 399
Book Description
Silicone Surface Science offers a survey of the major topics concerning the properties and behavior of silicone surfaces. It covers all main aspects of the subject, including: polydimethylsiloxane, spread monolayers, self-assembled monolayers, hydrophobicity and super-hydrophobicity, coupling agents, surfactants, fluorosilicones, surface treatments and surface analysis. This book brings together the field's leading experts who investigated both fundamental and applied aspects of silicone surface science and technology, and introduces the reader to the origins and historical development of silicone surfaces as well as to their most significant current key features. Silicone Surface Science is an invaluable guide and indispensable reference source for all those interested in this important area of polymer and materials science and technology, from graduate students to experienced scientists alike.
Author: Peter Jutzi Publisher: John Wiley & Sons ISBN: 3527611215 Category : Science Languages : de Pages : 506
Book Description
The combined results from an international research project involving 40 interdisciplinary groups, providing the latest knowledge from the past few years. Adopting an application-oriented approach, this handy reference is a must-have for every silicon chemist, whether working in inorganic, organic, physical or polymer chemistry, materials science or physics.
Author: François Ganachaud Publisher: Springer Science & Business Media ISBN: 1402085281 Category : Technology & Engineering Languages : en Pages : 285
Book Description
Silicon Based Polymers presents highlights in advanced research and technological innovations using macromolecular organosilicon compounds and systems, as presented in the 2007 ISPO congress. Silicon-containing materials and polymers are used all over the world and in a variety of industries, domestic products and high technology applications. Among them, silicones are certainly the most well–known, however there are still new properties discovered and preparative processes developed all the time, therefore adding to their potential. Less known, but in preparation for the future, are other silicon containing-polymers which are now close to maturity and in fact some are already available like polysilsesquioxanes and polysilanes. All these silicon based materials can adopt very different structures like chains, dendrimers, hyperbranched and networks, physical and chemical gels. The result is a vast array of materials with applications in various areas such as optics, electronics, ionic electrolytes, liquid crystals, biomaterials, ceramics and concrete, paints and coatings ... all needed to face the environmental, energetical and technological issues of today. Some industrial aspects of the applications of these materials will also be presented.
Author: Gerald L. Larson Publisher: JAI Press ISBN: 9781559388313 Category : Science Languages : en Pages : 304
Book Description
This volume covers such topics as oxidative cleavage of the silicon-carbon bond, organosilyl peroxides and the chemistry of silyil carbonyl compounds.
Author: Stephen E. Saddow Publisher: Artech House ISBN: 9781580537414 Category : Science Languages : en Pages : 236
Book Description
Learn the latest advances in SiC (Silicon Carbide) technology from the leading experts in the field with this new cutting-edge resource. The book is your single source for in-depth information on both SiC device fabrication and system-level applications. This comprehensive reference begins with an examination of how SiC is grown and how defects in SiC growth can affect working devices. Key issues in selective doping of SiC via ion implantation are covered with special focus on implant conditions and electrical activation of implants. SiC applications discussed include chemical sensors, motor-control components, high-temperature gas sensors, and high-temperature electronics. By cutting through the arcane data and jargon surrounding the hype on SiC, this book gives an honest assessment of today's SiC technology and shows you how SiC can be adopted in developing tomorrow's applications.
Author: Bogdan Marciniec Publisher: Springer Science & Business Media ISBN: 1402081723 Category : Science Languages : en Pages : 424
Book Description
For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.
Author: Herbert W Roesky Publisher: Academic Press ISBN: 0128035684 Category : Science Languages : en Pages : 540
Book Description
Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter
Author: Paul M. Zelisko Publisher: Springer ISBN: 9401794391 Category : Science Languages : en Pages : 132
Book Description
The contributed volume addresses a wide range of topics including, but not limited to, biotechnology, synthetic chemistry, polymer chemistry and materials chemistry. The book will serve as a specialized review of the field of biologically inspired silicon-based structures. Researchers studying biologically inspired silicon materials chemistry will find this volume invaluable.
Author: Michael A. Brook Publisher: Wiley-Interscience ISBN: 9780471196587 Category : Science Languages : en Pages : 704
Book Description
A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations
Author: Prof. Dr. Shigeyoshi Inoue
Author: Michael J. Owen
Author: Peter Jutzi
Author: François Ganachaud
Author: Gerald L. Larson
Author: Stephen E. Saddow
Author: Bogdan Marciniec
Author: Herbert W Roesky
Author: Paul M. Zelisko
Author: Michael A. Brook